Self-assembled monolayer of designed and synthesized triazinedithiolsilane molecule as interfacial adhesion enhancer for integrated circuit
<p>Abstract</p> <p>Self-assembled monolayer (SAM) with tunable surface chemistry and smooth surface provides an approach to adhesion improvement and suppressing deleterious chemical interactions. Here, we demonstrate the SAM comprising of designed and synthesized 6-(3-triethoxysily...
Main Authors: | , , , |
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Format: | Article |
Language: | English |
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SpringerOpen
2011-01-01
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Series: | Nanoscale Research Letters |
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Online Access: | http://www.nanoscalereslett.com/content/6/1/483 |
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author | Wang Fang Li Yanni Wang Yabin Cao Zhuo |
author_facet | Wang Fang Li Yanni Wang Yabin Cao Zhuo |
author_sort | Wang Fang |
collection | DOAJ |
description | <p>Abstract</p> <p>Self-assembled monolayer (SAM) with tunable surface chemistry and smooth surface provides an approach to adhesion improvement and suppressing deleterious chemical interactions. Here, we demonstrate the SAM comprising of designed and synthesized 6-(3-triethoxysilylpropyl)amino-1,3,5-triazine-2,4-dithiol molecule, which can enhance interfacial adhesion to inhibit copper diffusion used in device metallization. The formation of the triazinedithiolsilane SAM is confirmed by X-ray photoelectron spectroscopy. The adhesion strength between SAM-coated substrate and electroless deposition copper film was up to 13.8 MPa. The design strategy of triazinedithiolsilane molecule is expected to open up the possibilities for replacing traditional organosilane to be applied in microelectronic industry.</p> |
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institution | Directory Open Access Journal |
issn | 1931-7573 1556-276X |
language | English |
last_indexed | 2024-03-12T19:35:40Z |
publishDate | 2011-01-01 |
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series | Nanoscale Research Letters |
spelling | doaj.art-8f3c3f2fb1344c76998c225b34cc7b242023-08-02T04:12:06ZengSpringerOpenNanoscale Research Letters1931-75731556-276X2011-01-0161483Self-assembled monolayer of designed and synthesized triazinedithiolsilane molecule as interfacial adhesion enhancer for integrated circuitWang FangLi YanniWang YabinCao Zhuo<p>Abstract</p> <p>Self-assembled monolayer (SAM) with tunable surface chemistry and smooth surface provides an approach to adhesion improvement and suppressing deleterious chemical interactions. Here, we demonstrate the SAM comprising of designed and synthesized 6-(3-triethoxysilylpropyl)amino-1,3,5-triazine-2,4-dithiol molecule, which can enhance interfacial adhesion to inhibit copper diffusion used in device metallization. The formation of the triazinedithiolsilane SAM is confirmed by X-ray photoelectron spectroscopy. The adhesion strength between SAM-coated substrate and electroless deposition copper film was up to 13.8 MPa. The design strategy of triazinedithiolsilane molecule is expected to open up the possibilities for replacing traditional organosilane to be applied in microelectronic industry.</p>http://www.nanoscalereslett.com/content/6/1/483adhesioncopperdiffusion barrierself-assembled monolayersurface chemistry |
spellingShingle | Wang Fang Li Yanni Wang Yabin Cao Zhuo Self-assembled monolayer of designed and synthesized triazinedithiolsilane molecule as interfacial adhesion enhancer for integrated circuit Nanoscale Research Letters adhesion copper diffusion barrier self-assembled monolayer surface chemistry |
title | Self-assembled monolayer of designed and synthesized triazinedithiolsilane molecule as interfacial adhesion enhancer for integrated circuit |
title_full | Self-assembled monolayer of designed and synthesized triazinedithiolsilane molecule as interfacial adhesion enhancer for integrated circuit |
title_fullStr | Self-assembled monolayer of designed and synthesized triazinedithiolsilane molecule as interfacial adhesion enhancer for integrated circuit |
title_full_unstemmed | Self-assembled monolayer of designed and synthesized triazinedithiolsilane molecule as interfacial adhesion enhancer for integrated circuit |
title_short | Self-assembled monolayer of designed and synthesized triazinedithiolsilane molecule as interfacial adhesion enhancer for integrated circuit |
title_sort | self assembled monolayer of designed and synthesized triazinedithiolsilane molecule as interfacial adhesion enhancer for integrated circuit |
topic | adhesion copper diffusion barrier self-assembled monolayer surface chemistry |
url | http://www.nanoscalereslett.com/content/6/1/483 |
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