Process Simulation and Life Cycle Assessment of Dilute Sodium Hydroxide Pretreatment of Wheat Straw

Wheat straw is an abundant lignocellulosic residue from wheat cultivation. It is composed of cellulose, hemicellulose, and lignin and offers several possibilities for valorisation. Nowadays, a growing interest in lignocellulosic biomass fractionation and lignin utilisation is observed. Alkaline pret...

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Main Authors: Diana Dimande, Walter Wukovits, Daniel Koch, Bettina Mihalyi-Schneider, Anton Friedl
Format: Article
Language:English
Published: AIDIC Servizi S.r.l. 2022-09-01
Series:Chemical Engineering Transactions
Online Access:https://www.cetjournal.it/index.php/cet/article/view/12651
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author Diana Dimande
Walter Wukovits
Daniel Koch
Bettina Mihalyi-Schneider
Anton Friedl
author_facet Diana Dimande
Walter Wukovits
Daniel Koch
Bettina Mihalyi-Schneider
Anton Friedl
author_sort Diana Dimande
collection DOAJ
description Wheat straw is an abundant lignocellulosic residue from wheat cultivation. It is composed of cellulose, hemicellulose, and lignin and offers several possibilities for valorisation. Nowadays, a growing interest in lignocellulosic biomass fractionation and lignin utilisation is observed. Alkaline pretreatment with NaOH is often applied to obtain a high-quality lignin fraction under milder conditions. In this study, alkaline pretreatment of wheat straw using a NaOH solution is simulated in Aspen Plus to determine mass and energy balances producing a lignin fraction. These balances were used as input to perform a life cycle assessment to screen and estimate the environmental impacts underlying 12 different scenarios. According to the impact assessment results, pretreatment with 2 % NaOH solution, reactor temperature 105 ºC, and solid biomass as the thermal energy source, as described in the base case, is the best compromise between low Global Warming, Eutrophication, Human Toxicity potentials, Blue Water Consumption, and resource efficiency.
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spelling doaj.art-8fbcab025b56492fbab828c238a651e82022-12-22T04:04:58ZengAIDIC Servizi S.r.l.Chemical Engineering Transactions2283-92162022-09-019410.3303/CET2294094Process Simulation and Life Cycle Assessment of Dilute Sodium Hydroxide Pretreatment of Wheat StrawDiana DimandeWalter WukovitsDaniel KochBettina Mihalyi-SchneiderAnton FriedlWheat straw is an abundant lignocellulosic residue from wheat cultivation. It is composed of cellulose, hemicellulose, and lignin and offers several possibilities for valorisation. Nowadays, a growing interest in lignocellulosic biomass fractionation and lignin utilisation is observed. Alkaline pretreatment with NaOH is often applied to obtain a high-quality lignin fraction under milder conditions. In this study, alkaline pretreatment of wheat straw using a NaOH solution is simulated in Aspen Plus to determine mass and energy balances producing a lignin fraction. These balances were used as input to perform a life cycle assessment to screen and estimate the environmental impacts underlying 12 different scenarios. According to the impact assessment results, pretreatment with 2 % NaOH solution, reactor temperature 105 ºC, and solid biomass as the thermal energy source, as described in the base case, is the best compromise between low Global Warming, Eutrophication, Human Toxicity potentials, Blue Water Consumption, and resource efficiency.https://www.cetjournal.it/index.php/cet/article/view/12651
spellingShingle Diana Dimande
Walter Wukovits
Daniel Koch
Bettina Mihalyi-Schneider
Anton Friedl
Process Simulation and Life Cycle Assessment of Dilute Sodium Hydroxide Pretreatment of Wheat Straw
Chemical Engineering Transactions
title Process Simulation and Life Cycle Assessment of Dilute Sodium Hydroxide Pretreatment of Wheat Straw
title_full Process Simulation and Life Cycle Assessment of Dilute Sodium Hydroxide Pretreatment of Wheat Straw
title_fullStr Process Simulation and Life Cycle Assessment of Dilute Sodium Hydroxide Pretreatment of Wheat Straw
title_full_unstemmed Process Simulation and Life Cycle Assessment of Dilute Sodium Hydroxide Pretreatment of Wheat Straw
title_short Process Simulation and Life Cycle Assessment of Dilute Sodium Hydroxide Pretreatment of Wheat Straw
title_sort process simulation and life cycle assessment of dilute sodium hydroxide pretreatment of wheat straw
url https://www.cetjournal.it/index.php/cet/article/view/12651
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