Preparation of Benzothiazole-Substituted Carbosilane Dendrimers up to the 7th Generation

Carbosilane dendrimers with 2-(2-phenyloxy)benzothiazole groups on the periphery were prepared from the 1st to the 7th generation. All dendrimers were characterized by 1H- and 13C-NMR, elemental analysis, MALDI TOF MS, GPC, and PL (photoluminescence) spectroscopy. Characteristic PDI (Polydisperse In...

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Main Authors: Chungkyun Kim, Hyojeong Kim
Format: Article
Language:English
Published: MDPI AG 2009-04-01
Series:Molecules
Subjects:
Online Access:http://www.mdpi.com/1420-3049/14/4/1605/
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author Chungkyun Kim
Hyojeong Kim
author_facet Chungkyun Kim
Hyojeong Kim
author_sort Chungkyun Kim
collection DOAJ
description Carbosilane dendrimers with 2-(2-phenyloxy)benzothiazole groups on the periphery were prepared from the 1st to the 7th generation. All dendrimers were characterized by 1H- and 13C-NMR, elemental analysis, MALDI TOF MS, GPC, and PL (photoluminescence) spectroscopy. Characteristic PDI (Polydisperse Index) values of the peaks corresponding to the respective dendrimers in the GPC data is in very narrow range of 1.00~1.04. All PL spectra show a blue-shift increasing with generation from the 1st to the 7th.
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spelling doaj.art-8f2eeabf71344ae79304b01ce4f4cc2a2022-12-22T00:29:48ZengMDPI AGMolecules1420-30492009-04-011441605161310.3390/molecules14041605Preparation of Benzothiazole-Substituted Carbosilane Dendrimers up to the 7th GenerationChungkyun KimHyojeong KimCarbosilane dendrimers with 2-(2-phenyloxy)benzothiazole groups on the periphery were prepared from the 1st to the 7th generation. All dendrimers were characterized by 1H- and 13C-NMR, elemental analysis, MALDI TOF MS, GPC, and PL (photoluminescence) spectroscopy. Characteristic PDI (Polydisperse Index) values of the peaks corresponding to the respective dendrimers in the GPC data is in very narrow range of 1.00~1.04. All PL spectra show a blue-shift increasing with generation from the 1st to the 7th.http://www.mdpi.com/1420-3049/14/4/1605/DendrimerCarbosilanePLGPCSilicone
spellingShingle Chungkyun Kim
Hyojeong Kim
Preparation of Benzothiazole-Substituted Carbosilane Dendrimers up to the 7th Generation
Molecules
Dendrimer
Carbosilane
PL
GPC
Silicone
title Preparation of Benzothiazole-Substituted Carbosilane Dendrimers up to the 7th Generation
title_full Preparation of Benzothiazole-Substituted Carbosilane Dendrimers up to the 7th Generation
title_fullStr Preparation of Benzothiazole-Substituted Carbosilane Dendrimers up to the 7th Generation
title_full_unstemmed Preparation of Benzothiazole-Substituted Carbosilane Dendrimers up to the 7th Generation
title_short Preparation of Benzothiazole-Substituted Carbosilane Dendrimers up to the 7th Generation
title_sort preparation of benzothiazole substituted carbosilane dendrimers up to the 7th generation
topic Dendrimer
Carbosilane
PL
GPC
Silicone
url http://www.mdpi.com/1420-3049/14/4/1605/
work_keys_str_mv AT chungkyunkim preparationofbenzothiazolesubstitutedcarbosilanedendrimersuptothe7thgeneration
AT hyojeongkim preparationofbenzothiazolesubstitutedcarbosilanedendrimersuptothe7thgeneration