Nanocellulose from Unbleached Hemp Fibers as a Filler for Biobased Photocured Composites with Epoxidized Cardanol
Biobased composites were successfully prepared using raw materials derived from biomass waste, i.e., an epoxy resin obtained from cardanol and nanocellulose from unbleached hemp fibers. The composites were prepared by solvent exchange and an impregnation of the cellulosic mat with the resin, followe...
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MDPI AG
2021-01-01
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Series: | Journal of Composites Science |
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Online Access: | https://www.mdpi.com/2504-477X/5/1/11 |
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author | Sara Dalle Vacche Vijayaletchumy Karunakaran Silvia Maria Ronchetti Alessandra Vitale Roberta Bongiovanni |
author_facet | Sara Dalle Vacche Vijayaletchumy Karunakaran Silvia Maria Ronchetti Alessandra Vitale Roberta Bongiovanni |
author_sort | Sara Dalle Vacche |
collection | DOAJ |
description | Biobased composites were successfully prepared using raw materials derived from biomass waste, i.e., an epoxy resin obtained from cardanol and nanocellulose from unbleached hemp fibers. The composites were prepared by solvent exchange and an impregnation of the cellulosic mat with the resin, followed by photocuring. Quantitative conversion was obtained, despite the high amount of fibers (30 wt%) and their absorbance in the UV region of the light spectrum. X-ray diffraction confirmed that the crystalline structure of cellulose did not change during the impregnation and curing process. The cured composites were flexible, hydrophobic, water resistant, transparent with a yellow/brown color, and in the rubbery state at room temperature. |
first_indexed | 2024-03-10T13:32:03Z |
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id | doaj.art-9121d5059a0e4fa98dd4c3f894e11d17 |
institution | Directory Open Access Journal |
issn | 2504-477X |
language | English |
last_indexed | 2024-03-10T13:32:03Z |
publishDate | 2021-01-01 |
publisher | MDPI AG |
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series | Journal of Composites Science |
spelling | doaj.art-9121d5059a0e4fa98dd4c3f894e11d172023-11-21T07:54:51ZengMDPI AGJournal of Composites Science2504-477X2021-01-01511110.3390/jcs5010011Nanocellulose from Unbleached Hemp Fibers as a Filler for Biobased Photocured Composites with Epoxidized CardanolSara Dalle Vacche0Vijayaletchumy Karunakaran1Silvia Maria Ronchetti2Alessandra Vitale3Roberta Bongiovanni4Department of Applied Science and Technology, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Torino, ItalyDepartment of Applied Science and Technology, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Torino, ItalyDepartment of Applied Science and Technology, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Torino, ItalyDepartment of Applied Science and Technology, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Torino, ItalyDepartment of Applied Science and Technology, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Torino, ItalyBiobased composites were successfully prepared using raw materials derived from biomass waste, i.e., an epoxy resin obtained from cardanol and nanocellulose from unbleached hemp fibers. The composites were prepared by solvent exchange and an impregnation of the cellulosic mat with the resin, followed by photocuring. Quantitative conversion was obtained, despite the high amount of fibers (30 wt%) and their absorbance in the UV region of the light spectrum. X-ray diffraction confirmed that the crystalline structure of cellulose did not change during the impregnation and curing process. The cured composites were flexible, hydrophobic, water resistant, transparent with a yellow/brown color, and in the rubbery state at room temperature.https://www.mdpi.com/2504-477X/5/1/11biobased polymersphotocuringX-ray diffractionFourier-transform infrared spectroscopynanocellulosehemp |
spellingShingle | Sara Dalle Vacche Vijayaletchumy Karunakaran Silvia Maria Ronchetti Alessandra Vitale Roberta Bongiovanni Nanocellulose from Unbleached Hemp Fibers as a Filler for Biobased Photocured Composites with Epoxidized Cardanol Journal of Composites Science biobased polymers photocuring X-ray diffraction Fourier-transform infrared spectroscopy nanocellulose hemp |
title | Nanocellulose from Unbleached Hemp Fibers as a Filler for Biobased Photocured Composites with Epoxidized Cardanol |
title_full | Nanocellulose from Unbleached Hemp Fibers as a Filler for Biobased Photocured Composites with Epoxidized Cardanol |
title_fullStr | Nanocellulose from Unbleached Hemp Fibers as a Filler for Biobased Photocured Composites with Epoxidized Cardanol |
title_full_unstemmed | Nanocellulose from Unbleached Hemp Fibers as a Filler for Biobased Photocured Composites with Epoxidized Cardanol |
title_short | Nanocellulose from Unbleached Hemp Fibers as a Filler for Biobased Photocured Composites with Epoxidized Cardanol |
title_sort | nanocellulose from unbleached hemp fibers as a filler for biobased photocured composites with epoxidized cardanol |
topic | biobased polymers photocuring X-ray diffraction Fourier-transform infrared spectroscopy nanocellulose hemp |
url | https://www.mdpi.com/2504-477X/5/1/11 |
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