Microstructure and property evolution of Cu–9Ni–6Sn-xCr alloys during thermo-mechanical treatment process

In this study, Cu–9Ni–6Sn-xCr alloys (x = 0, 0.3, 0.6, or 1.0) were designed and prepared. The influence of Cr content on the microstructure, the precipitation behavior, and the mechanical properties of the alloys was systematically investigated. The results show that the Cu–9Ni–6Sn-0.6Cr alloy exhi...

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Main Authors: Yuanqi You, Caiju Li, Kui Jin, Jiangnan Li, Qiong Lu, Zunyan Xu, Peng Gao, Xuhui Xu, Fengxian Li, Jianhong Yi
Format: Article
Language:English
Published: Elsevier 2024-05-01
Series:Journal of Materials Research and Technology
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2238785424008068
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author Yuanqi You
Caiju Li
Kui Jin
Jiangnan Li
Qiong Lu
Zunyan Xu
Peng Gao
Xuhui Xu
Fengxian Li
Jianhong Yi
author_facet Yuanqi You
Caiju Li
Kui Jin
Jiangnan Li
Qiong Lu
Zunyan Xu
Peng Gao
Xuhui Xu
Fengxian Li
Jianhong Yi
author_sort Yuanqi You
collection DOAJ
description In this study, Cu–9Ni–6Sn-xCr alloys (x = 0, 0.3, 0.6, or 1.0) were designed and prepared. The influence of Cr content on the microstructure, the precipitation behavior, and the mechanical properties of the alloys was systematically investigated. The results show that the Cu–9Ni–6Sn-0.6Cr alloy exhibits outstanding mechanical properties and higher level electrical conductivity after aging at 400 °C for 8 h: The peak-aged hardness reaches 323.6 ± 8.4 HV, with a tensile strength of 876.4 MPa and an electrical conductivity of 12.59 ± 0.33% IACS. These excellent comprehensive properties of Cu–9Ni–6Sn-0.6Cr alloy are attribute to the refinement effect and the precipitation of DO22 phase within the Cu matrix grains. Further analysis reveals that the addition of an appropriate amount of Cr refines the microstructure of the alloy and promotes the precipitation of the DO22 phase. At the same time, Cr also suppresses the precipitation of the DO3 phase at grain boundaries, achieving an excellent combination of plasticity, electrical conductivity, and strength. This work suggests that the potential application prospects of Cr in the multi-component design of Cu–Ni–Sn alloy, and the addition of 0.6 wt% Cr can achieve good strengthening effects and provide outstanding comprehensive performance for Cu–Ni–Sn alloys.
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spelling doaj.art-8f181d5013d544429b5061e6473399402024-04-10T04:29:03ZengElsevierJournal of Materials Research and Technology2238-78542024-05-013026422652Microstructure and property evolution of Cu–9Ni–6Sn-xCr alloys during thermo-mechanical treatment processYuanqi You0Caiju Li1Kui Jin2Jiangnan Li3Qiong Lu4Zunyan Xu5Peng Gao6Xuhui Xu7Fengxian Li8Jianhong Yi9Faculty of Materials Science and Engineering, Kunming University of Science and Technology, Kunming, Yunnan, 650093, ChinaFaculty of Materials Science and Engineering, Kunming University of Science and Technology, Kunming, Yunnan, 650093, China; Yunnan Engineering Research Center of Metallic Powder Materials, Kunming University of Science and Technology, Kunming, 650093, China; Corresponding author. Faculty of Materials Science and Engineering, Kunming University of Science and Technology, Kunming, Yunnan, 650093, China.Faculty of Materials Science and Engineering, Kunming University of Science and Technology, Kunming, Yunnan, 650093, ChinaFaculty of Materials Science and Engineering, Kunming University of Science and Technology, Kunming, Yunnan, 650093, China; Yunnan Engineering Research Center of Metallic Powder Materials, Kunming University of Science and Technology, Kunming, 650093, ChinaFaculty of Materials Science and Engineering, Kunming University of Science and Technology, Kunming, Yunnan, 650093, China; Yunnan Engineering Research Center of Metallic