Activated banana peel macrocomposite adsorbent for river water treatment: isotherm and kinetic studies

This study investigates the potential of a hybrid process combining sand filtration column with activated banana peels macrocomposite (ABPM) adsorbent for river water treatment. Scanning electron microscopy (SEM) analysis displayed an irregular structure and high cavities of the banana peel adsorben...

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Main Authors: Najeeha Mohd Apandi, Mimi Suliza Muhamad, Tan Wee Yek, Norshuhaila Mohamed Sunar, Ramathasan Nagarajah
Format: Article
Language:English
Published: IWA Publishing 2023-04-01
Series:Water Practice and Technology
Subjects:
Online Access:http://wpt.iwaponline.com/content/18/4/753
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author Najeeha Mohd Apandi
Mimi Suliza Muhamad
Tan Wee Yek
Norshuhaila Mohamed Sunar
Ramathasan Nagarajah
author_facet Najeeha Mohd Apandi
Mimi Suliza Muhamad
Tan Wee Yek
Norshuhaila Mohamed Sunar
Ramathasan Nagarajah
author_sort Najeeha Mohd Apandi
collection DOAJ
description This study investigates the potential of a hybrid process combining sand filtration column with activated banana peels macrocomposite (ABPM) adsorbent for river water treatment. Scanning electron microscopy (SEM) analysis displayed an irregular structure and high cavities of the banana peel adsorbent surface that caters to the deposition of contaminants, while energy-dispersive X-ray analysis detected major elements of the adsorbent, such as calcium, oxygen, silicon, and carbon. Fourier-transform infrared analysis of the banana peels adsorbent showed the presence of hydroxyl, acyl, amine, and alkene groups that were responsible for the adsorption process. The sand filtration column experiment was investigated to find out the removal of turbidity, biochemical oxygen demand (BOD), chemical oxygen demand (COD), total suspended solids (TSS), and ammonia nitrogen (AN) where it resulted in the highest removal efficiency operated at a flowrate of 1.15 ml/s with >90% turbidity, 44% COD, 87% BOD, 75% TSS, and 54% AN removal. The adsorption isotherm was best described by the Langmuir model (R2 > 0.98) compared to the Freundlich model (R2 > 0.95). The pseudo-first-order kinetic model was the best fit for all the experimental data. The combination of sand filtration column with ABPM adsorbent is an efficient treatment solution for improving river water quality. HIGHLIGHTS Studies on activated banana peels as an adsorbent is a remarkable function for water treatment.; Significantly reduces the fruit waste disposal in landfills and practices the waste-to-wealth concept.; Isotherm and kinetic studies also provide the best overall model for experimental data.; Banana peel has a valuable potential as a natural adsorbent.; Economical and reduces a negative impact on the environment.;
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spelling doaj.art-917a200b905c41a7ae347e73646112652023-05-09T09:58:08ZengIWA PublishingWater Practice and Technology1751-231X2023-04-0118475377010.2166/wpt.2023.050050Activated banana peel macrocomposite adsorbent for river water treatment: isotherm and kinetic studiesNajeeha Mohd Apandi0Mimi Suliza Muhamad1Tan Wee Yek2Norshuhaila Mohamed Sunar3Ramathasan Nagarajah4 Sustainable Engineering Technology Research Centre (SETecRC), Faculty of Civil Engineering Technology, University Tun Hussein Onn Malaysia, Pagoh Education Hub, 84600 Pagoh, Johor, Malaysia Sustainable Engineering Technology Research Centre (SETecRC), Faculty of Civil Engineering Technology, University Tun Hussein Onn Malaysia, Pagoh Education Hub, 84600 Pagoh, Johor, Malaysia Department of Civil Engineering Technology, Faculty of Civil Engineering Technology, Universiti Tun Hussein Onn Malaysia, Pagoh Education Hub, 84600 Pagoh, Johor, Malaysia Research Centre for Soft Soil (RECESS), Institute of Integrated Engineering, Universiti Tun