Synthesis and Luminescence Properties of the Binary/Ternary Complex of Samarium Ion with Phenacylmethyl P-Tolyl Sulfoxide and Benzoic Acid
A new ligand phenacylmethyl p-tolyl sulfoxide (denoted as L1) has been synthesized by an asymmetric synthesis method. Its novel binary complex Sm(L1)7·(ClO4)3·6H2O, and ternary complex Sm(L1)6·(L2)·(ClO4)2·6H2O (benzoic acid denoted as L2) have been synthesized. The structure and composition of the...
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| Format: | Article |
| Language: | English |
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EDP Sciences
2018-01-01
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| Series: | MATEC Web of Conferences |
| Online Access: | https://doi.org/10.1051/matecconf/201714201010 |
| _version_ | 1818368888525553664 |
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| author | Yang Kui-Suo Li Wen-Xian Bao Jin-Rong |
| author_facet | Yang Kui-Suo Li Wen-Xian Bao Jin-Rong |
| author_sort | Yang Kui-Suo |
| collection | DOAJ |
| description | A new ligand phenacylmethyl p-tolyl sulfoxide (denoted as L1) has been synthesized by an asymmetric synthesis method. Its novel binary complex Sm(L1)7·(ClO4)3·6H2O, and ternary complex Sm(L1)6·(L2)·(ClO4)2·6H2O (benzoic acid denoted as L2) have been synthesized. The structure and composition of the samarium complexes characterized by elemental analysis, molar conductivity, IR, UV, and 1HNMR. Additionally, fluorescence spectra measurements shows that the complexes display stronger fluorescence intensity in solid state, indicating the ligands could efficiently transfer the energy to Sm3+ ions in the complexes. The ternary complex has stronger fluorescence intensity than the binary complex. |
| first_indexed | 2024-12-13T23:15:06Z |
| format | Article |
| id | doaj.art-8fc67a5c053d440eb6ce2d8580b15a93 |
| institution | Directory Open Access Journal |
| issn | 2261-236X |
| language | English |
| last_indexed | 2024-12-13T23:15:06Z |
| publishDate | 2018-01-01 |
| publisher | EDP Sciences |
| record_format | Article |
| series | MATEC Web of Conferences |
| spelling | doaj.art-8fc67a5c053d440eb6ce2d8580b15a932022-12-21T23:27:58ZengEDP SciencesMATEC Web of Conferences2261-236X2018-01-011420101010.1051/matecconf/201714201010matecconf_icmae2017_01010Synthesis and Luminescence Properties of the Binary/Ternary Complex of Samarium Ion with Phenacylmethyl P-Tolyl Sulfoxide and Benzoic AcidYang Kui-SuoLi Wen-XianBao Jin-RongA new ligand phenacylmethyl p-tolyl sulfoxide (denoted as L1) has been synthesized by an asymmetric synthesis method. Its novel binary complex Sm(L1)7·(ClO4)3·6H2O, and ternary complex Sm(L1)6·(L2)·(ClO4)2·6H2O (benzoic acid denoted as L2) have been synthesized. The structure and composition of the samarium complexes characterized by elemental analysis, molar conductivity, IR, UV, and 1HNMR. Additionally, fluorescence spectra measurements shows that the complexes display stronger fluorescence intensity in solid state, indicating the ligands could efficiently transfer the energy to Sm3+ ions in the complexes. The ternary complex has stronger fluorescence intensity than the binary complex.https://doi.org/10.1051/matecconf/201714201010 |
| spellingShingle | Yang Kui-Suo Li Wen-Xian Bao Jin-Rong Synthesis and Luminescence Properties of the Binary/Ternary Complex of Samarium Ion with Phenacylmethyl P-Tolyl Sulfoxide and Benzoic Acid MATEC Web of Conferences |
| title | Synthesis and Luminescence Properties of the Binary/Ternary Complex of Samarium Ion with Phenacylmethyl P-Tolyl Sulfoxide and Benzoic Acid |
| title_full | Synthesis and Luminescence Properties of the Binary/Ternary Complex of Samarium Ion with Phenacylmethyl P-Tolyl Sulfoxide and Benzoic Acid |
| title_fullStr | Synthesis and Luminescence Properties of the Binary/Ternary Complex of Samarium Ion with Phenacylmethyl P-Tolyl Sulfoxide and Benzoic Acid |
| title_full_unstemmed | Synthesis and Luminescence Properties of the Binary/Ternary Complex of Samarium Ion with Phenacylmethyl P-Tolyl Sulfoxide and Benzoic Acid |
| title_short | Synthesis and Luminescence Properties of the Binary/Ternary Complex of Samarium Ion with Phenacylmethyl P-Tolyl Sulfoxide and Benzoic Acid |
| title_sort | synthesis and luminescence properties of the binary ternary complex of samarium ion with phenacylmethyl p tolyl sulfoxide and benzoic acid |
| url | https://doi.org/10.1051/matecconf/201714201010 |
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