SYNTHESIS AND CRYSTAL STRUCTURE OF A NA(I) COMPLEX WITH 4,4’-BIPYRIDINE AND 2-FORMYL- BENZENESULFONATE-HYDRAZINE
A Na(I) complex, [Na(4,4’-bipyridine)2·(H2O)4]·L·OH·2H2O (L = 2-formyl-benzenesulfonate-hydrazine), has been synthesized. And its structure was determined by X-ray single crystal diffraction analysis. The Na(I) complex belongs to orthorhombic, space group C2221 with a = 7.9162(16) Å, b = 18.451(4) Å...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
2015-07-01
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| Series: | Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry |
| Subjects: | |
| Online Access: | http://pubs.ub.ro/?pg=revues&rev=cscc6&num=201502&vol=2&aid=4237 |
| Summary: | A Na(I) complex, [Na(4,4’-bipyridine)2·(H2O)4]·L·OH·2H2O (L = 2-formyl-benzenesulfonate-hydrazine), has been synthesized. And its structure was determined by X-ray single crystal diffraction analysis. The Na(I) complex belongs to orthorhombic, space group C2221 with a = 7.9162(16) Å, b = 18.451(4) Å, c = 26.397(5) Å, V= 3855.7(13) Å3, Z = 4, Dc = 1.394 mg·m-3, μ = 0.218 mm-1, F(000) =1689, and final R1 = 0.0683, ωR2 = 0.2017. The result shows that the Na(I) center is six-coordination with a N2O4 distorted octahedral coordination environment. The Na(I) complex forms 1D chain structure by the π-π stacking interaction. |
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| ISSN: | 1582-540X 1582-540X |