COMPARATIVE ANALYSIS OF THE PROPERTIES OF SODIUM NIOBATE AND SODIUM – LITHIUM NIOBATE CERAMICS

The authors studied the effect of the temperature of sodium niobate synthesis on the state of polarization in ceramic samples of pure sodium niobate and modified with lithium. A comparative study of the structure and pyroelectric properties of the obtained samples has been carried out. It is shown t...

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Main Authors: O.V. Malyshkina, K.V. Patsuev, A.I. Ivanova, M. Ali
Format: Article
Language:Russian
Published: Tver State University 2021-12-01
Series:Физико-химические аспекты изучения кластеров, наноструктур и наноматериалов
Subjects:
Online Access:https://physchemaspects.ru/2021/doi-10-26456-pcascnn-2021-13-278/?lang=en
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author O.V. Malyshkina
K.V. Patsuev
A.I. Ivanova
M. Ali
author_facet O.V. Malyshkina
K.V. Patsuev
A.I. Ivanova
M. Ali
author_sort O.V. Malyshkina
collection DOAJ
description The authors studied the effect of the temperature of sodium niobate synthesis on the state of polarization in ceramic samples of pure sodium niobate and modified with lithium. A comparative study of the structure and pyroelectric properties of the obtained samples has been carried out. It is shown that the introduction of lithium as a modifier leads to a significant change in the structure in the depth of ceramic samples based on sodium niobate. If in the depth of the pure sodium niobate samples, as well as on the surface, there are individual grains, then the central part of the sodium niobate-lithium niobate ceramics is a continuous mass in which individual grains are not observed. In all samples, except for pure sodium niobate, which was synthesized by double synthesis (the first at 650°C, the second at 700°C), the existence of a polarization gradient along the thickness of the samples was established. The gradient is directed from the side corresponding to the positive end of the polarization vector to the side corresponding to the negative end of the polarization vector.
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spelling doaj.art-901bf71e9f02416ca047ab5d1556be0b2022-12-21T21:34:29ZrusTver State UniversityФизико-химические аспекты изучения кластеров, наноструктур и наноматериалов2226-44422658-43602021-12-011327828510.26456/pcascnn/2021.13.278COMPARATIVE ANALYSIS OF THE PROPERTIES OF SODIUM NIOBATE AND SODIUM – LITHIUM NIOBATE CERAMICSO.V. Malyshkina0K.V. Patsuev1A.I. Ivanova2M. Ali3Tver State University, Tver, RussiaTver State University, Tver, RussiaTver State University, Tver, RussiaTver State University, Tver, RussiaThe authors studied the effect of the temperature of sodium niobate synthesis on the state of polarization in ceramic samples of pure sodium niobate and modified with lithium. A comparative study of the structure and pyroelectric properties of the obtained samples has been carried out. It is shown that the introduction of lithium as a modifier leads to a significant change in the structure in the depth of ceramic samples based on sodium niobate. If in the depth of the pure sodium niobate samples, as well as on the surface, there are individual grains, then the central part of the sodium niobate-lithium niobate ceramics is a continuous mass in which individual grains are not observed. In all samples, except for pure sodium niobate, which was synthesized by double synthesis (the first at 650°C, the second at 700°C), the existence of a polarization gradient along the thickness of the samples was established. The gradient is directed from the side corresponding to the positive end of the polarization vector to the side corresponding to the negative end of the polarization vector.https://physchemaspects.ru/2021/doi-10-26456-pcascnn-2021-13-278/?lang=enpiezoelectric ceramicslead-free materialspyroelectric effectspontaneous polarizationgrain structure
spellingShingle O.V. Malyshkina
K.V. Patsuev
A.I. Ivanova
M. Ali
COMPARATIVE ANALYSIS OF THE PROPERTIES OF SODIUM NIOBATE AND SODIUM – LITHIUM NIOBATE CERAMICS
Физико-химические аспекты изучения кластеров, наноструктур и наноматериалов
piezoelectric ceramics
lead-free materials
pyroelectric effect
spontaneous polarization
grain structure
title COMPARATIVE ANALYSIS OF THE PROPERTIES OF SODIUM NIOBATE AND SODIUM – LITHIUM NIOBATE CERAMICS
title_full COMPARATIVE ANALYSIS OF THE PROPERTIES OF SODIUM NIOBATE AND SODIUM – LITHIUM NIOBATE CERAMICS
title_fullStr COMPARATIVE ANALYSIS OF THE PROPERTIES OF SODIUM NIOBATE AND SODIUM – LITHIUM NIOBATE CERAMICS
title_full_unstemmed COMPARATIVE ANALYSIS OF THE PROPERTIES OF SODIUM NIOBATE AND SODIUM – LITHIUM NIOBATE CERAMICS
title_short COMPARATIVE ANALYSIS OF THE PROPERTIES OF SODIUM NIOBATE AND SODIUM – LITHIUM NIOBATE CERAMICS
title_sort comparative analysis of the properties of sodium niobate and sodium lithium niobate ceramics
topic piezoelectric ceramics
lead-free materials
pyroelectric effect
spontaneous polarization
grain structure
url https://physchemaspects.ru/2021/doi-10-26456-pcascnn-2021-13-278/?lang=en
work_keys_str_mv AT ovmalyshkina comparativeanalysisofthepropertiesofsodiumniobateandsodiumlithiumniobateceramics
AT kvpatsuev comparativeanalysisofthepropertiesofsodiumniobateandsodiumlithiumniobateceramics
AT aiivanova comparativeanalysisofthepropertiesofsodiumniobateandsodiumlithiumniobateceramics
AT mali comparativeanalysisofthepropertiesofsodiumniobateandsodiumlithiumniobateceramics