Tris(ethylenediamine-κ2N,N′)cadmium hexafluoridogermanate
In the title compound, [Cd(C2H8N2)3](GeF6), the CdII atom, lying on a 32 symmetry site, is coordinated by six N atoms from three ethylenediamine (en) ligands in a distorted octahedral geometry. The Ge atom also lies on a 32 symmetry site and is coordinated by six F atoms. The en ligand has a twofold...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-04-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S160053681200983X |
| _version_ | 1828128200372256768 |
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| author | Guo-Ming Wang Zeng-Xin Li Pei Wang |
| author_facet | Guo-Ming Wang Zeng-Xin Li Pei Wang |
| author_sort | Guo-Ming Wang |
| collection | DOAJ |
| description | In the title compound, [Cd(C2H8N2)3](GeF6), the CdII atom, lying on a 32 symmetry site, is coordinated by six N atoms from three ethylenediamine (en) ligands in a distorted octahedral geometry. The Ge atom also lies on a 32 symmetry site and is coordinated by six F atoms. The en ligand has a twofold rotation axis passing through the mid-point of the C—C bond. The F atom is disordered over two sites with equal occupancy factors. In the crystal, the [Cd(en)3]2+ cations and [GeF6]2− anions are connected through N—H...F hydrogen bonds, forming a three-dimensional supramolecular network. |
| first_indexed | 2024-04-11T16:00:23Z |
| format | Article |
| id | doaj.art-8ef224e430064a239e2e8714d3dd4605 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T16:00:23Z |
| publishDate | 2012-04-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-8ef224e430064a239e2e8714d3dd46052022-12-22T04:15:03ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-04-01684m396m39710.1107/S160053681200983XTris(ethylenediamine-κ2N,N′)cadmium hexafluoridogermanateGuo-Ming WangZeng-Xin LiPei WangIn the title compound, [Cd(C2H8N2)3](GeF6), the CdII atom, lying on a 32 symmetry site, is coordinated by six N atoms from three ethylenediamine (en) ligands in a distorted octahedral geometry. The Ge atom also lies on a 32 symmetry site and is coordinated by six F atoms. The en ligand has a twofold rotation axis passing through the mid-point of the C—C bond. The F atom is disordered over two sites with equal occupancy factors. In the crystal, the [Cd(en)3]2+ cations and [GeF6]2− anions are connected through N—H...F hydrogen bonds, forming a three-dimensional supramolecular network.http://scripts.iucr.org/cgi-bin/paper?S160053681200983X |
| spellingShingle | Guo-Ming Wang Zeng-Xin Li Pei Wang Tris(ethylenediamine-κ2N,N′)cadmium hexafluoridogermanate Acta Crystallographica Section E |
| title | Tris(ethylenediamine-κ2N,N′)cadmium hexafluoridogermanate |
| title_full | Tris(ethylenediamine-κ2N,N′)cadmium hexafluoridogermanate |
| title_fullStr | Tris(ethylenediamine-κ2N,N′)cadmium hexafluoridogermanate |
| title_full_unstemmed | Tris(ethylenediamine-κ2N,N′)cadmium hexafluoridogermanate |
| title_short | Tris(ethylenediamine-κ2N,N′)cadmium hexafluoridogermanate |
| title_sort | tris ethylenediamine amp 954 2n n amp 8242 cadmium hexafluoridogermanate |
| url | http://scripts.iucr.org/cgi-bin/paper?S160053681200983X |
| work_keys_str_mv | AT guomingwang trisethylenediamineamp9542nnamp8242cadmiumhexafluoridogermanate AT zengxinli trisethylenediamineamp9542nnamp8242cadmiumhexafluoridogermanate AT peiwang trisethylenediamineamp9542nnamp8242cadmiumhexafluoridogermanate |