Crystal structure of 5-(β-d-glucopyranosylthio)-N-(4-methylphenyl)-1,3,4-thiadiazol-2-amine
In the structure of the title compound, C15H19N3O5S2, the bond lengths at the linking sulfur atom are significantly different [1.7473 (17) and 1.811 (2) Å], and the angle at the exocyclic nitrogen atom is wide at 128.45 (18)°. The interplanar angle between the tolyl and thiadiazole rings is 9.2 (1)°...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2023-07-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989023005248 |
| _version_ | 1797692270019870720 |
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| author | Mamdouh A. Abu-Zaied Ali M. S. Hebishy Galal H. Elgemeie Hagar T. Salama Peter G. Jones |
| author_facet | Mamdouh A. Abu-Zaied Ali M. S. Hebishy Galal H. Elgemeie Hagar T. Salama Peter G. Jones |
| author_sort | Mamdouh A. Abu-Zaied |
| collection | DOAJ |
| description | In the structure of the title compound, C15H19N3O5S2, the bond lengths at the linking sulfur atom are significantly different [1.7473 (17) and 1.811 (2) Å], and the angle at the exocyclic nitrogen atom is wide at 128.45 (18)°. The interplanar angle between the tolyl and thiadiazole rings is 9.2 (1)°. The complex hydrogen-bonding pattern, involving five donors and five acceptors, can be broken down into a one-dimensional ribbon parallel to the b axis, involving hydrogen bonds of the sugar residues only, and a two-dimensional layer structure parallel to the ab plane, based on the N—H...O and O—H...N hydrogen bonds. |
| first_indexed | 2024-03-12T02:26:08Z |
| format | Article |
| id | doaj.art-90fe68cdb0b74b3ea8ee7bb7c2559e0b |
| institution | Directory Open Access Journal |
| issn | 2056-9890 |
| language | English |
| last_indexed | 2024-03-12T02:26:08Z |
| publishDate | 2023-07-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj.art-90fe68cdb0b74b3ea8ee7bb7c2559e0b2023-09-05T13:04:52ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902023-07-0179765265610.1107/S2056989023005248yz2035Crystal structure of 5-(β-d-glucopyranosylthio)-N-(4-methylphenyl)-1,3,4-thiadiazol-2-amineMamdouh A. Abu-Zaied0Ali M. S. Hebishy1Galal H. Elgemeie2Hagar T. Salama3Peter G. Jones4Green Chemistry Department, National Research Centre, Dokki, Giza, EgyptChemistry Department, Faculty of Science, Helwan University, Cairo, EgyptChemistry Department, Faculty of Science, Helwan University, Cairo, EgyptChemistry Department, Faculty of Science, Helwan University, Cairo, EgyptInstitut für Anorganische und Analytische Chemie, Technische Universität Braunschweig, Hagenring 30, D-38106 Braunschweig, GermanyIn the structure of the title compound, C15H19N3O5S2, the bond lengths at the linking sulfur atom are significantly different [1.7473 (17) and 1.811 (2) Å], and the angle at the exocyclic nitrogen atom is wide at 128.45 (18)°. The interplanar angle between the tolyl and thiadiazole rings is 9.2 (1)°. The complex hydrogen-bonding pattern, involving five donors and five acceptors, can be broken down into a one-dimensional ribbon parallel to the b axis, involving hydrogen bonds of the sugar residues only, and a two-dimensional layer structure parallel to the ab plane, based on the N—H...O and O—H...N hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S2056989023005248glucosethiadiazolecrystal structurehydrogen bonds |
| spellingShingle | Mamdouh A. Abu-Zaied Ali M. S. Hebishy Galal H. Elgemeie Hagar T. Salama Peter G. Jones Crystal structure of 5-(β-d-glucopyranosylthio)-N-(4-methylphenyl)-1,3,4-thiadiazol-2-amine Acta Crystallographica Section E: Crystallographic Communications glucose thiadiazole crystal structure hydrogen bonds |
| title | Crystal structure of 5-(β-d-glucopyranosylthio)-N-(4-methylphenyl)-1,3,4-thiadiazol-2-amine |
| title_full | Crystal structure of 5-(β-d-glucopyranosylthio)-N-(4-methylphenyl)-1,3,4-thiadiazol-2-amine |
| title_fullStr | Crystal structure of 5-(β-d-glucopyranosylthio)-N-(4-methylphenyl)-1,3,4-thiadiazol-2-amine |
| title_full_unstemmed | Crystal structure of 5-(β-d-glucopyranosylthio)-N-(4-methylphenyl)-1,3,4-thiadiazol-2-amine |
| title_short | Crystal structure of 5-(β-d-glucopyranosylthio)-N-(4-methylphenyl)-1,3,4-thiadiazol-2-amine |
| title_sort | crystal structure of 5 β d glucopyranosylthio n 4 methylphenyl 1 3 4 thiadiazol 2 amine |
| topic | glucose thiadiazole crystal structure hydrogen bonds |
| url | http://scripts.iucr.org/cgi-bin/paper?S2056989023005248 |
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