SYNTHESIS AND CRYSTAL STRUCTURE OF A NA(I) COMPLEX WITH 4,4’-BIPYRIDINE AND 2-FORMYL- BENZENESULFONATE-HYDRAZINE
A Na(I) complex, [Na(4,4’-bipyridine)2·(H2O)4]·L·OH·2H2O (L = 2-formyl-benzenesulfonate-hydrazine), has been synthesized. And its structure was determined by X-ray single crystal diffraction analysis. The Na(I) complex belongs to orthorhombic, space group C2221 with a = 7.9162(16) Å, b = 18.451(4) Å...
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
2015-07-01
|
| Series: | Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry |
| Subjects: | |
| Online Access: | http://pubs.ub.ro/?pg=revues&rev=cscc6&num=201502&vol=2&aid=4237 |
| _version_ | 1819211763731660800 |
|---|---|
| author | TAI XI-SHI WANG GUANG-LI LIU YUAN-YUAN |
| author_facet | TAI XI-SHI WANG GUANG-LI LIU YUAN-YUAN |
| author_sort | TAI XI-SHI |
| collection | DOAJ |
| description | A Na(I) complex, [Na(4,4’-bipyridine)2·(H2O)4]·L·OH·2H2O (L = 2-formyl-benzenesulfonate-hydrazine), has been synthesized. And its structure was determined by X-ray single crystal diffraction analysis. The Na(I) complex belongs to orthorhombic, space group C2221 with a = 7.9162(16) Å, b = 18.451(4) Å, c = 26.397(5) Å, V= 3855.7(13) Å3, Z = 4, Dc = 1.394 mg·m-3, μ = 0.218 mm-1, F(000) =1689, and final R1 = 0.0683, ωR2 = 0.2017. The result shows that the Na(I) center is six-coordination with a N2O4 distorted octahedral coordination environment. The Na(I) complex forms 1D chain structure by the π-π stacking interaction. |
| first_indexed | 2024-12-23T06:32:15Z |
| format | Article |
| id | doaj.art-90e421224159499b8bdb05dc3a28618f |
| institution | Directory Open Access Journal |
| issn | 1582-540X 1582-540X |
| language | English |
| last_indexed | 2024-12-23T06:32:15Z |
| publishDate | 2015-07-01 |
| publisher | Alma Mater Publishing House "Vasile Alecsandri" University of Bacau |
| record_format | Article |
| series | Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry |
| spelling | doaj.art-90e421224159499b8bdb05dc3a28618f2022-12-21T17:56:53ZengAlma Mater Publishing House "Vasile Alecsandri" University of BacauScientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry1582-540X1582-540X2015-07-01162173177SYNTHESIS AND CRYSTAL STRUCTURE OF A NA(I) COMPLEX WITH 4,4’-BIPYRIDINE AND 2-FORMYL- BENZENESULFONATE-HYDRAZINETAI XI-SHI0WANG GUANG-LI1LIU YUAN-YUAN2College of Chemistry and Chemical Engineering, Weifang University, Weifang 261061, P. R. ChinaWeifang Bureau of Quality and Technical Supervision, Weifang 261061, P. R. China College of Chemistry and Chemical Engineering, Weifang University, Weifang 261061, P. R. ChinaA Na(I) complex, [Na(4,4’-bipyridine)2·(H2O)4]·L·OH·2H2O (L = 2-formyl-benzenesulfonate-hydrazine), has been synthesized. And its structure was determined by X-ray single crystal diffraction analysis. The Na(I) complex belongs to orthorhombic, space group C2221 with a = 7.9162(16) Å, b = 18.451(4) Å, c = 26.397(5) Å, V= 3855.7(13) Å3, Z = 4, Dc = 1.394 mg·m-3, μ = 0.218 mm-1, F(000) =1689, and final R1 = 0.0683, ωR2 = 0.2017. The result shows that the Na(I) center is six-coordination with a N2O4 distorted octahedral coordination environment. The Na(I) complex forms 1D chain structure by the π-π stacking interaction.http://pubs.ub.ro/?pg=revues&rev=cscc6&num=201502&vol=2&aid=423744’-bipyridine2-formyl-benzenesulfonate-hydrazineNa(I) complexsynthesisstructural characterization |
| spellingShingle | TAI XI-SHI WANG GUANG-LI LIU YUAN-YUAN SYNTHESIS AND CRYSTAL STRUCTURE OF A NA(I) COMPLEX WITH 4,4’-BIPYRIDINE AND 2-FORMYL- BENZENESULFONATE-HYDRAZINE Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry 4 4’-bipyridine 2-formyl-benzenesulfonate-hydrazine Na(I) complex synthesis structural characterization |
| title | SYNTHESIS AND CRYSTAL STRUCTURE OF A NA(I) COMPLEX WITH 4,4’-BIPYRIDINE AND 2-FORMYL- BENZENESULFONATE-HYDRAZINE |
| title_full | SYNTHESIS AND CRYSTAL STRUCTURE OF A NA(I) COMPLEX WITH 4,4’-BIPYRIDINE AND 2-FORMYL- BENZENESULFONATE-HYDRAZINE |
| title_fullStr | SYNTHESIS AND CRYSTAL STRUCTURE OF A NA(I) COMPLEX WITH 4,4’-BIPYRIDINE AND 2-FORMYL- BENZENESULFONATE-HYDRAZINE |
| title_full_unstemmed | SYNTHESIS AND CRYSTAL STRUCTURE OF A NA(I) COMPLEX WITH 4,4’-BIPYRIDINE AND 2-FORMYL- BENZENESULFONATE-HYDRAZINE |
| title_short | SYNTHESIS AND CRYSTAL STRUCTURE OF A NA(I) COMPLEX WITH 4,4’-BIPYRIDINE AND 2-FORMYL- BENZENESULFONATE-HYDRAZINE |
| title_sort | synthesis and crystal structure of a na i complex with 4 4 bipyridine and 2 formyl benzenesulfonate hydrazine |
| topic | 4 4’-bipyridine 2-formyl-benzenesulfonate-hydrazine Na(I) complex synthesis structural characterization |
| url | http://pubs.ub.ro/?pg=revues&rev=cscc6&num=201502&vol=2&aid=4237 |
| work_keys_str_mv | AT taixishi synthesisandcrystalstructureofanaicomplexwith44bipyridineand2formylbenzenesulfonatehydrazine AT wangguangli synthesisandcrystalstructureofanaicomplexwith44bipyridineand2formylbenzenesulfonatehydrazine AT liuyuanyuan synthesisandcrystalstructureofanaicomplexwith44bipyridineand2formylbenzenesulfonatehydrazine |