An Unusual Bismuth Ethanedisulfonate Network
The three dimensional bismuth ethanedisulfonate framework Bi(O3SC2H4SO3)1.5(H2O)2 was synthesized under hydrothermal conditions using the bidentate ligand 1,2-ethanedisulfonate and then characterized through X-ray diffraction and elemental analyses. The bismuth cation coordinates at three different...
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| Format: | Article |
| Language: | English |
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MDPI AG
2012-09-01
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| Series: | Crystals |
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| Online Access: | http://www.mdpi.com/2073-4352/2/4/1374 |
| _version_ | 1828348658524880896 |
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| author | Fabienne Gschwind Martin Jansen |
| author_facet | Fabienne Gschwind Martin Jansen |
| author_sort | Fabienne Gschwind |
| collection | DOAJ |
| description | The three dimensional bismuth ethanedisulfonate framework Bi(O3SC2H4SO3)1.5(H2O)2 was synthesized under hydrothermal conditions using the bidentate ligand 1,2-ethanedisulfonate and then characterized through X-ray diffraction and elemental analyses. The bismuth cation coordinates at three different ethanedisulfonate ligands and has a coordination number of eight, which is accompanied by a distorted square antiprismatic configuration. Here, we report on the crystal structure of this bismuth metal–organic framework and its coordination behavior, which has thus far not been reported in heavier main group elements. |
| first_indexed | 2024-04-14T00:58:32Z |
| format | Article |
| id | doaj.art-8f3007dc5ad441fe962a955894f5fe70 |
| institution | Directory Open Access Journal |
| issn | 2073-4352 |
| language | English |
| last_indexed | 2024-04-14T00:58:32Z |
| publishDate | 2012-09-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Crystals |
| spelling | doaj.art-8f3007dc5ad441fe962a955894f5fe702022-12-22T02:21:31ZengMDPI AGCrystals2073-43522012-09-01241374138110.3390/cryst2041374An Unusual Bismuth Ethanedisulfonate NetworkFabienne GschwindMartin JansenThe three dimensional bismuth ethanedisulfonate framework Bi(O3SC2H4SO3)1.5(H2O)2 was synthesized under hydrothermal conditions using the bidentate ligand 1,2-ethanedisulfonate and then characterized through X-ray diffraction and elemental analyses. The bismuth cation coordinates at three different ethanedisulfonate ligands and has a coordination number of eight, which is accompanied by a distorted square antiprismatic configuration. Here, we report on the crystal structure of this bismuth metal–organic framework and its coordination behavior, which has thus far not been reported in heavier main group elements.http://www.mdpi.com/2073-4352/2/4/1374main group chemistrybismuth complexethanedisulfonateMOF |
| spellingShingle | Fabienne Gschwind Martin Jansen An Unusual Bismuth Ethanedisulfonate Network Crystals main group chemistry bismuth complex ethanedisulfonate MOF |
| title | An Unusual Bismuth Ethanedisulfonate Network |
| title_full | An Unusual Bismuth Ethanedisulfonate Network |
| title_fullStr | An Unusual Bismuth Ethanedisulfonate Network |
| title_full_unstemmed | An Unusual Bismuth Ethanedisulfonate Network |
| title_short | An Unusual Bismuth Ethanedisulfonate Network |
| title_sort | unusual bismuth ethanedisulfonate network |
| topic | main group chemistry bismuth complex ethanedisulfonate MOF |
| url | http://www.mdpi.com/2073-4352/2/4/1374 |
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