Diffusion Dialysis for Acid Recovery from Acidic Waste Solutions: Anion Exchange Membranes and Technology Integration

Inorganic acids are commonly used in mining, metallurgical, metal-processing, and nuclear-fuel-reprocessing industries in various processes, such as leaching, etching, electroplating, and metal-refining. Large amounts of spent acidic liquids containing toxic metal ion complexes are produced during t...

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Main Authors: Chengyi Zhang, Wen Zhang, Yuxin Wang
Format: Article
Language:English
Published: MDPI AG 2020-07-01
Series:Membranes
Subjects:
Online Access:https://www.mdpi.com/2077-0375/10/8/169
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author Chengyi Zhang
Wen Zhang
Yuxin Wang
author_facet Chengyi Zhang
Wen Zhang
Yuxin Wang
author_sort Chengyi Zhang
collection DOAJ
description Inorganic acids are commonly used in mining, metallurgical, metal-processing, and nuclear-fuel-reprocessing industries in various processes, such as leaching, etching, electroplating, and metal-refining. Large amounts of spent acidic liquids containing toxic metal ion complexes are produced during these operations, which pose a serious hazard to the living and non-living environment. Developing economic and eco-friendly regeneration approaches to recover acid and valuable metals from these industrial effluents has focused the interest of the research community. Diffusion dialysis (DD) using anion exchange membranes (AEMs) driven by an activity gradient is considered an effective technology with a low energy consumption and little environmental contamination. In addition, the properties of AEMs have an important effect on the DD process. Hence, this paper gives a critical review of the properties of AEMs, including their acid permeability, membrane stability, and acid selectivity during the DD process for acid recovery. Furthermore, the DD processes using AEMs integrated with various technologies, such as pressure, an electric field, or continuous operation are discussed to enhance its potential for industrial applications. Finally, some directions are provided for the further development of AEMs in DD for acid recovery from acidic waste solutions.
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spelling doaj.art-8fc9fbc9f98c44a7befceab96b3305172023-11-20T08:22:20ZengMDPI AGMembranes2077-03752020-07-0110816910.3390/membranes10080169Diffusion Dialysis for Acid Recovery from Acidic Waste Solutions: Anion Exchange Membranes and Technology IntegrationChengyi Zhang0Wen Zhang1Yuxin Wang2State Key Laboratory of Chemical Engineering, Tianjin Key Laboratory of Membrane Science & Desalination Technology, and School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, ChinaState Key Laboratory of Chemical Engineering, Tianjin Key Laboratory of Membrane Science & Desalination Technology, and School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, ChinaState Key Laboratory of Chemical Engineering, Tianjin Key Laboratory of Membrane Science & Desalination Technology, and School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, ChinaInorganic acids are commonly used in mining, metallurgical, metal-processing, and nuclear-fuel-reprocessing industries in various processes, such as leaching, etching, electroplating, and metal-refining. Large amounts of spent acidic liquids containing toxic metal ion complexes are produced during these operations, which pose a serious hazard to the living and non-living environment. Developing economic and eco-friendly regeneration approaches to recover acid and valuable metals from these industrial effluents has focused the interest of the research community. Diffusion dialysis (DD) using anion exchange membranes (AEMs) driven by an activity gradient is considered an effective technology with a low energy consumption and little environmental contamination. In addition, the properties of AEMs have an important effect on the DD process. Hence, this paper gives a critical review of the properties of AEMs, including their acid permeability, membrane stability, and acid selectivity during the DD process for acid recovery. Furthermore, the DD processes using AEMs integrated with various technologies, such as pressure, an electric field, or continuous operation are discussed to enhance its potential for industrial applications. Finally, some directions are provided for the further development of AEMs in DD for acid recovery from acidic waste solutions.https://www.mdpi.com/2077-0375/10/8/169diffusion dialysisanion exchange membraneacid recovery
spellingShingle Chengyi Zhang
Wen Zhang
Yuxin Wang
Diffusion Dialysis for Acid Recovery from Acidic Waste Solutions: Anion Exchange Membranes and Technology Integration
Membranes
diffusion dialysis
anion exchange membrane
acid recovery
title Diffusion Dialysis for Acid Recovery from Acidic Waste Solutions: Anion Exchange Membranes and Technology Integration
title_full Diffusion Dialysis for Acid Recovery from Acidic Waste Solutions: Anion Exchange Membranes and Technology Integration
title_fullStr Diffusion Dialysis for Acid Recovery from Acidic Waste Solutions: Anion Exchange Membranes and Technology Integration
title_full_unstemmed Diffusion Dialysis for Acid Recovery from Acidic Waste Solutions: Anion Exchange Membranes and Technology Integration
title_short Diffusion Dialysis for Acid Recovery from Acidic Waste Solutions: Anion Exchange Membranes and Technology Integration
title_sort diffusion dialysis for acid recovery from acidic waste solutions anion exchange membranes and technology integration
topic diffusion dialysis
anion exchange membrane
acid recovery
url https://www.mdpi.com/2077-0375/10/8/169
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AT yuxinwang diffusiondialysisforacidrecoveryfromacidicwastesolutionsanionexchangemembranesandtechnologyintegration