Inhibitive impacts extract of Citrus aurantium leaves of carbon steel in corrosive media

Relatively inexpensive, stable plant extract, namely Citrus aurantium leaves, was employed as highly efficient inhibitor of carbon steel corrosion by corrosive acid. The inhibition efficiency was estimated based on the weight loss method. Inhibition impacts of researched inhibitor increase with the...

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Main Authors: Rifat Mohammed Dakhil, Tayser Sumer Gaaz, Ahmed A. Al-Amiery, Abdul Amir H. Kadhum
Format: Article
Language:English
Published: Taylor & Francis Group 2018-10-01
Series:Green Chemistry Letters and Reviews
Subjects:
Online Access:http://dx.doi.org/10.1080/17518253.2018.1547796
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author Rifat Mohammed Dakhil
Tayser Sumer Gaaz
Ahmed A. Al-Amiery
Abdul Amir H. Kadhum
author_facet Rifat Mohammed Dakhil
Tayser Sumer Gaaz
Ahmed A. Al-Amiery
Abdul Amir H. Kadhum
author_sort Rifat Mohammed Dakhil
collection DOAJ
description Relatively inexpensive, stable plant extract, namely Citrus aurantium leaves, was employed as highly efficient inhibitor of carbon steel corrosion by corrosive acid. The inhibition efficiency was estimated based on the weight loss method. Inhibition impacts of researched inhibitor increase with the concentration of the plant extract increase. The inhibition efficiency depends on three factors: molecular structure, concentration, and molecular weight of the inhibitor. Inhibition efficiency of 81.2% was achieved with 20% (v/v) of the extract in 1 M hydrochloric acid during 3 h at 25°C. The effect of temperature was also investigated and activation parameters were evaluated. Inhibition adsorption characteristics were approximated by Langmuir adsorption isotherm. Chemical adsorption mechanism was proposed for the studied inhibitor from the trend of inhibition performance and temperature degree in addition to activation energy values and heat of adsorption.
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spelling doaj.art-90312bcfc625480fb9f54c7fed218b1b2022-12-22T01:42:50ZengTaylor & Francis GroupGreen Chemistry Letters and Reviews1751-82531751-71922018-10-0111455956610.1080/17518253.2018.15477961547796Inhibitive impacts extract of Citrus aurantium leaves of carbon steel in corrosive mediaRifat Mohammed Dakhil0Tayser Sumer Gaaz1Ahmed A. Al-Amiery2Abdul Amir H. Kadhum3Technical College, Basrah, Southern Technical UniversityTechnical College Al-Musaib, Al-Furat Al Awsat Technical UniversityUniversiti Kebangsaan MalaysiaUniversiti Kebangsaan MalaysiaRelatively inexpensive, stable plant extract, namely Citrus aurantium leaves, was employed as highly efficient inhibitor of carbon steel corrosion by corrosive acid. The inhibition efficiency was estimated based on the weight loss method. Inhibition impacts of researched inhibitor increase with the concentration of the plant extract increase. The inhibition efficiency depends on three factors: molecular structure, concentration, and molecular weight of the inhibitor. Inhibition efficiency of 81.2% was achieved with 20% (v/v) of the extract in 1 M hydrochloric acid during 3 h at 25°C. The effect of temperature was also investigated and activation parameters were evaluated. Inhibition adsorption characteristics were approximated by Langmuir adsorption isotherm. Chemical adsorption mechanism was proposed for the studied inhibitor from the trend of inhibition performance and temperature degree in addition to activation energy values and heat of adsorption.http://dx.doi.org/10.1080/17518253.2018.1547796Citrus aurantiumcarbon steelhydrochloric acid solutioncorrosion inhibitionadsorption
spellingShingle Rifat Mohammed Dakhil
Tayser Sumer Gaaz
Ahmed A. Al-Amiery
Abdul Amir H. Kadhum
Inhibitive impacts extract of Citrus aurantium leaves of carbon steel in corrosive media
Green Chemistry Letters and Reviews
Citrus aurantium
carbon steel
hydrochloric acid solution
corrosion inhibition
adsorption
title Inhibitive impacts extract of Citrus aurantium leaves of carbon steel in corrosive media
title_full Inhibitive impacts extract of Citrus aurantium leaves of carbon steel in corrosive media
title_fullStr Inhibitive impacts extract of Citrus aurantium leaves of carbon steel in corrosive media
title_full_unstemmed Inhibitive impacts extract of Citrus aurantium leaves of carbon steel in corrosive media
title_short Inhibitive impacts extract of Citrus aurantium leaves of carbon steel in corrosive media
title_sort inhibitive impacts extract of citrus aurantium leaves of carbon steel in corrosive media
topic Citrus aurantium
carbon steel
hydrochloric acid solution
corrosion inhibition
adsorption
url http://dx.doi.org/10.1080/17518253.2018.1547796
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