| Summary: | Adverse side-effects occurred in slurry foaming and thickening process when carbide slag was substituted for quicklime in HCS-AAC. Cement accelerators were introduced to modify the slurry foaming and coagulating process during pre-curing. Meanwhile, the affiliated effects on the physical-mechanical properties and hydration products were discussed to evaluate the applicability and influence of the cement accelerator. The hydration products were characterized by mineralogical (XRD) and thermal analysis (DSC-TG). The results indicated that substituting carbide slag for quicklime retarded slurry foaming and curing progress; meanwhile, the induced mechanical property declination had a negative effect on the generation of C–S–H (I) and tobermorite. Na<sub>2</sub>SO<sub>4</sub> and Na<sub>2</sub>O·2.0SiO<sub>2</sub> can effectively accelerate the slurry foaming rate, but the promoting effect on slurry thickening was inconspicuous. The compressive strength of HCS-AAC obviously declined with increasing cement coagulant content, which was mainly ascribed to the decrease in bulk density caused by the accelerating effect on the slurry foaming process. Dosing Na<sub>2</sub>SO<sub>4</sub> under 0.4% has little effect on the generation of strength contributing to hydration products while the addition of Na<sub>2</sub>O·2.0SiO<sub>2</sub> can accelerate the generation and crystallization of C–S–H, which contributed to the high activity gelatinous SiO<sub>2</sub> generated from the reaction between Na<sub>2</sub>O·2.0SiO<sub>2</sub> and Ca(OH)<sub>2</sub>.
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