Influence of Deposition Parameters of TiO<sub>2</sub> + CuO Coating on the Membranes Surface Used in the Filtration Process of Dairy Wastewater on Their Functional Properties

A novel approach of the deposition of two-component coating consisting of TiO<sub>2</sub> and CuO on polymer membranes by MS-PVD method was presented in this work. This confirmed the possibility of using thin functional coatings for the modification of polymer membranes. The influence of...

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Main Authors: Joanna Kacprzyńska-Gołacka, Monika Łożyńska, Wioletta Barszcz, Sylwia Sowa, Piotr Wieciński, Ewa Woskowicz, Maciej Życki
Format: Article
Language:English
Published: MDPI AG 2021-04-01
Series:Membranes
Subjects:
Online Access:https://www.mdpi.com/2077-0375/11/4/290
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author Joanna Kacprzyńska-Gołacka
Monika Łożyńska
Wioletta Barszcz
Sylwia Sowa
Piotr Wieciński
Ewa Woskowicz
Maciej Życki
author_facet Joanna Kacprzyńska-Gołacka
Monika Łożyńska
Wioletta Barszcz
Sylwia Sowa
Piotr Wieciński
Ewa Woskowicz
Maciej Życki
author_sort Joanna Kacprzyńska-Gołacka
collection DOAJ
description A novel approach of the deposition of two-component coating consisting of TiO<sub>2</sub> and CuO on polymer membranes by MS-PVD method was presented in this work. This confirmed the possibility of using thin functional coatings for the modification of polymer membranes. The influence of technological parameters of the coating deposition on the membrane’s structure, chemical composition and functional properties (hydrophilic, photocatalytic and bactericidal properties) were analyzed using SEM. Model microorganism such as <i>Escherichia coli</i> and <i>Bacillus subtilis</i> have been used to check the antibacterial properties. The results indicated that doping with CuO highlights the potential of bactericidal efficiency. The surface properties of the membranes were evaluated with the surface free energy. For evaluating photocatalytic properties, the UV and visible light were used. The filtration tests showed that polymer membranes treated with two-component TiO<sub>2</sub> + CuO coatings have a permeate flux similar to the reference material (non-coated membrane). The obtained results constitute a very promising perspective of the potential application of magnetron sputtering for deposition of TiO<sub>2</sub> + CuO coatings in the prevention of biofouling resulted from the membrane filtration of dairy wastewater.
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spelling doaj.art-8f41e0961e374747865207db1c6740bd2023-11-21T15:55:09ZengMDPI AGMembranes2077-03752021-04-0111429010.3390/membranes11040290Influence of Deposition Parameters of TiO<sub>2</sub> + CuO Coating on the Membranes Surface Used in the Filtration Process of Dairy Wastewater on Their Functional PropertiesJoanna Kacprzyńska-Gołacka0Monika Łożyńska1Wioletta Barszcz2Sylwia Sowa3Piotr Wieciński4Ewa Woskowicz5Maciej Życki6Łukasiewicz Research Network—Institute for Sustainable Technology, 6/10 Pułaskiego St., 26-600 Radom, PolandŁukasiewicz Research Network—Institute for Sustainable Technology, 6/10 Pułaskiego St., 26-600 Radom, PolandŁukasiewicz Research Network—Institute for Sustainable Technology, 6/10 Pułaskiego St., 26-600 Radom, PolandŁukasiewicz Research Network—Institute for Sustainable Technology, 6/10 Pułaskiego St., 26-600 Radom, PolandFaculty of Chemistry, Warsaw University of Technology, 3 Noakowskiego St., 00-664 Warsaw, PolandŁukasiewicz Research Network—Institute for Sustainable Technology, 6/10 Pułaskiego St., 26-600 Radom, PolandŁukasiewicz Research Network—Institute for Sustainable Technology, 6/10 Pułaskiego St., 26-600 Radom, PolandA novel approach of the deposition of two-component coating consisting of TiO<sub>2</sub> and CuO on polymer membranes by MS-PVD method was presented in this work. This confirmed the possibility of using thin functional coatings for the modification of polymer membranes. The influence of technological parameters of the coating deposition on the membrane’s structure, chemical composition and functional properties (hydrophilic, photocatalytic and bactericidal properties) were analyzed using SEM. Model microorganism such as <i>Escherichia coli</i> and <i>Bacillus subtilis</i> have been used to check the antibacterial properties. The results indicated that doping with CuO highlights the potential of bactericidal efficiency. The surface properties of the membranes were evaluated with the surface free energy. For evaluating photocatalytic properties, the UV and visible light were used. The filtration tests showed that polymer membranes treated with two-component TiO<sub>2</sub> + CuO coatings have a permeate flux similar to the reference material (non-coated membrane). The obtained results constitute a very promising perspective of the potential application of magnetron sputtering for deposition of TiO<sub>2</sub> + CuO coatings in the prevention of biofouling resulted from the membrane filtration of dairy wastewater.https://www.mdpi.com/2077-0375/11/4/290polyamide membranesMS-PVD methodTiO<sub>2</sub> + CuO coatingsbactericidal and hydrophilic properties
spellingShingle Joanna Kacprzyńska-Gołacka
Monika Łożyńska
Wioletta Barszcz
Sylwia Sowa
Piotr Wieciński
Ewa Woskowicz
Maciej Życki
Influence of Deposition Parameters of TiO<sub>2</sub> + CuO Coating on the Membranes Surface Used in the Filtration Process of Dairy Wastewater on Their Functional Properties
Membranes
polyamide membranes
MS-PVD method
TiO<sub>2</sub> + CuO coatings
bactericidal and hydrophilic properties
title Influence of Deposition Parameters of TiO<sub>2</sub> + CuO Coating on the Membranes Surface Used in the Filtration Process of Dairy Wastewater on Their Functional Properties
title_full Influence of Deposition Parameters of TiO<sub>2</sub> + CuO Coating on the Membranes Surface Used in the Filtration Process of Dairy Wastewater on Their Functional Properties
title_fullStr Influence of Deposition Parameters of TiO<sub>2</sub> + CuO Coating on the Membranes Surface Used in the Filtration Process of Dairy Wastewater on Their Functional Properties
title_full_unstemmed Influence of Deposition Parameters of TiO<sub>2</sub> + CuO Coating on the Membranes Surface Used in the Filtration Process of Dairy Wastewater on Their Functional Properties
title_short Influence of Deposition Parameters of TiO<sub>2</sub> + CuO Coating on the Membranes Surface Used in the Filtration Process of Dairy Wastewater on Their Functional Properties
title_sort influence of deposition parameters of tio sub 2 sub cuo coating on the membranes surface used in the filtration process of dairy wastewater on their functional properties
topic polyamide membranes
MS-PVD method
TiO<sub>2</sub> + CuO coatings
bactericidal and hydrophilic properties
url https://www.mdpi.com/2077-0375/11/4/290
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