| Summary: | Equiatomic medium-entropy alloy (MEA) FeNiCr-B<sub>4</sub>C (0, 1, and 3 wt.% B<sub>4</sub>C) coatings were deposited onto an AISI 1040 steel substrate using pulsed laser cladding. Based on an SEM microstructural analysis, it was found that the cross-sections of all the obtained specimens were characterized by an average coating thickness of 400 ± 20 μm, a sufficiently narrow (100 ± 20 μm) “coating–substrate” transition zone, and the presence of a small number of defects, including cracks and pores. An XRD analysis showed that the formed coatings consisted of a single face-centered cubic (FCC) γ-phase and the space group <i>Fm-3m</i>, regardless of the B<sub>4</sub>C content. However, additional TEM analysis of the FeNiCr coating with 3 wt.% B<sub>4</sub>C revealed a two-phase FCC structure consisting of grains (FCC-1 phase, <i>Fm-3m</i>) up to 1 µm in size and banded interlayers (FCC-2 phase, <i>Fm-3m</i>) between the grains. The grains were clean with a low density of dislocations. Raman spectroscopy confirmed the presence of B<sub>4</sub>C carbides inside the FeNiCr (1 and 3 wt.% B<sub>4</sub>C) coatings, as evidenced by detected peaks corresponding to amorphous carbon and peaks indicating the stretching of C-B-C chains. The mechanical characterization of the FeNiCr-B<sub>4</sub>C coatings specified that additions of 1 and 3 wt.% B<sub>4</sub>C resulted in a notable increase in microhardness of 16% and 38%, respectively, with a slight decrease in ductility of 4% and 10%, respectively, compared to the B<sub>4</sub>C-free FeNiCr coating. Thus, the B<sub>4</sub>C addition can be considered a promising method for strengthening laser-cladded MEA FeNiCr-B<sub>4</sub>C coatings.
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