Nanocellulose from Unbleached Hemp Fibers as a Filler for Biobased Photocured Composites with Epoxidized Cardanol

Biobased composites were successfully prepared using raw materials derived from biomass waste, i.e., an epoxy resin obtained from cardanol and nanocellulose from unbleached hemp fibers. The composites were prepared by solvent exchange and an impregnation of the cellulosic mat with the resin, followe...

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Main Authors: Sara Dalle Vacche, Vijayaletchumy Karunakaran, Silvia Maria Ronchetti, Alessandra Vitale, Roberta Bongiovanni
Format: Article
Language:English
Published: MDPI AG 2021-01-01
Series:Journal of Composites Science
Subjects:
Online Access:https://www.mdpi.com/2504-477X/5/1/11
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author Sara Dalle Vacche
Vijayaletchumy Karunakaran
Silvia Maria Ronchetti
Alessandra Vitale
Roberta Bongiovanni
author_facet Sara Dalle Vacche
Vijayaletchumy Karunakaran
Silvia Maria Ronchetti
Alessandra Vitale
Roberta Bongiovanni
author_sort Sara Dalle Vacche
collection DOAJ
description Biobased composites were successfully prepared using raw materials derived from biomass waste, i.e., an epoxy resin obtained from cardanol and nanocellulose from unbleached hemp fibers. The composites were prepared by solvent exchange and an impregnation of the cellulosic mat with the resin, followed by photocuring. Quantitative conversion was obtained, despite the high amount of fibers (30 wt%) and their absorbance in the UV region of the light spectrum. X-ray diffraction confirmed that the crystalline structure of cellulose did not change during the impregnation and curing process. The cured composites were flexible, hydrophobic, water resistant, transparent with a yellow/brown color, and in the rubbery state at room temperature.
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spelling doaj.art-9121d5059a0e4fa98dd4c3f894e11d172023-11-21T07:54:51ZengMDPI AGJournal of Composites Science2504-477X2021-01-01511110.3390/jcs5010011Nanocellulose from Unbleached Hemp Fibers as a Filler for Biobased Photocured Composites with Epoxidized CardanolSara Dalle Vacche0Vijayaletchumy Karunakaran1Silvia Maria Ronchetti2Alessandra Vitale3Roberta Bongiovanni4Department of Applied Science and Technology, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Torino, ItalyDepartment of Applied Science and Technology, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Torino, ItalyDepartment of Applied Science and Technology, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Torino, ItalyDepartment of Applied Science and Technology, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Torino, ItalyDepartment of Applied Science and Technology, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Torino, ItalyBiobased composites were successfully prepared using raw materials derived from biomass waste, i.e., an epoxy resin obtained from cardanol and nanocellulose from unbleached hemp fibers. The composites were prepared by solvent exchange and an impregnation of the cellulosic mat with the resin, followed by photocuring. Quantitative conversion was obtained, despite the high amount of fibers (30 wt%) and their absorbance in the UV region of the light spectrum. X-ray diffraction confirmed that the crystalline structure of cellulose did not change during the impregnation and curing process. The cured composites were flexible, hydrophobic, water resistant, transparent with a yellow/brown color, and in the rubbery state at room temperature.https://www.mdpi.com/2504-477X/5/1/11biobased polymersphotocuringX-ray diffractionFourier-transform infrared spectroscopynanocellulosehemp
spellingShingle Sara Dalle Vacche
Vijayaletchumy Karunakaran
Silvia Maria Ronchetti
Alessandra Vitale
Roberta Bongiovanni
Nanocellulose from Unbleached Hemp Fibers as a Filler for Biobased Photocured Composites with Epoxidized Cardanol
Journal of Composites Science
biobased polymers
photocuring
X-ray diffraction
Fourier-transform infrared spectroscopy
nanocellulose
hemp
title Nanocellulose from Unbleached Hemp Fibers as a Filler for Biobased Photocured Composites with Epoxidized Cardanol
title_full Nanocellulose from Unbleached Hemp Fibers as a Filler for Biobased Photocured Composites with Epoxidized Cardanol
title_fullStr Nanocellulose from Unbleached Hemp Fibers as a Filler for Biobased Photocured Composites with Epoxidized Cardanol
title_full_unstemmed Nanocellulose from Unbleached Hemp Fibers as a Filler for Biobased Photocured Composites with Epoxidized Cardanol
title_short Nanocellulose from Unbleached Hemp Fibers as a Filler for Biobased Photocured Composites with Epoxidized Cardanol
title_sort nanocellulose from unbleached hemp fibers as a filler for biobased photocured composites with epoxidized cardanol
topic biobased polymers
photocuring
X-ray diffraction
Fourier-transform infrared spectroscopy
nanocellulose
hemp
url https://www.mdpi.com/2504-477X/5/1/11
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