Facile synthesis of water-soluble carbon nano-onions under alkaline conditions

Carbonization of tomatoes at 240 °C using 30% (w/v) NaOH as catalyst produced carbon onions (C-onions), while solely carbon dots (C-dots) were obtained at the same temperature in the absence of the catalyst. Other natural materials, such as carrots and tree leaves (acer saccharum), under the same te...

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Main Authors: Gaber Hashem Gaber Ahmed, Rosana Badía Laíño, Josefa Angela García Calzón, Marta Elena Díaz García
Format: Article
Language:English
Published: Beilstein-Institut 2016-05-01
Series:Beilstein Journal of Nanotechnology
Subjects:
Online Access:https://doi.org/10.3762/bjnano.7.67
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author Gaber Hashem Gaber Ahmed
Rosana Badía Laíño
Josefa Angela García Calzón
Marta Elena Díaz García
author_facet Gaber Hashem Gaber Ahmed
Rosana Badía Laíño
Josefa Angela García Calzón
Marta Elena Díaz García
author_sort Gaber Hashem Gaber Ahmed
collection DOAJ
description Carbonization of tomatoes at 240 °C using 30% (w/v) NaOH as catalyst produced carbon onions (C-onions), while solely carbon dots (C-dots) were obtained at the same temperature in the absence of the catalyst. Other natural materials, such as carrots and tree leaves (acer saccharum), under the same temperature and alkaline conditions did not produce carbon onions. XRD, FTIR, HRTEM, UV–vis spectroscopy, and photoluminescence analyses were performed to characterize the as-synthesized carbon nanomaterials. Preliminary tests demonstrate a capability of the versatile materials for chemical sensing of metal ions. The high content of lycopene in tomatoes may explain the formation of C-onions in alkaline media and a possible formation mechanism for such structures was outlined.
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spelling doaj.art-8fea1f09a188403faaaa3abcf51bf38b2022-12-22T03:58:46ZengBeilstein-InstitutBeilstein Journal of Nanotechnology2190-42862016-05-017175876610.3762/bjnano.7.672190-4286-7-67Facile synthesis of water-soluble carbon nano-onions under alkaline conditionsGaber Hashem Gaber Ahmed0Rosana Badía Laíño1Josefa Angela García Calzón2Marta Elena Díaz García3Department of Physical and Analytical Chemistry, Faculty of Chemistry, University of Oviedo, c/Julián Clavería, 8. Oviedo, 33006, SpainChemistry Department, Faculty of Science, Damanhour University, Damanhour, EgyptChemistry Department, Faculty of Science, Damanhour University, Damanhour, EgyptChemistry Department, Faculty of Science, Damanhour University, Damanhour, EgyptCarbonization of tomatoes at 240 °C using 30% (w/v) NaOH as catalyst produced carbon onions (C-onions), while solely carbon dots (C-dots) were obtained at the same temperature in the absence of the catalyst. Other natural materials, such as carrots and tree leaves (acer saccharum), under the same temperature and alkaline conditions did not produce carbon onions. XRD, FTIR, HRTEM, UV–vis spectroscopy, and photoluminescence analyses were performed to characterize the as-synthesized carbon nanomaterials. Preliminary tests demonstrate a capability of the versatile materials for chemical sensing of metal ions. The high content of lycopene in tomatoes may explain the formation of C-onions in alkaline media and a possible formation mechanism for such structures was outlined.https://doi.org/10.3762/bjnano.7.67carbon dotscarbon onionsmetal-ion sensingphotoluminescencethermal carbonization
spellingShingle Gaber Hashem Gaber Ahmed
Rosana Badía Laíño
Josefa Angela García Calzón
Marta Elena Díaz García
Facile synthesis of water-soluble carbon nano-onions under alkaline conditions
Beilstein Journal of Nanotechnology
carbon dots
carbon onions
metal-ion sensing
photoluminescence
thermal carbonization
title Facile synthesis of water-soluble carbon nano-onions under alkaline conditions
title_full Facile synthesis of water-soluble carbon nano-onions under alkaline conditions
title_fullStr Facile synthesis of water-soluble carbon nano-onions under alkaline conditions
title_full_unstemmed Facile synthesis of water-soluble carbon nano-onions under alkaline conditions
title_short Facile synthesis of water-soluble carbon nano-onions under alkaline conditions
title_sort facile synthesis of water soluble carbon nano onions under alkaline conditions
topic carbon dots
carbon onions
metal-ion sensing
photoluminescence
thermal carbonization
url https://doi.org/10.3762/bjnano.7.67
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AT martaelenadiazgarcia facilesynthesisofwatersolublecarbonnanoonionsunderalkalineconditions