Study on the decomposition mechanism and insulation stability of HFO-1336mzz(E)/air mixtures as a new environment-friendly insulation medium under AC voltage
As one of hydrofluoroolefins (HFOs), HFO-1336mzz(E) is regarded as a promising eco-friendly alternative insulation medium to Sulfur Hexafluoride (SF6) owing to its excellent environmental effect and insulation property. To study the decomposition mechanism and insulation stability, the decomposition...
| Main Authors: | , , , , , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
AIP Publishing LLC
2023-04-01
|
| Series: | AIP Advances |
| Online Access: | http://dx.doi.org/10.1063/5.0134818 |
| _version_ | 1797771850417176576 |
|---|---|
| author | Nian Tang Jia Nie Jie Liu Dongwei Sun Li Li Zhenguo Liu Manjun Zhang Feng Wang Zhe Qu Yuzhu Hu |
| author_facet | Nian Tang Jia Nie Jie Liu Dongwei Sun Li Li Zhenguo Liu Manjun Zhang Feng Wang Zhe Qu Yuzhu Hu |
| author_sort | Nian Tang |
| collection | DOAJ |
| description | As one of hydrofluoroolefins (HFOs), HFO-1336mzz(E) is regarded as a promising eco-friendly alternative insulation medium to Sulfur Hexafluoride (SF6) owing to its excellent environmental effect and insulation property. To study the decomposition mechanism and insulation stability, the decomposition experiment of a 0.5 MPa mixture containing 8% HFO-1336mzz(E) and 92% air was performed under AC breakdown conditions. The results indicated that the main decomposition products were CF4, C2F6, C3F8, CF3H, CF3C=CH, CF3CH=CHF(E), CF3CHF2, CF3CH=CH2, CF2=CFH, CF2=CH2, CH≡CH, C4H2F6O, CF3O3CF3, etc. Among them, the generation of C3F8, CH≡CH, and C4H2F6O was relatively more difficult than others. Thus, these three compounds can be considered typical decomposition products. New elements, namely C, F, and N, appeared on the electrode surface after breakdowns compared to the state before breakdowns. It can be concluded that some complex chemical reactions were triggered between the electrode material and gas mixture under the action of breakdown discharge. Additionally, the breakdown voltage of the HFO-1336mzz(E)/air mixture almost remained unchanged, showing that the gas mixture still exhibited an excellent insulation stability after multiple breakdowns. |
| first_indexed | 2024-03-12T21:43:27Z |
| format | Article |
| id | doaj.art-91b8bd50c258440ab38a16a124520d2c |
| institution | Directory Open Access Journal |
| issn | 2158-3226 |
| language | English |
| last_indexed | 2024-03-12T21:43:27Z |
| publishDate | 2023-04-01 |
| publisher | AIP Publishing LLC |
| record_format | Article |
| series | AIP Advances |
| spelling | doaj.art-91b8bd50c258440ab38a16a124520d2c2023-07-26T14:57:20ZengAIP Publishing LLCAIP Advances2158-32262023-04-01134045007045007-1010.1063/5.0134818Study on the decomposition mechanism and insulation stability of HFO-1336mzz(E)/air mixtures as a new environment-friendly insulation medium under AC voltageNian Tang0Jia Nie1Jie Liu2Dongwei Sun3Li Li4Zhenguo Liu5Manjun Zhang6Feng Wang7Zhe Qu8Yuzhu Hu9Key Laboratory of Sulfur Hexafluoride of China Southern Power Grid Co., Ltd. (Electric Power Research Institute of Guangdong Power Grid Co., Ltd.), Guangzhou 510080, People’s Republic of ChinaCollege of Electrical and Information Engineering, Hunan University, Changsha 410082, People’s Republic of ChinaCollege of Electrical and Information Engineering, Hunan University, Changsha 410082, People’s Republic of ChinaKey Laboratory of Sulfur Hexafluoride of China Southern Power Grid Co., Ltd. (Electric Power Research Institute of Guangdong Power Grid Co., Ltd.), Guangzhou 510080, People’s Republic of ChinaKey Laboratory of Sulfur Hexafluoride of China Southern Power Grid Co., Ltd. (Electric Power Research Institute of