The Curing Rheokinetics of Epoxyphosphazene Binders
The influence of epoxyphosphazene-modifying additives on the features of the hot curing process of epoxy-amine composition was studied by the rotational viscometry method. The modification caused an acceleration of the curing process, changed rheokinetics of viscosity increase, especially the stage...
| Main Authors: | , , , , , , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2020-12-01
|
| Series: | Materials |
| Subjects: | |
| Online Access: | https://www.mdpi.com/1996-1944/13/24/5685 |
| _version_ | 1797544893573234688 |
|---|---|
| author | Natalia V. Bornosuz Irina Yu. Gorbunova Vyacheslav V. Kireev Denis V. Onuchin Mikhail L. Kerber Viktoria V. Petrakova Ivan A. Kryuchkov Roman E. Nevskiy Alexey V. Sokovishin Venera V. Khammatova Igor S. Sirotin |
| author_facet | Natalia V. Bornosuz Irina Yu. Gorbunova Vyacheslav V. Kireev Denis V. Onuchin Mikhail L. Kerber Viktoria V. Petrakova Ivan A. Kryuchkov Roman E. Nevskiy Alexey V. Sokovishin Venera V. Khammatova Igor S. Sirotin |
| author_sort | Natalia V. Bornosuz |
| collection | DOAJ |
| description | The influence of epoxyphosphazene-modifying additives on the features of the hot curing process of epoxy-amine composition was studied by the rotational viscometry method. The modification caused an acceleration of the curing process, changed rheokinetics of viscosity increase, especially the stage molecular mass growth of linear chains became almost twice shorter for composition with 30% modifier than for unmodified one. We suggest the reason for these changes is the polyfunctionality of epoxyphosphazene, which finally results in high-density network formation. In cold curing process the bulkiness of epoxyphosphazene molecule and the lack of heat for its motion results in incomplete cure. Thus, in order to cope with these difficulties hot curing systems were proposed and studied. |
| first_indexed | 2024-03-10T14:07:01Z |
| format | Article |
| id | doaj.art-8fd89f64821a4607ad53b3f6535cac7c |
| institution | Directory Open Access Journal |
| issn | 1996-1944 |
| language | English |
| last_indexed | 2024-03-10T14:07:01Z |
| publishDate | 2020-12-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Materials |
| spelling | doaj.art-8fd89f64821a4607ad53b3f6535cac7c2023-11-21T00:33:15ZengMDPI AGMaterials1996-19442020-12-011324568510.3390/ma13245685The Curing Rheokinetics of Epoxyphosphazene BindersNatalia V. Bornosuz0Irina Yu. Gorbunova1Vyacheslav V. Kireev2Denis V. Onuchin3Mikhail L. Kerber4Viktoria V. Petrakova5Ivan A. Kryuchkov6Roman E. Nevskiy7Alexey V. Sokovishin8Venera V. Khammatova9Igor S. Sirotin10Faculty of Petrochemistry and Polymer Materials, Mendeleev University of Chemical Technology, 125047 Moscow, RussiaFaculty of Petrochemistry and Polymer Materials, Mendeleev University of Chemical Technology, 125047 Moscow, RussiaFaculty of Petrochemistry and Polymer Materials, Mendeleev University of Chemical Technology, 125047 Moscow, RussiaFaculty of Petrochemistry and Polymer Materials, Mendeleev University of Chemical Technology, 125047 Moscow, RussiaFaculty of Petrochemistry and Polymer Materials, Mendeleev University of Chemical Technology, 125047 Moscow, RussiaFaculty of Petrochemistry and Polymer Materials, Mendeleev University of Chemical Technology, 125047 Moscow, RussiaDivision of Materials Science, Dukhov Automatics Research Institute (VNIIA), 125047 Moscow, RussiaDivision of Materials Science, Dukhov Automatics Research Institute (VNIIA), 125047 Moscow, RussiaDivision