(4,4′-Dimethyl-2,2′-bipyridine-κ2N,N′)(dimethyl sulfoxide-κO)diiodidozinc(II)
In the title compound, [ZnI2(C12H12N2)(C2H6OS)], the ZnII ion is coordinated by two N atoms from a 4,4′-dimethyl-2,2′-bipyridine ligand, one O atom from a dimethyl sulfoxide molecule and two I atoms in a distorted trigonal-bipyramidal geometry. Intramolecular C&#8...
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Format: | Article |
Language: | English |
Published: |
International Union of Crystallography
2010-12-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810046763 |
Summary: | In the title compound, [ZnI2(C12H12N2)(C2H6OS)], the ZnII ion is coordinated by two N atoms from a 4,4′-dimethyl-2,2′-bipyridine ligand, one O atom from a dimethyl sulfoxide molecule and two I atoms in a distorted trigonal-bipyramidal geometry. Intramolecular C—H...O hydrogen bonds and intermolecular π–π stacking interactions between the pyridine rings [centroid–centroid distances = 3.637 (4) and 3.818 (4) Å] are present in the crystal structure. |
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ISSN: | 1600-5368 |