Diaquabis(1,3-propanediamine)nickel(II) squarate tetrahydrate
The asymmetric unit of the title compound, [Ni(C3H10N2)2(H2O)2](C4O4)·4H2O, contains one-half of the diaquabis(1,3-propanediamine)nickel(II) cation, one-half of the centrosymmetric squarate anion and two uncoordinated water molecules. In the cation, the NiII atom is located on a crystal...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2009-07-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S160053680902087X |
| _version_ | 1819279775123898368 |
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| author | Ersin Temel Hakan Erer Okan Zafer Yeşilel Orhan Büyükgüngör |
| author_facet | Ersin Temel Hakan Erer Okan Zafer Yeşilel Orhan Büyükgüngör |
| author_sort | Ersin Temel |
| collection | DOAJ |
| description | The asymmetric unit of the title compound, [Ni(C3H10N2)2(H2O)2](C4O4)·4H2O, contains one-half of the diaquabis(1,3-propanediamine)nickel(II) cation, one-half of the centrosymmetric squarate anion and two uncoordinated water molecules. In the cation, the NiII atom is located on a crystallographic inversion centre and has a slightly distorted octahedral coordination geometry. The six-membered chelate ring adopts a chair conformation. O—H...O hydrogen bonds link the cation and anion through the water molecule, while N—H...O hydrogen bonds link the cation and anion and cation and water molecules. In the crystal structure, intermolecular O—H...O and N—H...O hydrogen bonds link the molecules into a three-dimensional network structure. |
| first_indexed | 2024-12-24T00:33:15Z |
| format | Article |
| id | doaj.art-8f26ff3fd96a4bea89427b87e717ff78 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T00:33:15Z |
| publishDate | 2009-07-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-8f26ff3fd96a4bea89427b87e717ff782022-12-21T17:24:11ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-07-01657m735m73610.1107/S160053680902087XDiaquabis(1,3-propanediamine)nickel(II) squarate tetrahydrateErsin TemelHakan ErerOkan Zafer YeşilelOrhan BüyükgüngörThe asymmetric unit of the title compound, [Ni(C3H10N2)2(H2O)2](C4O4)·4H2O, contains one-half of the diaquabis(1,3-propanediamine)nickel(II) cation, one-half of the centrosymmetric squarate anion and two uncoordinated water molecules. In the cation, the NiII atom is located on a crystallographic inversion centre and has a slightly distorted octahedral coordination geometry. The six-membered chelate ring adopts a chair conformation. O—H...O hydrogen bonds link the cation and anion through the water molecule, while N—H...O hydrogen bonds link the cation and anion and cation and water molecules. In the crystal structure, intermolecular O—H...O and N—H...O hydrogen bonds link the molecules into a three-dimensional network structure.http://scripts.iucr.org/cgi-bin/paper?S160053680902087X |
| spellingShingle | Ersin Temel Hakan Erer Okan Zafer Yeşilel Orhan Büyükgüngör Diaquabis(1,3-propanediamine)nickel(II) squarate tetrahydrate Acta Crystallographica Section E |
| title | Diaquabis(1,3-propanediamine)nickel(II) squarate tetrahydrate |
| title_full | Diaquabis(1,3-propanediamine)nickel(II) squarate tetrahydrate |
| title_fullStr | Diaquabis(1,3-propanediamine)nickel(II) squarate tetrahydrate |
| title_full_unstemmed | Diaquabis(1,3-propanediamine)nickel(II) squarate tetrahydrate |
| title_short | Diaquabis(1,3-propanediamine)nickel(II) squarate tetrahydrate |
| title_sort | diaquabis 1 3 propanediamine nickel ii squarate tetrahydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S160053680902087X |
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