Occurrence of harmful elements in the ‘high-aluminium coals' from the Pingshuo mining district, Shanxi Province, China

“High-aluminous coal” is an important coal kind and widely distributed in North China in age of Permo-Carboniferous period. To explore their occurrence state, a total of 15 harmful elements (Li, Ga, In, Cd, Cr, Pb, Be, Mn, Zn, Ag, Co, Ni, Cu, Ba and U) in the No.9 coal and No.11 coal collected from...

Full description

Bibliographic Details
Main Authors: Qiaojing Zhao, Xin Li, Jun Wang, Minmin Zhang, Cunliang Zhao, Jing Zhao, Balaji Panchal, Jialiang Ma
Format: Article
Language:English
Published: SAGE Publishing 2022-05-01
Series:Energy Exploration & Exploitation
Online Access:https://doi.org/10.1177/01445987221092110
_version_ 1811306499588227072
author Qiaojing Zhao
Xin Li
Jun Wang
Minmin Zhang
Cunliang Zhao
Jing Zhao
Balaji Panchal
Jialiang Ma
author_facet Qiaojing Zhao
Xin Li
Jun Wang
Minmin Zhang
Cunliang Zhao
Jing Zhao
Balaji Panchal
Jialiang Ma
author_sort Qiaojing Zhao
collection DOAJ
description “High-aluminous coal” is an important coal kind and widely distributed in North China in age of Permo-Carboniferous period. To explore their occurrence state, a total of 15 harmful elements (Li, Ga, In, Cd, Cr, Pb, Be, Mn, Zn, Ag, Co, Ni, Cu, Ba and U) in the No.9 coal and No.11 coal collected from Pingshuo mining district were determined by inductively coupled plasma mass spectrometry (ICP-MS) and scanning electron microscope with energy spectrum (SEM-EDX). The results showed that the content of Li, Ga, In, Pb, Ag and U were all exceed the world hard coal. In view of the result of clustering analysis within trace elements, it was found that Co, Ni, Zn, Cu, Ag and Cr were mainly associated with sulfide minerals due to their common sulfophilic property. Manganese was mainly occurred in carbonate minerals, while Ba, Cd and U were mainly associated with total minerals. In addition, Pb was related to sulfides and Be is mainly distributed in clay minerals. The enrichment of such harmful elements in Pingshuo coal was caused by the combined effect of transgression and input of terrestrial materials in the peat accumulation stage. Li, Ga, In and Ag have reached the harmful grade.
first_indexed 2024-04-13T08:45:47Z
format Article
id doaj.art-908b6e91b9fa4359929fa6f24bc9760c
institution Directory Open Access Journal
issn 0144-5987
2048-4054
language English
last_indexed 2024-04-13T08:45:47Z
publishDate 2022-05-01
publisher SAGE Publishing
record_format Article
series Energy Exploration & Exploitation
spelling doaj.art-908b6e91b9fa4359929fa6f24bc9760c2022-12-22T02:53:40ZengSAGE PublishingEnergy Exploration & Exploitation0144-59872048-40542022-05-014010.1177/01445987221092110Occurrence of harmful elements in the ‘high-aluminium coals' from the Pingshuo mining district, Shanxi Province, ChinaQiaojing Zhao0Xin Li1Jun Wang2Minmin Zhang3Cunliang Zhao4Jing ZhaoBalaji Panchal5Jialiang Ma6 College of Earth Science and Engineering, , Handan, Hebei, China College of Earth Science and Engineering, , Handan, Hebei, China College of Earth Science and Engineering, , Handan, Hebei, China Key Laboratory for Resource Exploration Research of Hebei Province, , Handan, Hebei, China Key Laboratory for Resource Exploration Research of Hebei Province, , Handan, Hebei, China College of Earth Science and Engineering, , Handan, Hebei, China Department of Atmospheric Environmental Analytics, , Frankfurt am Main, Germany“High-aluminous coal” is an important coal kind and widely distributed in North China in age of Permo-Carboniferous period. To explore their occurrence state, a total of 15 harmful elements (Li, Ga, In, Cd, Cr, Pb, Be, Mn, Zn, Ag, Co, Ni, Cu, Ba and U) in the No.9 coal and No.11 coal collected from Pingshuo mining district were determined by inductively coupled plasma mass spectrometry (ICP-MS) and scanning electron microscope with energy spectrum (SEM-EDX). The results showed that the content of Li, Ga, In, Pb, Ag and U were all exceed the world hard coal. In view of the result of clustering analysis within trace elements, it was found that Co, Ni, Zn, Cu, Ag and Cr were mainly associated with sulfide minerals due to their common sulfophilic property. Manganese was mainly occurred in carbonate minerals, while Ba, Cd and U were mainly associated with total minerals. In addition, Pb was related to sulfides and Be is mainly distributed in clay minerals. The enrichment of such harmful elements in Pingshuo coal was caused by the combined effect of transgression and input of terrestrial materials in the peat accumulation stage. Li, Ga, In and Ag have reached the harmful grade.https://doi.org/10.1177/01445987221092110
spellingShingle Qiaojing Zhao
Xin Li
Jun Wang
Minmin Zhang
Cunliang Zhao
Jing Zhao
Balaji Panchal
Jialiang Ma
Occurrence of harmful elements in the ‘high-aluminium coals' from the Pingshuo mining district, Shanxi Province, China
Energy Exploration & Exploitation
title Occurrence of harmful elements in the ‘high-aluminium coals' from the Pingshuo mining district, Shanxi Province, China
title_full Occurrence of harmful elements in the ‘high-aluminium coals' from the Pingshuo mining district, Shanxi Province, China
title_fullStr Occurrence of harmful elements in the ‘high-aluminium coals' from the Pingshuo mining district, Shanxi Province, China
title_full_unstemmed Occurrence of harmful elements in the ‘high-aluminium coals' from the Pingshuo mining district, Shanxi Province, China
title_short Occurrence of harmful elements in the ‘high-aluminium coals' from the Pingshuo mining district, Shanxi Province, China
title_sort occurrence of harmful elements in the high aluminium coals from the pingshuo mining district shanxi province china
url https://doi.org/10.1177/01445987221092110
work_keys_str_mv AT qiaojingzhao occurrenceofharmfulelementsinthehighaluminiumcoalsfromthepingshuominingdistrictshanxiprovincechina
AT xinli occurrenceofharmfulelementsinthehighaluminiumcoalsfromthepingshuominingdistrictshanxiprovincechina
AT junwang occurrenceofharmfulelementsinthehighaluminiumcoalsfromthepingshuominingdistrictshanxiprovincechina
AT minminzhang occurrenceofharmfulelementsinthehighaluminiumcoalsfromthepingshuominingdistrictshanxiprovincechina
AT cunliangzhao occurrenceofharmfulelementsinthehighaluminiumcoalsfromthepingshuominingdistrictshanxiprovincechina
AT jingzhao occurrenceofharmfulelementsinthehighaluminiumcoalsfromthepingshuominingdistrictshanxiprovincechina
AT balajipanchal occurrenceofharmfulelementsinthehighaluminiumcoalsfromthepingshuominingdistrictshanxiprovincechina
AT jialiangma occurrenceofharmfulelementsinthehighaluminiumcoalsfromthepingshuominingdistrictshanxiprovincechina