Diguanidinium bis(μ-2-hydroxypropane-1,2,3-tricarboxylato)bis[diaquazincate(II)] dihydrate
The asymmetric unit of the title compound, (CH6N3)2[Zn2(C6H5O7)2(H2O)2]·2H2O, contains one-half of a centrosymmetric dizinc(II) complex anion, one guanidinium cation and one water molecule. Each ZnII ion is hexacoordinated by two citrate anions, one in a bidentate fashion and the second...
| Main Authors: | , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010-02-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809054439 |
| _version_ | 1819277990010290176 |
|---|---|
| author | Mohammad T. M. Al-Dajani Hassan H. Abdallah Nornisah Mohamed Chin Sing Yeap Hoong-Kun Fun |
| author_facet | Mohammad T. M. Al-Dajani Hassan H. Abdallah Nornisah Mohamed Chin Sing Yeap Hoong-Kun Fun |
| author_sort | Mohammad T. M. Al-Dajani |
| collection | DOAJ |
| description | The asymmetric unit of the title compound, (CH6N3)2[Zn2(C6H5O7)2(H2O)2]·2H2O, contains one-half of a centrosymmetric dizinc(II) complex anion, one guanidinium cation and one water molecule. Each ZnII ion is hexacoordinated by two citrate anions, one in a bidentate fashion and the second monodentate, and two water molecules in a distorted octahedral geometry. Intramolecular O—H...O hydrogen bonds add further stability to the molecular structure. In the crystal structure, molecules are linked into a three-dimensional framework by intermolecular N—H...O, O—H...O and C—H...O hydrogen bonds. |
| first_indexed | 2024-12-24T00:04:53Z |
| format | Article |
| id | doaj.art-8f45111d92594e6d835583f6251ee297 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T00:04:53Z |
| publishDate | 2010-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-8f45111d92594e6d835583f6251ee2972022-12-21T17:25:02ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-02-01662m109m11010.1107/S1600536809054439Diguanidinium bis(μ-2-hydroxypropane-1,2,3-tricarboxylato)bis[diaquazincate(II)] dihydrateMohammad T. M. Al-DajaniHassan H. AbdallahNornisah MohamedChin Sing YeapHoong-Kun FunThe asymmetric unit of the title compound, (CH6N3)2[Zn2(C6H5O7)2(H2O)2]·2H2O, contains one-half of a centrosymmetric dizinc(II) complex anion, one guanidinium cation and one water molecule. Each ZnII ion is hexacoordinated by two citrate anions, one in a bidentate fashion and the second monodentate, and two water molecules in a distorted octahedral geometry. Intramolecular O—H...O hydrogen bonds add further stability to the molecular structure. In the crystal structure, molecules are linked into a three-dimensional framework by intermolecular N—H...O, O—H...O and C—H...O hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S1600536809054439 |
| spellingShingle | Mohammad T. M. Al-Dajani Hassan H. Abdallah Nornisah Mohamed Chin Sing Yeap Hoong-Kun Fun Diguanidinium bis(μ-2-hydroxypropane-1,2,3-tricarboxylato)bis[diaquazincate(II)] dihydrate Acta Crystallographica Section E |
| title | Diguanidinium bis(μ-2-hydroxypropane-1,2,3-tricarboxylato)bis[diaquazincate(II)] dihydrate |
| title_full | Diguanidinium bis(μ-2-hydroxypropane-1,2,3-tricarboxylato)bis[diaquazincate(II)] dihydrate |
| title_fullStr | Diguanidinium bis(μ-2-hydroxypropane-1,2,3-tricarboxylato)bis[diaquazincate(II)] dihydrate |
| title_full_unstemmed | Diguanidinium bis(μ-2-hydroxypropane-1,2,3-tricarboxylato)bis[diaquazincate(II)] dihydrate |
| title_short | Diguanidinium bis(μ-2-hydroxypropane-1,2,3-tricarboxylato)bis[diaquazincate(II)] dihydrate |
| title_sort | diguanidinium bis amp 956 2 hydroxypropane 1 2 3 tricarboxylato bis diaquazincate ii dihydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809054439 |
| work_keys_str_mv | AT mohammadtmaldajani diguanidiniumbisamp9562hydroxypropane123tricarboxylatobisdiaquazincateiidihydrate AT hassanhabdallah diguanidiniumbisamp9562hydroxypropane123tricarboxylatobisdiaquazincateiidihydrate AT nornisahmohamed diguanidiniumbisamp9562hydroxypropane123tricarboxylatobisdiaquazincateiidihydrate AT chinsingyeap diguanidiniumbisamp9562hydroxypropane123tricarboxylatobisdiaquazincateiidihydrate AT hoongkunfun diguanidiniumbisamp9562hydroxypropane123tricarboxylatobisdiaquazincateiidihydrate |