Preparation of Benzothiazole-Substituted Carbosilane Dendrimers up to the 7th Generation
Carbosilane dendrimers with 2-(2-phenyloxy)benzothiazole groups on the periphery were prepared from the 1st to the 7th generation. All dendrimers were characterized by 1H- and 13C-NMR, elemental analysis, MALDI TOF MS, GPC, and PL (photoluminescence) spectroscopy. Characteristic PDI (Polydisperse In...
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MDPI AG
2009-04-01
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Series: | Molecules |
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Online Access: | http://www.mdpi.com/1420-3049/14/4/1605/ |
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author | Chungkyun Kim Hyojeong Kim |
author_facet | Chungkyun Kim Hyojeong Kim |
author_sort | Chungkyun Kim |
collection | DOAJ |
description | Carbosilane dendrimers with 2-(2-phenyloxy)benzothiazole groups on the periphery were prepared from the 1st to the 7th generation. All dendrimers were characterized by 1H- and 13C-NMR, elemental analysis, MALDI TOF MS, GPC, and PL (photoluminescence) spectroscopy. Characteristic PDI (Polydisperse Index) values of the peaks corresponding to the respective dendrimers in the GPC data is in very narrow range of 1.00~1.04. All PL spectra show a blue-shift increasing with generation from the 1st to the 7th. |
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format | Article |
id | doaj.art-8f2eeabf71344ae79304b01ce4f4cc2a |
institution | Directory Open Access Journal |
issn | 1420-3049 |
language | English |
last_indexed | 2024-12-12T09:02:05Z |
publishDate | 2009-04-01 |
publisher | MDPI AG |
record_format | Article |
series | Molecules |
spelling | doaj.art-8f2eeabf71344ae79304b01ce4f4cc2a2022-12-22T00:29:48ZengMDPI AGMolecules1420-30492009-04-011441605161310.3390/molecules14041605Preparation of Benzothiazole-Substituted Carbosilane Dendrimers up to the 7th GenerationChungkyun KimHyojeong KimCarbosilane dendrimers with 2-(2-phenyloxy)benzothiazole groups on the periphery were prepared from the 1st to the 7th generation. All dendrimers were characterized by 1H- and 13C-NMR, elemental analysis, MALDI TOF MS, GPC, and PL (photoluminescence) spectroscopy. Characteristic PDI (Polydisperse Index) values of the peaks corresponding to the respective dendrimers in the GPC data is in very narrow range of 1.00~1.04. All PL spectra show a blue-shift increasing with generation from the 1st to the 7th.http://www.mdpi.com/1420-3049/14/4/1605/DendrimerCarbosilanePLGPCSilicone |
spellingShingle | Chungkyun Kim Hyojeong Kim Preparation of Benzothiazole-Substituted Carbosilane Dendrimers up to the 7th Generation Molecules Dendrimer Carbosilane PL GPC Silicone |
title | Preparation of Benzothiazole-Substituted Carbosilane Dendrimers up to the 7th Generation |
title_full | Preparation of Benzothiazole-Substituted Carbosilane Dendrimers up to the 7th Generation |
title_fullStr | Preparation of Benzothiazole-Substituted Carbosilane Dendrimers up to the 7th Generation |
title_full_unstemmed | Preparation of Benzothiazole-Substituted Carbosilane Dendrimers up to the 7th Generation |
title_short | Preparation of Benzothiazole-Substituted Carbosilane Dendrimers up to the 7th Generation |
title_sort | preparation of benzothiazole substituted carbosilane dendrimers up to the 7th generation |
topic | Dendrimer Carbosilane PL GPC Silicone |
url | http://www.mdpi.com/1420-3049/14/4/1605/ |
work_keys_str_mv | AT chungkyunkim preparationofbenzothiazolesubstitutedcarbosilanedendrimersuptothe7thgeneration AT hyojeongkim preparationofbenzothiazolesubstitutedcarbosilanedendrimersuptothe7thgeneration |