Synthesis and Characterization of Nickel-doped Manganese Dioxide Electrode Materials for Supercapacitors

Nickel-doped manganese dioxide (Ni-MnO2) synthesized by sol-gel method has been used as an electrode material for supercapacitors. The structure and electrochemical properties of the samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), cyclic voltammetry (CV), g...

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Main Authors: Dong Jie, Hou Zhenzhong, Zhao Qiuli, Yang Qinghao
Format: Article
Language:English
Published: EDP Sciences 2019-01-01
Series:E3S Web of Conferences
Online Access:https://doi.org/10.1051/e3sconf/20197903002
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author Dong Jie
Hou Zhenzhong
Zhao Qiuli
Yang Qinghao
author_facet Dong Jie
Hou Zhenzhong
Zhao Qiuli
Yang Qinghao
author_sort Dong Jie
collection DOAJ
description Nickel-doped manganese dioxide (Ni-MnO2) synthesized by sol-gel method has been used as an electrode material for supercapacitors. The structure and electrochemical properties of the samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), cyclic voltammetry (CV), galvanostatic charge-discharge (GCD) and electrochemical impedance spectrometry (EIS). Results showed that the nickel-doped manganese dioxide sample exhibited irregular particles with the diameter of about 500 nm. The crystallographic structure of MnO2 was the poorly crystallized γ-MnO2. The doping ratio had a great influence on the electrochemical properties of the materials. When the molar ratio of Ni/Mn was 3/100, the specific capacitance of Ni-MnO2 achieved to 252.61 F/g. After 2000 charge/discharge cycles, the specific capacitance of Ni-MnO2 was still maintained at 74.36%, which was attributed to its excellent cycling stability.
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spelling doaj.art-8f0c72268aa94884b082f17413eb019a2022-12-21T20:33:57ZengEDP SciencesE3S Web of Conferences2267-12422019-01-01790300210.1051/e3sconf/20197903002e3sconf_arfee2018_03002Synthesis and Characterization of Nickel-doped Manganese Dioxide Electrode Materials for SupercapacitorsDong JieHou ZhenzhongZhao QiuliYang QinghaoNickel-doped manganese dioxide (Ni-MnO2) synthesized by sol-gel method has been used as an electrode material for supercapacitors. The structure and electrochemical properties of the samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), cyclic voltammetry (CV), galvanostatic charge-discharge (GCD) and electrochemical impedance spectrometry (EIS). Results showed that the nickel-doped manganese dioxide sample exhibited irregular particles with the diameter of about 500 nm. The crystallographic structure of MnO2 was the poorly crystallized γ-MnO2. The doping ratio had a great influence on the electrochemical properties of the materials. When the molar ratio of Ni/Mn was 3/100, the specific capacitance of Ni-MnO2 achieved to 252.61 F/g. After 2000 charge/discharge cycles, the specific capacitance of Ni-MnO2 was still maintained at 74.36%, which was attributed to its excellent cycling stability.https://doi.org/10.1051/e3sconf/20197903002
spellingShingle Dong Jie
Hou Zhenzhong
Zhao Qiuli
Yang Qinghao
Synthesis and Characterization of Nickel-doped Manganese Dioxide Electrode Materials for Supercapacitors
E3S Web of Conferences
title Synthesis and Characterization of Nickel-doped Manganese Dioxide Electrode Materials for Supercapacitors
title_full Synthesis and Characterization of Nickel-doped Manganese Dioxide Electrode Materials for Supercapacitors
title_fullStr Synthesis and Characterization of Nickel-doped Manganese Dioxide Electrode Materials for Supercapacitors
title_full_unstemmed Synthesis and Characterization of Nickel-doped Manganese Dioxide Electrode Materials for Supercapacitors
title_short Synthesis and Characterization of Nickel-doped Manganese Dioxide Electrode Materials for Supercapacitors
title_sort synthesis and characterization of nickel doped manganese dioxide electrode materials for supercapacitors
url https://doi.org/10.1051/e3sconf/20197903002
work_keys_str_mv AT dongjie synthesisandcharacterizationofnickeldopedmanganesedioxideelectrodematerialsforsupercapacitors
AT houzhenzhong synthesisandcharacterizationofnickeldopedmanganesedioxideelectrodematerialsforsupercapacitors
AT zhaoqiuli synthesisandcharacterizationofnickeldopedmanganesedioxideelectrodematerialsforsupercapacitors
AT yangqinghao synthesisandcharacterizationofnickeldopedmanganesedioxideelectrodematerialsforsupercapacitors