Electrochemical synthesis of silver nanoparticles in poly(vinyl alcohol) solution

In this work silver/poly(vinyl alcohol), Ag/PVA, colloid dispersions were obtained by electrochemical reduction of Ag+ ions. The electrochemical synthesis of silver nanoparticles in the aqueous solutions of 5 and 10 wt. % PVA, containing 0.1 M KNO3 and 3.9 mM AgNO3, was performed at constan...

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Main Authors: Surudžić Rade, Jovanović Željka, Bibić Nataša, Nikolić Branislav, Mišković-Stanković Vesna
Format: Article
Language:English
Published: Serbian Chemical Society 2013-01-01
Series:Journal of the Serbian Chemical Society
Subjects:
Online Access:http://www.doiserbia.nb.rs/img/doi/0352-5139/2013/0352-51391300124S.pdf
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author Surudžić Rade
Jovanović Željka
Bibić Nataša
Nikolić Branislav
Mišković-Stanković Vesna
author_facet Surudžić Rade
Jovanović Željka
Bibić Nataša
Nikolić Branislav
Mišković-Stanković Vesna
author_sort Surudžić Rade
collection DOAJ
description In this work silver/poly(vinyl alcohol), Ag/PVA, colloid dispersions were obtained by electrochemical reduction of Ag+ ions. The electrochemical synthesis of silver nanoparticles in the aqueous solutions of 5 and 10 wt. % PVA, containing 0.1 M KNO3 and 3.9 mM AgNO3, was performed at constant current density of 25 mA cm-2, and during synthesis time of 10 min. The presence of silver nanoparticles was confirmed by UV-vis spectroscopy. Cyclic voltammetry analysis and FTIR spectroscopy indicated the interactions between silver nanoparticles and PVA molecules. TEM analysis confirmed spherical shape of the obtained silver nanoparticles, with the mean diameter of 15 ± 9 nm. [Projekat Ministarstva nauke Republike Srbije, br. III 45019 and Eureka E!6749]
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spelling doaj.art-8f21126a358a4180aad342f3190a09ef2022-12-21T21:17:28ZengSerbian Chemical SocietyJournal of the Serbian Chemical Society0352-51391820-74212013-01-0178122087209810.2298/JSC131017124S0352-51391300124SElectrochemical synthesis of silver nanoparticles in poly(vinyl alcohol) solutionSurudžić Rade0Jovanović Željka1Bibić Nataša2Nikolić Branislav3Mišković-Stanković Vesna4Faculty of Technology and Metallurgy, BelgradeFaculty of Technology and Metallurgy, BelgradeVinča Institute of Nuclear Sciences, BelgradeFaculty of Technology and Metallurgy, BelgradeFaculty of Technology and Metallurgy, BelgradeIn this work silver/poly(vinyl alcohol), Ag/PVA, colloid dispersions were obtained by electrochemical reduction of Ag+ ions. The electrochemical synthesis of silver nanoparticles in the aqueous solutions of 5 and 10 wt. % PVA, containing 0.1 M KNO3 and 3.9 mM AgNO3, was performed at constant current density of 25 mA cm-2, and during synthesis time of 10 min. The presence of silver nanoparticles was confirmed by UV-vis spectroscopy. Cyclic voltammetry analysis and FTIR spectroscopy indicated the interactions between silver nanoparticles and PVA molecules. TEM analysis confirmed spherical shape of the obtained silver nanoparticles, with the mean diameter of 15 ± 9 nm. [Projekat Ministarstva nauke Republike Srbije, br. III 45019 and Eureka E!6749]http://www.doiserbia.nb.rs/img/doi/0352-5139/2013/0352-51391300124S.pdfelectrochemical synthesisPVAsilver nanoparticles
spellingShingle Surudžić Rade
Jovanović Željka
Bibić Nataša
Nikolić Branislav
Mišković-Stanković Vesna
Electrochemical synthesis of silver nanoparticles in poly(vinyl alcohol) solution
Journal of the Serbian Chemical Society
electrochemical synthesis
PVA
silver nanoparticles
title Electrochemical synthesis of silver nanoparticles in poly(vinyl alcohol) solution
title_full Electrochemical synthesis of silver nanoparticles in poly(vinyl alcohol) solution
title_fullStr Electrochemical synthesis of silver nanoparticles in poly(vinyl alcohol) solution
title_full_unstemmed Electrochemical synthesis of silver nanoparticles in poly(vinyl alcohol) solution
title_short Electrochemical synthesis of silver nanoparticles in poly(vinyl alcohol) solution
title_sort electrochemical synthesis of silver nanoparticles in poly vinyl alcohol solution
topic electrochemical synthesis
PVA
silver nanoparticles
url http://www.doiserbia.nb.rs/img/doi/0352-5139/2013/0352-51391300124S.pdf
work_keys_str_mv AT surudzicrade electrochemicalsynthesisofsilvernanoparticlesinpolyvinylalcoholsolution
AT jovanoviczeljka electrochemicalsynthesisofsilvernanoparticlesinpolyvinylalcoholsolution
AT bibicnatasa electrochemicalsynthesisofsilvernanoparticlesinpolyvinylalcoholsolution
AT nikolicbranislav electrochemicalsynthesisofsilvernanoparticlesinpolyvinylalcoholsolution
AT miskovicstankovicvesna electrochemicalsynthesisofsilvernanoparticlesinpolyvinylalcoholsolution