Potential Thermoelectric Performance from Optimization of Hole-Doped Bi_{2}Se_{3}

We present an analysis of the potential thermoelectric performance of hole-doped Bi_{2}Se_{3}, which is commonly considered to show inferior room temperature performance when compared to Bi_{2}Te_{3}. We find that if the lattice thermal conductivity can be reduced by nanostructuring techniques (as h...

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Main Authors: David Parker, David J. Singh
Format: Article
Language:English
Published: American Physical Society 2011-10-01
Series:Physical Review X
Online Access:http://doi.org/10.1103/PhysRevX.1.021005
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author David Parker
David J. Singh
author_facet David Parker
David J. Singh
author_sort David Parker
collection DOAJ
description We present an analysis of the potential thermoelectric performance of hole-doped Bi_{2}Se_{3}, which is commonly considered to show inferior room temperature performance when compared to Bi_{2}Te_{3}. We find that if the lattice thermal conductivity can be reduced by nanostructuring techniques (as have been applied to Bi_{2}Te_{3} in Refs. [W. Xie, X. Tang, Y. Yan, Q. Zhang, and T. M. Tritt, Unique Nanostructures and Enhanced Thermoelectric Performance of Melt-Spun BiSbTe Alloys, Appl. Phys. Lett. 94, 102111 (2009); APPLAB0003-695110.1063/1.3097026B. Poudel et al., High-Thermoelectric Performance of Nanostructured Bismuth Antimony Telluride Bulk Alloys, Science 320, 634 (2008).SCIEAS0036-807510.1126/science.1156446]) the material may show optimized ZT values of unity or more in the 300–500 K temperature range and thus be suitable for cooling and moderate temperature waste heat recovery and thermoelectric solar cell applications. Central to this conclusion are the larger band gap and the relatively heavier valence bands of Bi_{2}Se_{3}.
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spelling doaj.art-8f571a36b5d5479c999c2f7e58ec09ed2022-12-21T19:28:29ZengAmerican Physical SocietyPhysical Review X2160-33082011-10-011202100510.1103/PhysRevX.1.021005Potential Thermoelectric Performance from Optimization of Hole-Doped Bi_{2}Se_{3}David ParkerDavid J. SinghWe present an analysis of the potential thermoelectric performance of hole-doped Bi_{2}Se_{3}, which is commonly considered to show inferior room temperature performance when compared to Bi_{2}Te_{3}. We find that if the lattice thermal conductivity can be reduced by nanostructuring techniques (as have been applied to Bi_{2}Te_{3} in Refs. [W. Xie, X. Tang, Y. Yan, Q. Zhang, and T. M. Tritt, Unique Nanostructures and Enhanced Thermoelectric Performance of Melt-Spun BiSbTe Alloys, Appl. Phys. Lett. 94, 102111 (2009); APPLAB0003-695110.1063/1.3097026B. Poudel et al., High-Thermoelectric Performance of Nanostructured Bismuth Antimony Telluride Bulk Alloys, Science 320, 634 (2008).SCIEAS0036-807510.1126/science.1156446]) the material may show optimized ZT values of unity or more in the 300–500 K temperature range and thus be suitable for cooling and moderate temperature waste heat recovery and thermoelectric solar cell applications. Central to this conclusion are the larger band gap and the relatively heavier valence bands of Bi_{2}Se_{3}.http://doi.org/10.1103/PhysRevX.1.021005
spellingShingle David Parker
David J. Singh
Potential Thermoelectric Performance from Optimization of Hole-Doped Bi_{2}Se_{3}
Physical Review X
title Potential Thermoelectric Performance from Optimization of Hole-Doped Bi_{2}Se_{3}
title_full Potential Thermoelectric Performance from Optimization of Hole-Doped Bi_{2}Se_{3}
title_fullStr Potential Thermoelectric Performance from Optimization of Hole-Doped Bi_{2}Se_{3}
title_full_unstemmed Potential Thermoelectric Performance from Optimization of Hole-Doped Bi_{2}Se_{3}
title_short Potential Thermoelectric Performance from Optimization of Hole-Doped Bi_{2}Se_{3}
title_sort potential thermoelectric performance from optimization of hole doped bi 2 se 3
url http://doi.org/10.1103/PhysRevX.1.021005
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