Active Bilayer PE/PCL Films for Food Packaging Modified with Zinc Oxide and Casein

This paper studies the properties of active polymer food packaging bilayer polyethylene/polycaprolactone (PE/PCL) films. Such packaging material consists of primary PE layer coated with thin film of PCL coating modified with active component (zinc oxide or zinc oxide/casein complex) with intention t...

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Main Authors: Ana Rešček, Ljerka Kratofil Krehula, Zvonimir Katančić, Zlata Hrnjak-Murgić
Format: Article
Language:English
Published: Croatian Chemical Society 2015-12-01
Series:Croatica Chemica Acta
Online Access:http://hrcak.srce.hr/file/222470
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author Ana Rešček
Ljerka Kratofil Krehula
Zvonimir Katančić
Zlata Hrnjak-Murgić
author_facet Ana Rešček
Ljerka Kratofil Krehula
Zvonimir Katančić
Zlata Hrnjak-Murgić
author_sort Ana Rešček
collection DOAJ
description This paper studies the properties of active polymer food packaging bilayer polyethylene/polycaprolactone (PE/PCL) films. Such packaging material consists of primary PE layer coated with thin film of PCL coating modified with active component (zinc oxide or zinc oxide/casein complex) with intention to extend the shelf life of food and to maintain the quality and health safety. The influence of additives as active components on barrier, mechanical, thermal and antimicrobial properties of such materials was studied. The results show that, in comparison to the neat PE and PE/PCL films, some of PE/PCL bilayer films with additives exhibit improved barrier properties <i>i.e.</i> decreased water vapour permeability. Higher thermal stability of modified PE/PCL material is obtained due to a modified mechanism of thermal degradation. The samples with the additive nanoparticles homogeneously dispersed in the polymer matrix showed good mechanical properties. Addition of higher ZnO content contributes to the enhanced antibacterial activity of a material.
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spelling doaj.art-911da1966e7f4ef1a0cc3eba3ffd46d12022-12-21T18:44:49ZengCroatian Chemical SocietyCroatica Chemica Acta0011-16431334-417X2015-12-0188446147310.5562/cca2768151219Active Bilayer PE/PCL Films for Food Packaging Modified with Zinc Oxide and CaseinAna Rešček0Ljerka Kratofil Krehula1Zvonimir Katančić2Zlata Hrnjak-Murgić3PIK Vrbovec d.d., Zagrebačka 148, HR-10340 Vrbovec, CroatiaFaculty of Chemical Engineering and Technology, University of Zagreb, Marulićev trg 19, P.O. Box 177, HR-10000 Zagreb, CroatiaFaculty of Chemical Engineering and Technology, University of Zagreb, Marulićev trg 19, P.O. Box 177, HR-10000 Zagreb, CroatiaFaculty of Chemical Engineering and Technology, University of Zagreb, Marulićev trg 19, P.O. Box 177, HR-10000 Zagreb, CroatiaThis paper studies the properties of active polymer food packaging bilayer polyethylene/polycaprolactone (PE/PCL) films. Such packaging material consists of primary PE layer coated with thin film of PCL coating modified with active component (zinc oxide or zinc oxide/casein complex) with intention to extend the shelf life of food and to maintain the quality and health safety. The influence of additives as active components on barrier, mechanical, thermal and antimicrobial properties of such materials was studied. The results show that, in comparison to the neat PE and PE/PCL films, some of PE/PCL bilayer films with additives exhibit improved barrier properties <i>i.e.</i> decreased water vapour permeability. Higher thermal stability of modified PE/PCL material is obtained due to a modified mechanism of thermal degradation. The samples with the additive nanoparticles homogeneously dispersed in the polymer matrix showed good mechanical properties. Addition of higher ZnO content contributes to the enhanced antibacterial activity of a material.http://hrcak.srce.hr/file/222470
spellingShingle Ana Rešček
Ljerka Kratofil Krehula
Zvonimir Katančić
Zlata Hrnjak-Murgić
Active Bilayer PE/PCL Films for Food Packaging Modified with Zinc Oxide and Casein
Croatica Chemica Acta
title Active Bilayer PE/PCL Films for Food Packaging Modified with Zinc Oxide and Casein
title_full Active Bilayer PE/PCL Films for Food Packaging Modified with Zinc Oxide and Casein
title_fullStr Active Bilayer PE/PCL Films for Food Packaging Modified with Zinc Oxide and Casein
title_full_unstemmed Active Bilayer PE/PCL Films for Food Packaging Modified with Zinc Oxide and Casein
title_short Active Bilayer PE/PCL Films for Food Packaging Modified with Zinc Oxide and Casein
title_sort active bilayer pe pcl films for food packaging modified with zinc oxide and casein
url http://hrcak.srce.hr/file/222470
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