Crystal Crosslinked Gels for the Deposition of Inorganic Salts with Polyhedral Shapes
Biomineralization has been given a great deal of attention by materials chemists because of its low environmental load and sustainability. With the goal of synthesizing such processes, various methods have been developed, especially for inorganic salts of calcium. In this report, we focused on the d...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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MDPI AG
2018-02-01
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| Series: | Gels |
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| Online Access: | http://www.mdpi.com/2310-2861/4/1/16 |
| _version_ | 1819296212490125312 |
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| author | Yumi Mochizuki Chihiro Oka Takumi Ishiwata Kenta Kokado Kazuki Sada |
| author_facet | Yumi Mochizuki Chihiro Oka Takumi Ishiwata Kenta Kokado Kazuki Sada |
| author_sort | Yumi Mochizuki |
| collection | DOAJ |
| description | Biomineralization has been given a great deal of attention by materials chemists because of its low environmental load and sustainability. With the goal of synthesizing such processes, various methods have been developed, especially for inorganic salts of calcium. In this report, we focused on the deposition of inorganic salts, such as calcium carbonate and calcium phosphate using crystal crosslinked gels (CCG), which are prepared by crystal crosslinking of metal-organic frameworks (MOFs). Due to the crystalline nature of MOFs, CCGs intrinsically possess polyhedral shapes derived from the original MOF crystals. As the result of deposition, the obtained inorganic salts also exhibited a polyhedral shape derived from the CCG. The deposition mainly occurred near the surface of the CCG, and the amorphous nature of the deposited inorganic salts was also confirmed. |
| first_indexed | 2024-12-24T04:54:31Z |
| format | Article |
| id | doaj.art-8fbdfdd51f424327a807848be726b1cc |
| institution | Directory Open Access Journal |
| issn | 2310-2861 |
| language | English |
| last_indexed | 2024-12-24T04:54:31Z |
| publishDate | 2018-02-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Gels |
| spelling | doaj.art-8fbdfdd51f424327a807848be726b1cc2022-12-21T17:14:26ZengMDPI AGGels2310-28612018-02-01411610.3390/gels4010016gels4010016Crystal Crosslinked Gels for the Deposition of Inorganic Salts with Polyhedral ShapesYumi Mochizuki0Chihiro Oka1Takumi Ishiwata2Kenta Kokado3Kazuki Sada4Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-0810, JapanGraduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-0810, JapanGraduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-0810, JapanGraduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-0810, JapanGraduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-0810, JapanBiomineralization has been given a great deal of attention by materials chemists because of its low environmental load and sustainability. With the goal of synthesizing such processes, various methods have been developed, especially for inorganic salts of calcium. In this report, we focused on the deposition of inorganic salts, such as calcium carbonate and calcium phosphate using crystal crosslinked gels (CCG), which are prepared by crystal crosslinking of metal-organic frameworks (MOFs). Due to the crystalline nature of MOFs, CCGs intrinsically possess polyhedral shapes derived from the original MOF crystals. As the result of deposition, the obtained inorganic salts also exhibited a polyhedral shape derived from the CCG. The deposition mainly occurred near the surface of the CCG, and the amorphous nature of the deposited inorganic salts was also confirmed.http://www.mdpi.com/2310-2861/4/1/16biomineralizationcalcium carbonatecalcium phosphatemetal-organic frameworkcrystal crosslinking |
| spellingShingle | Yumi Mochizuki Chihiro Oka Takumi Ishiwata Kenta Kokado Kazuki Sada Crystal Crosslinked Gels for the Deposition of Inorganic Salts with Polyhedral Shapes Gels biomineralization calcium carbonate calcium phosphate metal-organic framework crystal crosslinking |
| title | Crystal Crosslinked Gels for the Deposition of Inorganic Salts with Polyhedral Shapes |
| title_full | Crystal Crosslinked Gels for the Deposition of Inorganic Salts with Polyhedral Shapes |
| title_fullStr | Crystal Crosslinked Gels for the Deposition of Inorganic Salts with Polyhedral Shapes |
| title_full_unstemmed | Crystal Crosslinked Gels for the Deposition of Inorganic Salts with Polyhedral Shapes |
| title_short | Crystal Crosslinked Gels for the Deposition of Inorganic Salts with Polyhedral Shapes |
| title_sort | crystal crosslinked gels for the deposition of inorganic salts with polyhedral shapes |
| topic | biomineralization calcium carbonate calcium phosphate metal-organic framework crystal crosslinking |
| url | http://www.mdpi.com/2310-2861/4/1/16 |
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