Novel synthesis of (E) -α, β-unsaturated nitroalkenes((E)-α, β-不饱和硝基烯烃的高度区域选择性合成方法)
醛和硝基甲烷在甲醇和NaOH水溶液的混合溶液中在0 ℃反应，随后用稀盐酸处理，生成(E)-α，β-不饱和硝基烯烃单一化合物，反应有高度的区域选择性，收率较高(76%〜95%).合成方法便捷、高效、清洁，属于绿色合成.
| Main Authors: | , , , , , , |
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| Format: | Article |
| Language: | zho |
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Zhejiang University Press
2012-05-01
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| Series: | Zhejiang Daxue xuebao. Lixue ban |
| Subjects: | |
| Online Access: | https://doi.org/10.3785/j.issn.1008-9497.2012.03.015 |
| _version_ | 1827303192864489472 |
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| author | XIEJun-yi(谢隽毅) ZHANGBin(张斌) CHENRen-er(陈仁尔) ZHOUQi-zhong(周其忠) XUTu-gen(徐土根) YEYu-yuan(叶余原) JIANGHua-jiang(蒋华江) |
| author_facet | XIEJun-yi(谢隽毅) ZHANGBin(张斌) CHENRen-er(陈仁尔) ZHOUQi-zhong(周其忠) XUTu-gen(徐土根) YEYu-yuan(叶余原) JIANGHua-jiang(蒋华江) |
| author_sort | XIEJun-yi(谢隽毅) |
| collection | DOAJ |
| description | 醛和硝基甲烷在甲醇和NaOH水溶液的混合溶液中在0 ℃反应，随后用稀盐酸处理，生成(E)-α，β-不饱和硝基烯烃单一化合物，反应有高度的区域选择性，收率较高(76%〜95%).合成方法便捷、高效、清洁，属于绿色合成. |
| first_indexed | 2024-04-24T16:57:41Z |
| format | Article |
| id | doaj.art-919a51018f794c08838005ba2962f9e7 |
| institution | Directory Open Access Journal |
| issn | 1008-9497 |
| language | zho |
| last_indexed | 2024-04-24T16:57:41Z |
| publishDate | 2012-05-01 |
| publisher | Zhejiang University Press |
| record_format | Article |
| series | Zhejiang Daxue xuebao. Lixue ban |
| spelling | doaj.art-919a51018f794c08838005ba2962f9e72024-03-29T01:58:30ZzhoZhejiang University PressZhejiang Daxue xuebao. Lixue ban1008-94972012-05-0139330831210.3785/j.issn.1008-9497.2012.03.015Novel synthesis of (E) -α, β-unsaturated nitroalkenes((E)-α, β-不饱和硝基烯烃的高度区域选择性合成方法)XIEJun-yi(谢隽毅)0ZHANGBin(张斌)1CHENRen-er(陈仁尔)2ZHOUQi-zhong(周其忠)3XUTu-gen(徐土根)4YEYu-yuan(叶余原)5JIANGHua-jiang(蒋华江)6 1.Department of Chemistry, Taizhou University, Taizhou 317000, Zhejiang Province, China( 1.台州学院化学系，浙江 台州 317000) 2.College of Pharmacy, Zhejiang University of Technology, Hangzhou 310014, China( 2.浙江工业大学药学院，浙江 杭州 310014) 1.Department of Chemistry, Taizhou University, Taizhou 317000, Zhejiang Province, China( 1.台州学院化学系，浙江 台州 317000) 1.Department of Chemistry, Taizhou University, Taizhou 317000, Zhejiang Province, China( 1.台州学院化学系，浙江 台州 317000) 3.College of Material, Chemistry and Chemical Engineer, Hangzhou Normal University, Hangzhou 310036, China( 3.杭州师范大学材料与化学化工学院，浙江 杭州 310036) 1.Department of Chemistry, Taizhou University, Taizhou 317000, Zhejiang Province, China( 1.台州学院化学系，浙江 台州 317000) 1.Department of Chemistry, Taizhou University, Taizhou 317000, Zhejiang Province, China( 1.台州学院化学系，浙江 台州 317000)醛和硝基甲烷在甲醇和NaOH水溶液的混合溶液中在0 ℃反应，随后用稀盐酸处理，生成(E)-α，β-不饱和硝基烯烃单一化合物，反应有高度的区域选择性，收率较高(76%〜95%).合成方法便捷、高效、清洁，属于绿色合成.https://doi.org/10.3785/j.issn.1008-9497.2012.03.015醛硝基甲烷（e）-α，β-不饱和硝基烯烃 |
| spellingShingle | XIEJun-yi(谢隽毅) ZHANGBin(张斌) CHENRen-er(陈仁尔) ZHOUQi-zhong(周其忠) XUTu-gen(徐土根) YEYu-yuan(叶余原) JIANGHua-jiang(蒋华江) Novel synthesis of (E) -α, β-unsaturated nitroalkenes((E)-α, β-不饱和硝基烯烃的高度区域选择性合成方法) Zhejiang Daxue xuebao. Lixue ban 醛 硝基甲烷 （e）-α，β-不饱和硝基烯烃 |
| title | Novel synthesis of (E) -α, β-unsaturated nitroalkenes((E)-α, β-不饱和硝基烯烃的高度区域选择性合成方法) |
| title_full | Novel synthesis of (E) -α, β-unsaturated nitroalkenes((E)-α, β-不饱和硝基烯烃的高度区域选择性合成方法) |
| title_fullStr | Novel synthesis of (E) -α, β-unsaturated nitroalkenes((E)-α, β-不饱和硝基烯烃的高度区域选择性合成方法) |
| title_full_unstemmed | Novel synthesis of (E) -α, β-unsaturated nitroalkenes((E)-α, β-不饱和硝基烯烃的高度区域选择性合成方法) |
| title_short | Novel synthesis of (E) -α, β-unsaturated nitroalkenes((E)-α, β-不饱和硝基烯烃的高度区域选择性合成方法) |
| title_sort | novel synthesis of e α β unsaturated nitroalkenes e α β 不饱和硝基烯烃的高度区域选择性合成方法 |
| topic | 醛 硝基甲烷 （e）-α，β-不饱和硝基烯烃 |
| url | https://doi.org/10.3785/j.issn.1008-9497.2012.03.015 |
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