Hussein Onn Malaysia, 86400 Batu Pahat, Johor, Malaysia Department of Civil Engineering Technology, Faculty of Civil Engineering Technology, Universiti Tun Hussein Onn Malaysia, Pagoh Education Hub, 84600 Pagoh, Johor, Malaysia This study investigates the potential of a hybrid process combining sand filtration column with activated banana peels macrocomposite (ABPM) adsorbent for river water treatment. Scanning electron microscopy (SEM) analysis displayed an irregular structure and high cavities of the banana peel adsorbent surface that caters to the deposition of contaminants, while energy-dispersive X-ray analysis detected major elements of the adsorbent, such as calcium, oxygen, silicon, and carbon. Fourier-transform infrared analysis of the banana peels adsorbent showed the presence of hydroxyl, acyl, amine, and alkene groups that were responsible for the adsorption process. The sand filtration column experiment was investigated to find out the removal of turbidity, biochemical oxygen demand (BOD), chemical oxygen demand (COD), total suspended solids (TSS), and ammonia nitrogen (AN) where it resulted in the highest removal efficiency operated at a flowrate of 1.15 ml/s with >90% turbidity, 44% COD, 87% BOD, 75% TSS, and 54% AN removal. The adsorption isotherm was best described by the Langmuir model (R2 > 0.98) compared to the Freundlich model (R2 > 0.95). The pseudo-first-order kinetic model was the best fit for all the experimental data. The combination of sand filtration column with ABPM adsorbent is an efficient treatment solution for improving river water quality. HIGHLIGHTS Studies on activated banana peels as an adsorbent is a remarkable function for water treatment.; Significantly reduces the fruit waste disposal in landfills and practices the waste-to-wealth concept.; Isotherm and kinetic studies also provide the best overall model for experimental data.; Banana peel has a valuable potential as a natural adsorbent.; Economical and reduces a negative impact on the environment.;http://wpt.iwaponline.com/content/18/4/753activated banana peels macrocomposite adsorbentadsorption isothermfreundlich modellangmuir modelriver watersand filtration column
spellingShingle Najeeha Mohd Apandi
Mimi Suliza Muhamad
Tan Wee Yek
Norshuhaila Mohamed Sunar
Ramathasan Nagarajah
Activated banana peel macrocomposite adsorbent for river water treatment: isotherm and kinetic studies
Water Practice and Technology
activated banana peels macrocomposite adsorbent
adsorption isotherm
freundlich model
langmuir model
river water
sand filtration column
title Activated banana peel macrocomposite adsorbent for river water treatment: isotherm and kinetic studies
title_full Activated banana peel macrocomposite adsorbent for river water treatment: isotherm and kinetic studies
title_fullStr Activated banana peel macrocomposite adsorbent for river water treatment: isotherm and kinetic studies
title_full_unstemmed Activated banana peel macrocomposite adsorbent for river water treatment: isotherm and kinetic studies
title_short Activated banana peel macrocomposite adsorbent for river water treatment: isotherm and kinetic studies
title_sort activated banana peel macrocomposite adsorbent for river water treatment isotherm and kinetic studies
topic activated banana peels macrocomposite adsorbent
adsorption isotherm
freundlich model
langmuir model
river water
sand filtration column
url http://wpt.iwaponline.com/content/18/4/753
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AT mimisulizamuhamad activatedbananapeelmacrocompositeadsorbentforriverwatertreatmentisothermandkineticstudies
AT tanweeyek activatedbananapeelmacrocompositeadsorbentforriverwatertreatmentisothermandkineticstudies
AT norshuhailamohamedsunar activatedbananapeelmacrocompositeadsorbentforriverwatertreatmentisothermandkineticstudies
AT ramathasannagarajah activatedbananapeelmacrocompositeadsorbentforriverwatertreatmentisothermandkineticstudies