Powder Materials, Kunming University of Science and Technology, Kunming, 650093, ChinaFaculty of Materials Science and Engineering, Kunming University of Science and Technology, Kunming, Yunnan, 650093, China; Yunnan Engineering Research Center of Metallic Powder Materials, Kunming University of Science and Technology, Kunming, 650093, ChinaFaculty of Materials Science and Engineering, Kunming University of Science and Technology, Kunming, Yunnan, 650093, ChinaFaculty of Materials Science and Engineering, Kunming University of Science and Technology, Kunming, Yunnan, 650093, ChinaFaculty of Materials Science and Engineering, Kunming University of Science and Technology, Kunming, Yunnan, 650093, China; Yunnan Engineering Research Center of Metallic Powder Materials, Kunming University of Science and Technology, Kunming, 650093, ChinaFaculty of Materials Science and Engineering, Kunming University of Science and Technology, Kunming, Yunnan, 650093, China; Yunnan Engineering Research Center of Metallic Powder Materials, Kunming University of Science and Technology, Kunming, 650093, ChinaIn this study, Cu–9Ni–6Sn-xCr alloys (x = 0, 0.3, 0.6, or 1.0) were designed and prepared. The influence of Cr content on the microstructure, the precipitation behavior, and the mechanical properties of the alloys was systematically investigated. The results show that the Cu–9Ni–6Sn-0.6Cr alloy exhibits outstanding mechanical properties and higher level electrical conductivity after aging at 400 °C for 8 h: The peak-aged hardness reaches 323.6 ± 8.4 HV, with a tensile strength of 876.4 MPa and an electrical conductivity of 12.59 ± 0.33% IACS. These excellent comprehensive properties of Cu–9Ni–6Sn-0.6Cr alloy are attribute to the refinement effect and the precipitation of DO22 phase within the Cu matrix grains. Further analysis reveals that the addition of an appropriate amount of Cr refines the microstructure of the alloy and promotes the precipitation of the DO22 phase. At the same time, Cr also suppresses the precipitation of the DO3 phase at grain boundaries, achieving an excellent combination of plasticity, electrical conductivity, and strength. This work suggests that the potential application prospects of Cr in the multi-component design of Cu–Ni–Sn alloy, and the addition of 0.6 wt% Cr can achieve good strengthening effects and provide outstanding comprehensive performance for Cu–Ni–Sn alloys.http://www.sciencedirect.com/science/article/pii/S2238785424008068Cu-9Ni–6Sn-xCr alloysMicrostructurePrecipitation behaviorMechanical propertiesElectrical conductivity
spellingShingle Yuanqi You
Caiju Li
Kui Jin
Jiangnan Li
Qiong Lu
Zunyan Xu
Peng Gao
Xuhui Xu
Fengxian Li
Jianhong Yi
Microstructure and property evolution of Cu–9Ni–6Sn-xCr alloys during thermo-mechanical treatment process
Journal of Materials Research and Technology
Cu-9Ni–6Sn-xCr alloys
Microstructure
Precipitation behavior
Mechanical properties
Electrical conductivity
title Microstructure and property evolution of Cu–9Ni–6Sn-xCr alloys during thermo-mechanical treatment process
title_full Microstructure and property evolution of Cu–9Ni–6Sn-xCr alloys during thermo-mechanical treatment process
title_fullStr Microstructure and property evolution of Cu–9Ni–6Sn-xCr alloys during thermo-mechanical treatment process
title_full_unstemmed Microstructure and property evolution of Cu–9Ni–6Sn-xCr alloys during thermo-mechanical treatment process
title_short Microstructure and property evolution of Cu–9Ni–6Sn-xCr alloys during thermo-mechanical treatment process
title_sort microstructure and property evolution of cu 9ni 6sn xcr alloys during thermo mechanical treatment process
topic Cu-9Ni–6Sn-xCr alloys
Microstructure
Precipitation behavior
Mechanical properties
Electrical conductivity
url http://www.sciencedirect.com/science/article/pii/S2238785424008068
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