Superlubricity by polyimide-induced alignment

Abstract We have investigated the lubrication alignment behavior of point-plane contact and plane-plane contact between the GCr15 steel and polyimide (PI) friction pair using nematic liquid crystals (LCs) as the lubricant. In this system, rubbing orients the macromolecular PI molecules, and the orie...

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Main Authors: Xinlei Gao, Hao Chen, Hong Yan, Chengrui Huang, Li Wu, Tingting Wang
Format: Article
Language:English
Published: SpringerOpen 2023-03-01
Series:Friction
Subjects:
Online Access:https://doi.org/10.1007/s40544-022-0686-6
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author Xinlei Gao
Hao Chen
Hong Yan
Chengrui Huang
Li Wu
Tingting Wang
author_facet Xinlei Gao
Hao Chen
Hong Yan
Chengrui Huang
Li Wu
Tingting Wang
author_sort Xinlei Gao
collection DOAJ
description Abstract We have investigated the lubrication alignment behavior of point-plane contact and plane-plane contact between the GCr15 steel and polyimide (PI) friction pair using nematic liquid crystals (LCs) as the lubricant. In this system, rubbing orients the macromolecular PI molecules, and the oriented PI molecules induce alignment of the LC molecules in contact with or close to the oriented PI molecules. The LC molecules are aligned in the wear scar grooves of the PI film, and alignment extends to the GCr15-steel counterpart. Alignment of the LC molecules is correlated with the strong interaction force between the PI and LC molecules, the stable coordination structure of the LCs and GCr15 steel, and the weak interaction between the LC molecules. We performed simulations of the pretilt angle of PI and LCs and discussed the relationship between the pretilt angle and the friction properties. Owing to the small pretilt angle between PI and the LCs, the LC molecules orient almost parallel to the PI material, which is beneficial for superlubricity of this type of friction system.
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spelling doaj.art-90cd88b5be654b218a3404a79b995bc52023-07-09T11:24:40ZengSpringerOpenFriction2223-76902223-77042023-03-011191690170710.1007/s40544-022-0686-6Superlubricity by polyimide-induced alignmentXinlei Gao0Hao Chen1Hong Yan2Chengrui Huang3Li Wu4Tingting Wang5School of Materials Science and Engineering, Hubei UniversitySchool of Chemical and Environmental Engineering, Wuhan Polytechnic UniversityState Key Laboratory of Chemical Resource Engineering, College of Chemistry, Beijing University of Chemical TechnologySchool of Chemical and Environmental Engineering, Wuhan Polytechnic UniversitySchool of Chemistry and Environmental Engineering, Wuhan Institute of TechnologySchool of Chemical and Environmental Engineering, Wuhan Polytechnic UniversityAbstract We have investigated the lubrication alignment behavior of point-plane contact and plane-plane contact between the GCr15 steel and polyimide (PI) friction pair using nematic liquid crystals (LCs) as the lubricant. In this system, rubbing orients the macromolecular PI molecules, and the oriented PI molecules induce alignment of the LC molecules in contact with or close to the oriented PI molecules. The LC molecules are aligned in the wear scar grooves of the PI film, and alignment extends to the GCr15-steel counterpart. Alignment of the LC molecules is correlated with the strong interaction force between the PI and LC molecules, the stable coordination structure of the LCs and GCr15 steel, and the weak interaction between the LC molecules. We performed simulations of the pretilt angle of PI and LCs and discussed the relationship between the pretilt angle and the friction properties. Owing to the small pretilt angle between PI and the LCs, the LC molecules orient almost parallel to the PI material, which is beneficial for superlubricity of this type of friction system.https://doi.org/10.1007/s40544-022-0686-6superlubricitypolyimideliquid crystalalignment
spellingShingle Xinlei Gao
Hao Chen
Hong Yan
Chengrui Huang
Li Wu
Tingting Wang
Superlubricity by polyimide-induced alignment
Friction
superlubricity
polyimide
liquid crystal
alignment
title Superlubricity by polyimide-induced alignment
title_full Superlubricity by polyimide-induced alignment
title_fullStr Superlubricity by polyimide-induced alignment
title_full_unstemmed Superlubricity by polyimide-induced alignment
title_short Superlubricity by polyimide-induced alignment
title_sort superlubricity by polyimide induced alignment
topic superlubricity
polyimide
liquid crystal
alignment
url https://doi.org/10.1007/s40544-022-0686-6
work_keys_str_mv AT xinleigao superlubricitybypolyimideinducedalignment
AT haochen superlubricitybypolyimideinducedalignment
AT hongyan superlubricitybypolyimideinducedalignment
AT chengruihuang superlubricitybypolyimideinducedalignment
AT liwu superlubricitybypolyimideinducedalignment
AT tingtingwang superlubricitybypolyimideinducedalignment