Piperidinium N-(ferrocenylcarbonyl)glycinate
The title compound, (C5H12N)[Fe(C5H5)(C8H7NO3)], resulting from neutralization of N-(ferrocenylcarbonyl)glycine with piperidine, is built up from discrete ions that assemble into sheets via the combination of conventional and weak hydrogen bonds. The key repeating unit is constituted by two piperidi...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2010-12-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810041747 |
| _version_ | 1818297770575921152 |
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| author | Petr Štěpnička Ivana Císařová Martin Zábranský |
| author_facet | Petr Štěpnička Ivana Císařová Martin Zábranský |
| author_sort | Petr Štěpnička |
| collection | DOAJ |
| description | The title compound, (C5H12N)[Fe(C5H5)(C8H7NO3)], resulting from neutralization of N-(ferrocenylcarbonyl)glycine with piperidine, is built up from discrete ions that assemble into sheets via the combination of conventional and weak hydrogen bonds. The key repeating unit is constituted by two piperidium cations and two carboxylate anions that assemble into a centrosymmetric array via conventional and bifurcated N—H...O hydrogen bonds. The aggregates thus formed are further interlinked by N—H...O interactions and supportive C—H...O contacts into layers oriented parallel to the bc plane. |
| first_indexed | 2024-12-13T04:24:43Z |
| format | Article |
| id | doaj.art-9065593cf86a4fa8a67cd54b1230df13 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T04:24:43Z |
| publishDate | 2010-12-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-9065593cf86a4fa8a67cd54b1230df132022-12-21T23:59:43ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-12-016612m1506m150710.1107/S1600536810041747Piperidinium N-(ferrocenylcarbonyl)glycinatePetr ŠtěpničkaIvana CísařováMartin ZábranskýThe title compound, (C5H12N)[Fe(C5H5)(C8H7NO3)], resulting from neutralization of N-(ferrocenylcarbonyl)glycine with piperidine, is built up from discrete ions that assemble into sheets via the combination of conventional and weak hydrogen bonds. The key repeating unit is constituted by two piperidium cations and two carboxylate anions that assemble into a centrosymmetric array via conventional and bifurcated N—H...O hydrogen bonds. The aggregates thus formed are further interlinked by N—H...O interactions and supportive C—H...O contacts into layers oriented parallel to the bc plane.http://scripts.iucr.org/cgi-bin/paper?S1600536810041747 |
| spellingShingle | Petr Štěpnička Ivana Císařová Martin Zábranský Piperidinium N-(ferrocenylcarbonyl)glycinate Acta Crystallographica Section E |
| title | Piperidinium N-(ferrocenylcarbonyl)glycinate |
| title_full | Piperidinium N-(ferrocenylcarbonyl)glycinate |
| title_fullStr | Piperidinium N-(ferrocenylcarbonyl)glycinate |
| title_full_unstemmed | Piperidinium N-(ferrocenylcarbonyl)glycinate |
| title_short | Piperidinium N-(ferrocenylcarbonyl)glycinate |
| title_sort | piperidinium n ferrocenylcarbonyl glycinate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810041747 |
| work_keys_str_mv | AT petramp352tamp283pniamp269ka piperidiniumnferrocenylcarbonylglycinate AT ivanacamp237saamp345ovamp225 piperidiniumnferrocenylcarbonylglycinate AT martinzamp225branskamp253 piperidiniumnferrocenylcarbonylglycinate |