Study of the magnetic properties of Mn‐doped iron titanate nanoparticles fabricated using natural mineral

Abstract In this study, iron titanate (FT) and manganese‐doped iron titanate (MFT) nanoparticles were synthesised from a natural mineral, ilmenite ore, using a simple and effective method. X‐ray diffraction analysis confirmed the reduction of crystallite size from 56 to 29 nm with an increase in Mn...

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Main Authors: Sutha Senthil, Dhineshbabu Nattanmai Raman, Arunmetha Sundaramoorthy
Format: Article
Language:English
Published: Wiley 2021-04-01
Series:Micro & Nano Letters
Subjects:
Online Access:https://doi.org/10.1049/mna2.12039
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author Sutha Senthil
Dhineshbabu Nattanmai Raman
Arunmetha Sundaramoorthy
author_facet Sutha Senthil
Dhineshbabu Nattanmai Raman
Arunmetha Sundaramoorthy
author_sort Sutha Senthil
collection DOAJ
description Abstract In this study, iron titanate (FT) and manganese‐doped iron titanate (MFT) nanoparticles were synthesised from a natural mineral, ilmenite ore, using a simple and effective method. X‐ray diffraction analysis confirmed the reduction of crystallite size from 56 to 29 nm with an increase in Mn doping concentration from 0% to 2%. Doping of Mn transformed the agglomerated fine particles into nanosphere‐like morphology with dimensions less than 200 nm. Magnetization studies revealed that FT and MFT were hard ferrimagnetic materials, and beyond 0.8% Mn dopant concentration, reduction in magnetic saturation value of 1.46–1.41 emu g−1 was observed. Resistivity of FT decreased from ≈19 to ≈2 K Ω‐cm with doping Mn and tuning of such electrical property through doping concentration can lead to their application in fabricating spintronic devices. This work suggests a new pathway to synthesise magnetic–semiconducting nanostructures at large scale and in an environment friendly manner from ilmenite ore.
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spelling doaj.art-90e2234084a64c5ea65683d11856df382022-12-21T23:29:04ZengWileyMicro & Nano Letters1750-04432021-04-0116424525010.1049/mna2.12039Study of the magnetic properties of Mn‐doped iron titanate nanoparticles fabricated using natural mineralSutha Senthil0Dhineshbabu Nattanmai Raman1Arunmetha Sundaramoorthy2Department of Electronics and Communication Engineering Sri Venkateswara College of Engineering Sriperumbudur Tamil Nadu 602 117 IndiaDepartment of Electronics and Communication Engineering Aditya Engineering College Surampalem East Godavari Andhra Pradesh 533437 IndiaDepartment of Electronics and Communication Engineering, Center for Advanced Energy Studies Koneru Lakshmaiah Education Foundation Guntur Andhra Pradesh 522 502 IndiaAbstract In this study, iron titanate (FT) and manganese‐doped iron titanate (MFT) nanoparticles were synthesised from a natural mineral, ilmenite ore, using a simple and effective method. X‐ray diffraction analysis confirmed the reduction of crystallite size from 56 to 29 nm with an increase in Mn doping concentration from 0% to 2%. Doping of Mn transformed the agglomerated fine particles into nanosphere‐like morphology with dimensions less than 200 nm. Magnetization studies revealed that FT and MFT were hard ferrimagnetic materials, and beyond 0.8% Mn dopant concentration, reduction in magnetic saturation value of 1.46–1.41 emu g−1 was observed. Resistivity of FT decreased from ≈19 to ≈2 K Ω‐cm with doping Mn and tuning of such electrical property through doping concentration can lead to their application in fabricating spintronic devices. This work suggests a new pathway to synthesise magnetic–semiconducting nanostructures at large scale and in an environment friendly manner from ilmenite ore.https://doi.org/10.1049/mna2.12039Structure of solid clusters, nanoparticles, nanotubes and nanostructured materialsDoping and implantation of impuritiesImpurity concentration, distribution, and gradientsMicrostructureElectrical properties of other inorganic semiconductors (thin films, low-dimensional and nanoscale structures)Ferromagnetism of nonmetals
spellingShingle Sutha Senthil
Dhineshbabu Nattanmai Raman
Arunmetha Sundaramoorthy
Study of the magnetic properties of Mn‐doped iron titanate nanoparticles fabricated using natural mineral
Micro & Nano Letters
Structure of solid clusters, nanoparticles, nanotubes and nanostructured materials
Doping and implantation of impurities
Impurity concentration, distribution, and gradients
Microstructure
Electrical properties of other inorganic semiconductors (thin films, low-dimensional and nanoscale structures)
Ferromagnetism of nonmetals
title Study of the magnetic properties of Mn‐doped iron titanate nanoparticles fabricated using natural mineral
title_full Study of the magnetic properties of Mn‐doped iron titanate nanoparticles fabricated using natural mineral
title_fullStr Study of the magnetic properties of Mn‐doped iron titanate nanoparticles fabricated using natural mineral
title_full_unstemmed Study of the magnetic properties of Mn‐doped iron titanate nanoparticles fabricated using natural mineral
title_short Study of the magnetic properties of Mn‐doped iron titanate nanoparticles fabricated using natural mineral
title_sort study of the magnetic properties of mn doped iron titanate nanoparticles fabricated using natural mineral
topic Structure of solid clusters, nanoparticles, nanotubes and nanostructured materials
Doping and implantation of impurities
Impurity concentration, distribution, and gradients
Microstructure
Electrical properties of other inorganic semiconductors (thin films, low-dimensional and nanoscale structures)
Ferromagnetism of nonmetals
url https://doi.org/10.1049/mna2.12039
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AT arunmethasundaramoorthy studyofthemagneticpropertiesofmndopedirontitanatenanoparticlesfabricatedusingnaturalmineral