of Materials Science, Dukhov Automatics Research Institute (VNIIA), 125047 Moscow, RussiaDesign Department, Kazan National Research Technological University, 420111 Tatarstan, RussiaFaculty of Petrochemistry and Polymer Materials, Mendeleev University of Chemical Technology, 125047 Moscow, RussiaThe influence of epoxyphosphazene-modifying additives on the features of the hot curing process of epoxy-amine composition was studied by the rotational viscometry method. The modification caused an acceleration of the curing process, changed rheokinetics of viscosity increase, especially the stage molecular mass growth of linear chains became almost twice shorter for composition with 30% modifier than for unmodified one. We suggest the reason for these changes is the polyfunctionality of epoxyphosphazene, which finally results in high-density network formation. In cold curing process the bulkiness of epoxyphosphazene molecule and the lack of heat for its motion results in incomplete cure. Thus, in order to cope with these difficulties hot curing systems were proposed and studied.https://www.mdpi.com/1996-1944/13/24/5685epoxy resinsdiaminodiphenylsulfoneepoxyphosphazenesrheokinetics |
| spellingShingle | Natalia V. Bornosuz Irina Yu. Gorbunova Vyacheslav V. Kireev Denis V. Onuchin Mikhail L. Kerber Viktoria V. Petrakova Ivan A. Kryuchkov Roman E. Nevskiy Alexey V. Sokovishin Venera V. Khammatova Igor S. Sirotin The Curing Rheokinetics of Epoxyphosphazene Binders Materials epoxy resins diaminodiphenylsulfone epoxyphosphazenes rheokinetics |
| title | The Curing Rheokinetics of Epoxyphosphazene Binders |
| title_full | The Curing Rheokinetics of Epoxyphosphazene Binders |
| title_fullStr | The Curing Rheokinetics of Epoxyphosphazene Binders |
| title_full_unstemmed | The Curing Rheokinetics of Epoxyphosphazene Binders |
| title_short | The Curing Rheokinetics of Epoxyphosphazene Binders |
| title_sort | curing rheokinetics of epoxyphosphazene binders |
| topic | epoxy resins diaminodiphenylsulfone epoxyphosphazenes rheokinetics |
| url | https://www.mdpi.com/1996-1944/13/24/5685 |
| work_keys_str_mv | AT nataliavbornosuz thecuringrheokineticsofepoxyphosphazenebinders AT irinayugorbunova thecuringrheokineticsofepoxyphosphazenebinders AT vyacheslavvkireev thecuringrheokineticsofepoxyphosphazenebinders AT denisvonuchin thecuringrheokineticsofepoxyphosphazenebinders AT mikhaillkerber thecuringrheokineticsofepoxyphosphazenebinders AT viktoriavpetrakova thecuringrheokineticsofepoxyphosphazenebinders AT ivanakryuchkov thecuringrheokineticsofepoxyphosphazenebinders AT romanenevskiy thecuringrheokineticsofepoxyphosphazenebinders AT alexeyvsokovishin thecuringrheokineticsofepoxyphosphazenebinders AT veneravkhammatova thecuringrheokineticsofepoxyphosphazenebinders AT igorssirotin thecuringrheokineticsofepoxyphosphazenebinders AT nataliavbornosuz curingrheokineticsofepoxyphosphazenebinders AT irinayugorbunova curingrheokineticsofepoxyphosphazenebinders AT vyacheslavvkireev curingrheokineticsofepoxyphosphazenebinders AT denisvonuchin curingrheokineticsofepoxyphosphazenebinders AT mikhaillkerber curingrheokineticsofepoxyphosphazenebinders AT viktoriavpetrakova curingrheokineticsofepoxyphosphazenebinders AT ivanakryuchkov curingrheokineticsofepoxyphosphazenebinders AT romanenevskiy curingrheokineticsofepoxyphosphazenebinders AT alexeyvsokovishin curingrheokineticsofepoxyphosphazenebinders AT veneravkhammatova curingrheokineticsofepoxyphosphazenebinders AT igorssirotin curingrheokineticsofepoxyphosphazenebinders |