Synthesis of Poly- Tetra-p-Allylcalix[4]Arene Tetra Acetic Acid Adsorbent for Cr(III) and Pb(II) Metal Ions
This paper discusses the preparation, characterization, and the evaluation of adsorption properties of resin poly-tetra-p-allylcalix[4]arene tetra acetic acid from the p-t-butylphenol. The synthesized resins were applied as an adsorbent for Cr(III) and Pb(II) metal ions. The adsorption was conducted...
| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
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Universitas Indonesia
2014-01-01
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| Series: | International Journal of Technology |
| Subjects: | |
| Online Access: | http://ijtech.eng.ui.ac.id/article/view/1114 |
| _version_ | 1797967453526949888 |
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| author | Triana Kusumaningsih Jumina Dwi Siswanta Mustofa Keisuke Ohto Hidetaka Kawakita |
| author_facet | Triana Kusumaningsih Jumina Dwi Siswanta Mustofa Keisuke Ohto Hidetaka Kawakita |
| author_sort | Triana Kusumaningsih |
| collection | DOAJ |
| description | This paper discusses the preparation, characterization, and the evaluation of adsorption properties of resin poly-tetra-p-allylcalix[4]arene tetra acetic acid from the p-t-butylphenol. The synthesized resins were applied as an adsorbent for Cr(III) and Pb(II) metal ions. The adsorption was conducted in a batch system by investigating the effects of acidity (pH), contact time and initial concentration of a heavy metal solution. The adsorption of Cr(III) and Pb(II) metal ions on the resin had the optimum pH rating in region of 4–6 and reached the equilibrium condition in 40 minutes. The adsorption of Cr(III) and Pb(II) metal ions on the resin follows the Langmuir isothermal pattern with the linearity constant (R2 ) of Cr(III) and Pb(II) adsorption, whose results were 0.9640 and 0.9716, respectively. The adsorption capacity of Cr(III) and Pb(II) metal ions is 323.0 µmole/g and 33.4 µmole/g, while the adsorption energy is 30.4 kJ/mole and 39.7 kJ/mole, respectively. Most parameters in batch systems confirm that resin is a good adsorbent for Cr(III) and Pb(II), though Cr(III) adsorption was more favorable than that of Pb(II). The outstanding adsorption abilities for Cr(III) and Pb(II) metal ions have exhibited good prospects for disposal application of polluted water and environmental protection. |
| first_indexed | 2024-04-11T02:31:28Z |
| format | Article |
| id | doaj.art-90d3c8f1fd2c4e7b885c90093c4acc6c |
| institution | Directory Open Access Journal |
| issn | 2086-9614 2087-2100 |
| language | English |
| last_indexed | 2024-04-11T02:31:28Z |
| publishDate | 2014-01-01 |
| publisher | Universitas Indonesia |
| record_format | Article |
| series | International Journal of Technology |
| spelling | doaj.art-90d3c8f1fd2c4e7b885c90093c4acc6c2023-01-02T21:22:55ZengUniversitas IndonesiaInternational Journal of Technology2086-96142087-21002014-01-01329310210.14716/ijtech.v3i2.11141114Synthesis of Poly- Tetra-p-Allylcalix[4]Arene Tetra Acetic Acid Adsorbent for Cr(III) and Pb(II) Metal IonsTriana Kusumaningsih0Jumina1Dwi Siswanta2Mustofa3Keisuke Ohto4Hidetaka Kawakita5Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Sebelas Maret, Surakarta 57126, IndonesiaDepartment of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara, Yogyakarta 55281, IndonesiaDepartment of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara, Yogyakarta 55281, IndonesiaDepartment of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara, Yogyakarta 55281, IndonesiaDepartment of Applied Chemistry, Faculty of Science and Engineering, Saga University, 1-Honjo, Saga 840-8502, JapanDepartment of Applied Chemistry, Faculty of Science and Engineering, Saga University, 1-Honjo, Saga 840-8502, JapanThis paper discusses the preparation, characterization, and the evaluation of adsorption properties of resin poly-tetra-p-allylcalix[4]arene tetra acetic acid from the p-t-butylphenol. The synthesized resins were applied as an adsorbent for Cr(III) and Pb(II) metal ions. The adsorption was conducted in a batch system by investigating the effects of acidity (pH), contact time and initial concentration of a heavy metal solution. The adsorption of Cr(III) and Pb(II) metal ions on the resin had the optimum pH rating in region of 4–6 and reached the equilibrium condition in 40 minutes. The adsorption of Cr(III) and Pb(II) metal ions on the resin follows the Langmuir isothermal pattern with the linearity constant (R2 ) of Cr(III) and Pb(II) adsorption, whose results were 0.9640 and 0.9716, respectively. The adsorption capacity of Cr(III) and Pb(II) metal ions is 323.0 µmole/g and 33.4 µmole/g, while the adsorption energy is 30.4 kJ/mole and 39.7 kJ/mole, respectively. Most parameters in batch systems confirm that resin is a good adsorbent for Cr(III) and Pb(II), though Cr(III) adsorption was more favorable than that of Pb(II). The outstanding adsorption abilities for Cr(III) and Pb(II) metal ions have exhibited good prospects for disposal application of polluted water and environmental protection.http://ijtech.eng.ui.ac.id/article/view/1114This paper discusses the preparation, characterization, and the evaluation of adsorption properties of resin poly-tetra-p-allylcalix[4]arene tetra acetic acid from the p-t-butylphenol. The synthesized |
| spellingShingle | Triana Kusumaningsih Jumina Dwi Siswanta Mustofa Keisuke Ohto Hidetaka Kawakita Synthesis of Poly- Tetra-p-Allylcalix[4]Arene Tetra Acetic Acid Adsorbent for Cr(III) and Pb(II) Metal Ions International Journal of Technology This paper discusses the preparation, characterization, and the evaluation of adsorption properties of resin poly-tetra-p-allylcalix[4]arene tetra acetic acid from the p-t-butylphenol. The synthesized |
| title | Synthesis of Poly- Tetra-p-Allylcalix[4]Arene Tetra Acetic Acid Adsorbent for Cr(III) and Pb(II) Metal Ions |
| title_full | Synthesis of Poly- Tetra-p-Allylcalix[4]Arene Tetra Acetic Acid Adsorbent for Cr(III) and Pb(II) Metal Ions |
| title_fullStr | Synthesis of Poly- Tetra-p-Allylcalix[4]Arene Tetra Acetic Acid Adsorbent for Cr(III) and Pb(II) Metal Ions |
| title_full_unstemmed | Synthesis of Poly- Tetra-p-Allylcalix[4]Arene Tetra Acetic Acid Adsorbent for Cr(III) and Pb(II) Metal Ions |
| title_short | Synthesis of Poly- Tetra-p-Allylcalix[4]Arene Tetra Acetic Acid Adsorbent for Cr(III) and Pb(II) Metal Ions |
| title_sort | synthesis of poly tetra p allylcalix 4 arene tetra acetic acid adsorbent for cr iii and pb ii metal ions |
| topic | This paper discusses the preparation, characterization, and the evaluation of adsorption properties of resin poly-tetra-p-allylcalix[4]arene tetra acetic acid from the p-t-butylphenol. The synthesized |
| url | http://ijtech.eng.ui.ac.id/article/view/1114 |
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