Propane Pre-Reforming into Methane-Rich Gas over Ni Catalyst: Experiment and Kinetics Elucidation via Genetic Algorithm
Pre-reforming of propane was studied over an industrial nickel-chromium catalyst under pressures of 1 and 5 bar, at a low steam to carbon molar ratio of 1, in the temperature range of 220–380 °C and at flow rates of 4000 and 12,000 h<sup>−1</sup>. It was shown that propane conversion pro...
Main Authors: | , , , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
MDPI AG
2020-07-01
|
Series: | Energies |
Subjects: | |
Online Access: | https://www.mdpi.com/1996-1073/13/13/3393 |
_version_ | 1797563510171893760 |
---|---|
author | Sergey I. Uskov Dmitriy I. Potemkin Leniza V. Enikeeva Pavel V. Snytnikov Irek M. Gubaydullin Vladimir A. Sobyanin |
author_facet | Sergey I. Uskov Dmitriy I. Potemkin Leniza V. Enikeeva Pavel V. Snytnikov Irek M. Gubaydullin Vladimir A. Sobyanin |
author_sort | Sergey I. Uskov |
collection | DOAJ |
description | Pre-reforming of propane was studied over an industrial nickel-chromium catalyst under pressures of 1 and 5 bar, at a low steam to carbon molar ratio of 1, in the temperature range of 220–380 °C and at flow rates of 4000 and 12,000 h<sup>−1</sup>. It was shown that propane conversion proceeded more efficiently at low pressure (1 atm) and temperatures above 350 °C. A genetic algorithm was applied to search for kinetic parameters better fitting experimental results in such a wide range of experimental conditions. Power law and Langmuir–Hinshelwood kinetics were considered. It was shown that only Langmuir–Hinshelwood type kinetics correctly described the experimental data and could be used to simulate the process of propane pre-reforming and predict propane conversion under the given reaction conditions. The significance of Langmuir–Hinshelwood kinetics increases under high pressure and temperatures below 350 °C. |
first_indexed | 2024-03-10T18:44:40Z |
format | Article |
id | doaj.art-915f23a2c7834f278f9888034c573f21 |
institution | Directory Open Access Journal |
issn | 1996-1073 |
language | English |
last_indexed | 2024-03-10T18:44:40Z |
publishDate | 2020-07-01 |
publisher | MDPI AG |
record_format | Article |
series | Energies |
spelling | doaj.art-915f23a2c7834f278f9888034c573f212023-11-20T05:37:39ZengMDPI AGEnergies1996-10732020-07-011313339310.3390/en13133393Propane Pre-Reforming into Methane-Rich Gas over Ni Catalyst: Experiment and Kinetics Elucidation via Genetic AlgorithmSergey I. Uskov0Dmitriy I. Potemkin1Leniza V. Enikeeva2Pavel V. Snytnikov3Irek M. Gubaydullin4Vladimir A. Sobyanin5Boreskov Institute of Catalysis, Pr. Lavrentieva 5, Novosibirsk 630090, RussiaBoreskov Institute of Catalysis, Pr. Lavrentieva 5, Novosibirsk 630090, RussiaEnergy-Saving Catalytic Processes Laboratory, Novosibirsk State University, Pirogova St. 2, Novosibirsk 630090, RussiaBoreskov Institute of Catalysis, Pr. Lavrentieva 5, Novosibirsk 630090, RussiaTechnological Department, Ufa State Petroleum Technological University, Kosmonavtov St. 1, Ufa 450062, RussiaBoreskov Institute of Catalysis, Pr. Lavrentieva 5, Novosibirsk 630090, RussiaPre-reforming of propane was studied over an industrial nickel-chromium catalyst under pressures of 1 and 5 bar, at a low steam to carbon molar ratio of 1, in the temperature range of 220–380 °C and at flow rates of 4000 and 12,000 h<sup>−1</sup>. It was shown that propane conversion proceeded more efficiently at low pressure (1 atm) and temperatures above 350 °C. A genetic algorithm was applied to search for kinetic parameters better fitting experimental results in such a wide range of experimental conditions. Power law and Langmuir–Hinshelwood kinetics were considered. It was shown that only Langmuir–Hinshelwood type kinetics correctly described the experimental data and could be used to simulate the process of propane pre-reforming and predict propane conversion under the given reaction conditions. The significance of Langmuir–Hinshelwood kinetics increases under high pressure and temperatures below 350 °C.https://www.mdpi.com/1996-1073/13/13/3393liquefied petroleum gaspre-reformingpropanekineticsnickel catalystgenetic algorithm |
spellingShingle | Sergey I. Uskov Dmitriy I. Potemkin Leniza V. Enikeeva Pavel V. Snytnikov Irek M. Gubaydullin Vladimir A. Sobyanin Propane Pre-Reforming into Methane-Rich Gas over Ni Catalyst: Experiment and Kinetics Elucidation via Genetic Algorithm Energies liquefied petroleum gas pre-reforming propane kinetics nickel catalyst genetic algorithm |
title | Propane Pre-Reforming into Methane-Rich Gas over Ni Catalyst: Experiment and Kinetics Elucidation via Genetic Algorithm |
title_full | Propane Pre-Reforming into Methane-Rich Gas over Ni Catalyst: Experiment and Kinetics Elucidation via Genetic Algorithm |
title_fullStr | Propane Pre-Reforming into Methane-Rich Gas over Ni Catalyst: Experiment and Kinetics Elucidation via Genetic Algorithm |
title_full_unstemmed | Propane Pre-Reforming into Methane-Rich Gas over Ni Catalyst: Experiment and Kinetics Elucidation via Genetic Algorithm |
title_short | Propane Pre-Reforming into Methane-Rich Gas over Ni Catalyst: Experiment and Kinetics Elucidation via Genetic Algorithm |
title_sort | propane pre reforming into methane rich gas over ni catalyst experiment and kinetics elucidation via genetic algorithm |
topic | liquefied petroleum gas pre-reforming propane kinetics nickel catalyst genetic algorithm |
url | https://www.mdpi.com/1996-1073/13/13/3393 |
work_keys_str_mv | AT sergeyiuskov propaneprereformingintomethanerichgasovernicatalystexperimentandkineticselucidationviageneticalgorithm AT dmitriyipotemkin propaneprereformingintomethanerichgasovernicatalystexperimentandkineticselucidationviageneticalgorithm AT lenizavenikeeva propaneprereformingintomethanerichgasovernicatalystexperimentandkineticselucidationviageneticalgorithm AT pavelvsnytnikov propaneprereformingintomethanerichgasovernicatalystexperimentandkineticselucidationviageneticalgorithm AT irekmgubaydullin propaneprereformingintomethanerichgasovernicatalystexperimentandkineticselucidationviageneticalgorithm AT vladimirasobyanin propaneprereformingintomethanerichgasovernicatalystexperimentandkineticselucidationviageneticalgorithm |