catena-Poly[[cobalt(II)-μ-aqua-di-μ-butanoato-κ2O:O′;κ2O:O] 0.7-hydrate]
In the title coordination polymer, {[Co(C3H7COO)2(H2O)]·0.7H2O}n, the Co2+ cation is coordinated by four bridging butanoate anions and two bridging water molecules in a severely distorted octahedral geometry. The Co2+ cations are linked by means of bridging ligands into polymeric chains...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2011-06-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811019271 |
| Summary: | In the title coordination polymer, {[Co(C3H7COO)2(H2O)]·0.7H2O}n, the Co2+ cation is coordinated by four bridging butanoate anions and two bridging water molecules in a severely distorted octahedral geometry. The Co2+ cations are linked by means of bridging ligands into polymeric chains along [010]. These chains are further connected to each other through hydrogen bonds involving partially occupied disordered water molecules; thus, sheets parallel to (001) are formed. One of the positions of disordered water O atom lies on a twofold axis. Two atoms of the aliphatic chain of one of the butanoate anions are disordered over two positions each. |
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| ISSN: | 1600-5368 |