catena-Poly[[cobalt(II)-μ-aqua-di-μ-butanoato-κ2O:O′;κ2O:O] 0.7-hydrate]
In the title coordination polymer, {[Co(C3H7COO)2(H2O)]·0.7H2O}n, the Co2+ cation is coordinated by four bridging butanoate anions and two bridging water molecules in a severely distorted octahedral geometry. The Co2+ cations are linked by means of bridging ligands into polymeric chains...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2011-06-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811019271 |
| _version_ | 1828856478586372096 |
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| author | A. I. Fischer V. V. Gurzhiy A. N. Belyaev |
| author_facet | A. I. Fischer V. V. Gurzhiy A. N. Belyaev |
| author_sort | A. I. Fischer |
| collection | DOAJ |
| description | In the title coordination polymer, {[Co(C3H7COO)2(H2O)]·0.7H2O}n, the Co2+ cation is coordinated by four bridging butanoate anions and two bridging water molecules in a severely distorted octahedral geometry. The Co2+ cations are linked by means of bridging ligands into polymeric chains along [010]. These chains are further connected to each other through hydrogen bonds involving partially occupied disordered water molecules; thus, sheets parallel to (001) are formed. One of the positions of disordered water O atom lies on a twofold axis. Two atoms of the aliphatic chain of one of the butanoate anions are disordered over two positions each. |
| first_indexed | 2024-12-13T01:16:26Z |
| format | Article |
| id | doaj.art-8f078e0dbbb7489e9cea98645581191c |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T01:16:26Z |
| publishDate | 2011-06-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-8f078e0dbbb7489e9cea98645581191c2022-12-22T00:04:20ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-06-01676m807m80810.1107/S1600536811019271catena-Poly[[cobalt(II)-μ-aqua-di-μ-butanoato-κ2O:O′;κ2O:O] 0.7-hydrate]A. I. FischerV. V. GurzhiyA. N. BelyaevIn the title coordination polymer, {[Co(C3H7COO)2(H2O)]·0.7H2O}n, the Co2+ cation is coordinated by four bridging butanoate anions and two bridging water molecules in a severely distorted octahedral geometry. The Co2+ cations are linked by means of bridging ligands into polymeric chains along [010]. These chains are further connected to each other through hydrogen bonds involving partially occupied disordered water molecules; thus, sheets parallel to (001) are formed. One of the positions of disordered water O atom lies on a twofold axis. Two atoms of the aliphatic chain of one of the butanoate anions are disordered over two positions each.http://scripts.iucr.org/cgi-bin/paper?S1600536811019271 |
| spellingShingle | A. I. Fischer V. V. Gurzhiy A. N. Belyaev catena-Poly[[cobalt(II)-μ-aqua-di-μ-butanoato-κ2O:O′;κ2O:O] 0.7-hydrate] Acta Crystallographica Section E |
| title | catena-Poly[[cobalt(II)-μ-aqua-di-μ-butanoato-κ2O:O′;κ2O:O] 0.7-hydrate] |
| title_full | catena-Poly[[cobalt(II)-μ-aqua-di-μ-butanoato-κ2O:O′;κ2O:O] 0.7-hydrate] |
| title_fullStr | catena-Poly[[cobalt(II)-μ-aqua-di-μ-butanoato-κ2O:O′;κ2O:O] 0.7-hydrate] |
| title_full_unstemmed | catena-Poly[[cobalt(II)-μ-aqua-di-μ-butanoato-κ2O:O′;κ2O:O] 0.7-hydrate] |
| title_short | catena-Poly[[cobalt(II)-μ-aqua-di-μ-butanoato-κ2O:O′;κ2O:O] 0.7-hydrate] |
| title_sort | catena poly cobalt ii amp 956 aqua di amp 956 butanoato amp 954 2o o amp 8242 amp 954 2o o 0 7 hydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811019271 |
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