Preparation of Benzothiazole-Substituted Carbosilane Dendrimers up to the 7th Generation

Carbosilane dendrimers with 2-(2-phenyloxy)benzothiazole groups on the periphery were prepared from the 1st to the 7th generation. All dendrimers were characterized by 1H- and 13C-NMR, elemental analysis, MALDI TOF MS, GPC, and PL (photoluminescence) spectroscopy. Characteristic PDI (Polydisperse In...

Full description

Bibliographic Details
Main Authors: Chungkyun Kim, Hyojeong Kim
Format: Article
Language:English
Published: MDPI AG 2009-04-01
Series:Molecules
Subjects:
Online Access:http://www.mdpi.com/1420-3049/14/4/1605/
Description
Summary:Carbosilane dendrimers with 2-(2-phenyloxy)benzothiazole groups on the periphery were prepared from the 1st to the 7th generation. All dendrimers were characterized by 1H- and 13C-NMR, elemental analysis, MALDI TOF MS, GPC, and PL (photoluminescence) spectroscopy. Characteristic PDI (Polydisperse Index) values of the peaks corresponding to the respective dendrimers in the GPC data is in very narrow range of 1.00~1.04. All PL spectra show a blue-shift increasing with generation from the 1st to the 7th.
ISSN:1420-3049