Study of the magnetic properties of Mn‐doped iron titanate nanoparticles fabricated using natural mineral
Abstract In this study, iron titanate (FT) and manganese‐doped iron titanate (MFT) nanoparticles were synthesised from a natural mineral, ilmenite ore, using a simple and effective method. X‐ray diffraction analysis confirmed the reduction of crystallite size from 56 to 29 nm with an increase in Mn...
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Format: | Article |
Language: | English |
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Wiley
2021-04-01
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Series: | Micro & Nano Letters |
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Online Access: | https://doi.org/10.1049/mna2.12039 |
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author | Sutha Senthil Dhineshbabu Nattanmai Raman Arunmetha Sundaramoorthy |
author_facet | Sutha Senthil Dhineshbabu Nattanmai Raman Arunmetha Sundaramoorthy |
author_sort | Sutha Senthil |
collection | DOAJ |
description | Abstract In this study, iron titanate (FT) and manganese‐doped iron titanate (MFT) nanoparticles were synthesised from a natural mineral, ilmenite ore, using a simple and effective method. X‐ray diffraction analysis confirmed the reduction of crystallite size from 56 to 29 nm with an increase in Mn doping concentration from 0% to 2%. Doping of Mn transformed the agglomerated fine particles into nanosphere‐like morphology with dimensions less than 200 nm. Magnetization studies revealed that FT and MFT were hard ferrimagnetic materials, and beyond 0.8% Mn dopant concentration, reduction in magnetic saturation value of 1.46–1.41 emu g−1 was observed. Resistivity of FT decreased from ≈19 to ≈2 K Ω‐cm with doping Mn and tuning of such electrical property through doping concentration can lead to their application in fabricating spintronic devices. This work suggests a new pathway to synthesise magnetic–semiconducting nanostructures at large scale and in an environment friendly manner from ilmenite ore. |
first_indexed | 2024-12-13T22:32:07Z |
format | Article |
id | doaj.art-90e2234084a64c5ea65683d11856df38 |
institution | Directory Open Access Journal |
issn | 1750-0443 |
language | English |
last_indexed | 2024-12-13T22:32:07Z |
publishDate | 2021-04-01 |
publisher | Wiley |
record_format | Article |
series | Micro & Nano Letters |
spelling | doaj.art-90e2234084a64c5ea65683d11856df382022-12-21T23:29:04ZengWileyMicro & Nano Letters1750-04432021-04-0116424525010.1049/mna2.12039Study of the magnetic properties of Mn‐doped iron titanate nanoparticles fabricated using natural mineralSutha Senthil0Dhineshbabu Nattanmai Raman1Arunmetha Sundaramoorthy2Department of Electronics and Communication Engineering Sri Venkateswara College of Engineering Sriperumbudur Tamil Nadu 602 117 IndiaDepartment of Electronics and Communication Engineering Aditya Engineering College Surampalem East Godavari Andhra Pradesh 533437 IndiaDepartment of Electronics and Communication Engineering, Center for Advanced Energy Studies Koneru Lakshmaiah Education Foundation Guntur Andhra Pradesh 522 502 IndiaAbstract In this study, iron titanate (FT) and manganese‐doped iron titanate (MFT) nanoparticles were synthesised from a natural mineral, ilmenite ore, using a simple and effective method. X‐ray diffraction analysis confirmed the reduction of crystallite size from 56 to 29 nm with an increase in Mn doping concentration from 0% to 2%. Doping of Mn transformed the agglomerated fine particles into nanosphere‐like morphology with dimensions less than 200 nm. Magnetization studies revealed that FT and MFT were hard ferrimagnetic materials, and beyond 0.8% Mn dopant concentration, reduction in magnetic saturation value of 1.46–1.41 emu g−1 was observed. Resistivity of FT decreased from ≈19 to ≈2 K Ω‐cm with doping Mn and tuning of such electrical property through doping concentration can lead to their application in fabricating spintronic devices. This work suggests a new pathway to synthesise magnetic–semiconducting nanostructures at large scale and in an environment friendly manner from ilmenite ore.https://doi.org/10.1049/mna2.12039Structure of solid clusters, nanoparticles, nanotubes and nanostructured materialsDoping and implantation of impuritiesImpurity concentration, distribution, and gradientsMicrostructureElectrical properties of other inorganic semiconductors (thin films, low-dimensional and nanoscale structures)Ferromagnetism of nonmetals |
spellingShingle | Sutha Senthil Dhineshbabu Nattanmai Raman Arunmetha Sundaramoorthy Study of the magnetic properties of Mn‐doped iron titanate nanoparticles fabricated using natural mineral Micro & Nano Letters Structure of solid clusters, nanoparticles, nanotubes and nanostructured materials Doping and implantation of impurities Impurity concentration, distribution, and gradients Microstructure Electrical properties of other inorganic semiconductors (thin films, low-dimensional and nanoscale structures) Ferromagnetism of nonmetals |
title | Study of the magnetic properties of Mn‐doped iron titanate nanoparticles fabricated using natural mineral |
title_full | Study of the magnetic properties of Mn‐doped iron titanate nanoparticles fabricated using natural mineral |
title_fullStr | Study of the magnetic properties of Mn‐doped iron titanate nanoparticles fabricated using natural mineral |
title_full_unstemmed | Study of the magnetic properties of Mn‐doped iron titanate nanoparticles fabricated using natural mineral |
title_short | Study of the magnetic properties of Mn‐doped iron titanate nanoparticles fabricated using natural mineral |
title_sort | study of the magnetic properties of mn doped iron titanate nanoparticles fabricated using natural mineral |
topic | Structure of solid clusters, nanoparticles, nanotubes and nanostructured materials Doping and implantation of impurities Impurity concentration, distribution, and gradients Microstructure Electrical properties of other inorganic semiconductors (thin films, low-dimensional and nanoscale structures) Ferromagnetism of nonmetals |
url | https://doi.org/10.1049/mna2.12039 |
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