catena-Poly[[μ-bromido-(μ-hydroxydi-2-pyridylmethanolato-κ4N,O:O,N′)dicopper(II)(Cu—Cu)]-di-μ-bromido]
The title complex, [Cu2Br3(C11H9N2O2)]n, was one of three isolated by slow evaporation of an acetonitrile reaction mixture of CuBr2 with di-2-pyridyl ketone (1:1 molar ratio). The title complex contains a 2:1 metal-to-ligand ratio of copper(II) with the hydrated form of the ligand, di-2-pyridylmetha...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2008-09-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808024197 |
| _version_ | 1818084901255118848 |
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| author | Allen D. Hunter Kristin M. Kopp-Vaughn Barry L. Westcott Matthias Zeller |
| author_facet | Allen D. Hunter Kristin M. Kopp-Vaughn Barry L. Westcott Matthias Zeller |
| author_sort | Allen D. Hunter |
| collection | DOAJ |
| description | The title complex, [Cu2Br3(C11H9N2O2)]n, was one of three isolated by slow evaporation of an acetonitrile reaction mixture of CuBr2 with di-2-pyridyl ketone (1:1 molar ratio). The title complex contains a 2:1 metal-to-ligand ratio of copper(II) with the hydrated form of the ligand, di-2-pyridylmethanediol. The two copper centers are bridged by a bromide ion and the alkoxy O atom, and the Cu—Cu distance is 2.9801 (5) Å. The dimeric units are further linked by bromide ions, leading to a two-dimensional extended bridged structure. O—H...O hydrogen bonds are present in the crystal structure. |
| first_indexed | 2024-12-10T20:01:15Z |
| format | Article |
| id | doaj.art-8f02aed75fd7434bae283328461bc107 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-10T20:01:15Z |
| publishDate | 2008-09-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-8f02aed75fd7434bae283328461bc1072022-12-22T01:35:30ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-09-01649m1121m112110.1107/S1600536808024197catena-Poly[[μ-bromido-(μ-hydroxydi-2-pyridylmethanolato-κ4N,O:O,N′)dicopper(II)(Cu—Cu)]-di-μ-bromido]Allen D. HunterKristin M. Kopp-VaughnBarry L. WestcottMatthias ZellerThe title complex, [Cu2Br3(C11H9N2O2)]n, was one of three isolated by slow evaporation of an acetonitrile reaction mixture of CuBr2 with di-2-pyridyl ketone (1:1 molar ratio). The title complex contains a 2:1 metal-to-ligand ratio of copper(II) with the hydrated form of the ligand, di-2-pyridylmethanediol. The two copper centers are bridged by a bromide ion and the alkoxy O atom, and the Cu—Cu distance is 2.9801 (5) Å. The dimeric units are further linked by bromide ions, leading to a two-dimensional extended bridged structure. O—H...O hydrogen bonds are present in the crystal structure.http://scripts.iucr.org/cgi-bin/paper?S1600536808024197 |
| spellingShingle | Allen D. Hunter Kristin M. Kopp-Vaughn Barry L. Westcott Matthias Zeller catena-Poly[[μ-bromido-(μ-hydroxydi-2-pyridylmethanolato-κ4N,O:O,N′)dicopper(II)(Cu—Cu)]-di-μ-bromido] Acta Crystallographica Section E |
| title | catena-Poly[[μ-bromido-(μ-hydroxydi-2-pyridylmethanolato-κ4N,O:O,N′)dicopper(II)(Cu—Cu)]-di-μ-bromido] |
| title_full | catena-Poly[[μ-bromido-(μ-hydroxydi-2-pyridylmethanolato-κ4N,O:O,N′)dicopper(II)(Cu—Cu)]-di-μ-bromido] |
| title_fullStr | catena-Poly[[μ-bromido-(μ-hydroxydi-2-pyridylmethanolato-κ4N,O:O,N′)dicopper(II)(Cu—Cu)]-di-μ-bromido] |
| title_full_unstemmed | catena-Poly[[μ-bromido-(μ-hydroxydi-2-pyridylmethanolato-κ4N,O:O,N′)dicopper(II)(Cu—Cu)]-di-μ-bromido] |
| title_short | catena-Poly[[μ-bromido-(μ-hydroxydi-2-pyridylmethanolato-κ4N,O:O,N′)dicopper(II)(Cu—Cu)]-di-μ-bromido] |
| title_sort | catena poly 956 bromido 956 hydroxydi 2 pyridylmethanolato 954 4n o o n 8242 dicopper ii cu 8212 cu di 956 bromido |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536808024197 |
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