Guangdong Power Grid Co., Ltd.), Guangzhou 510080, People’s Republic of ChinaKey Laboratory of Sulfur Hexafluoride of China Southern Power Grid Co., Ltd. (Electric Power Research Institute of Guangdong Power Grid Co., Ltd.), Guangzhou 510080, People’s Republic of ChinaKey Laboratory of Sulfur Hexafluoride of China Southern Power Grid Co., Ltd. (Electric Power Research Institute of Guangdong Power Grid Co., Ltd.), Guangzhou 510080, People’s Republic of ChinaCollege of Electrical and Information Engineering, Hunan University, Changsha 410082, People’s Republic of ChinaCollege of Electrical and Information Engineering, Hunan University, Changsha 410082, People’s Republic of ChinaCollege of Electrical and Information Engineering, Hunan University, Changsha 410082, People’s Republic of ChinaAs one of hydrofluoroolefins (HFOs), HFO-1336mzz(E) is regarded as a promising eco-friendly alternative insulation medium to Sulfur Hexafluoride (SF6) owing to its excellent environmental effect and insulation property. To study the decomposition mechanism and insulation stability, the decomposition experiment of a 0.5 MPa mixture containing 8% HFO-1336mzz(E) and 92% air was performed under AC breakdown conditions. The results indicated that the main decomposition products were CF4, C2F6, C3F8, CF3H, CF3C=CH, CF3CH=CHF(E), CF3CHF2, CF3CH=CH2, CF2=CFH, CF2=CH2, CH≡CH, C4H2F6O, CF3O3CF3, etc. Among them, the generation of C3F8, CH≡CH, and C4H2F6O was relatively more difficult than others. Thus, these three compounds can be considered typical decomposition products. New elements, namely C, F, and N, appeared on the electrode surface after breakdowns compared to the state before breakdowns. It can be concluded that some complex chemical reactions were triggered between the electrode material and gas mixture under the action of breakdown discharge. Additionally, the breakdown voltage of the HFO-1336mzz(E)/air mixture almost remained unchanged, showing that the gas mixture still exhibited an excellent insulation stability after multiple breakdowns.http://dx.doi.org/10.1063/5.0134818 |
| spellingShingle | Nian Tang Jia Nie Jie Liu Dongwei Sun Li Li Zhenguo Liu Manjun Zhang Feng Wang Zhe Qu Yuzhu Hu Study on the decomposition mechanism and insulation stability of HFO-1336mzz(E)/air mixtures as a new environment-friendly insulation medium under AC voltage AIP Advances |
| title | Study on the decomposition mechanism and insulation stability of HFO-1336mzz(E)/air mixtures as a new environment-friendly insulation medium under AC voltage |
| title_full | Study on the decomposition mechanism and insulation stability of HFO-1336mzz(E)/air mixtures as a new environment-friendly insulation medium under AC voltage |
| title_fullStr | Study on the decomposition mechanism and insulation stability of HFO-1336mzz(E)/air mixtures as a new environment-friendly insulation medium under AC voltage |
| title_full_unstemmed | Study on the decomposition mechanism and insulation stability of HFO-1336mzz(E)/air mixtures as a new environment-friendly insulation medium under AC voltage |
| title_short | Study on the decomposition mechanism and insulation stability of HFO-1336mzz(E)/air mixtures as a new environment-friendly insulation medium under AC voltage |
| title_sort | study on the decomposition mechanism and insulation stability of hfo 1336mzz e air mixtures as a new environment friendly insulation medium under ac voltage |
| url | http://dx.doi.org/10.1063/5.0134818 |
| work_keys_str_mv | AT niantang studyonthedecompositionmechanismandinsulationstabilityofhfo1336mzzeairmixturesasanewenvironmentfriendlyinsulationmediumunderacvoltage AT jianie studyonthedecompositionmechanismandinsulationstabilityofhfo1336mzzeairmixturesasanewenvironmentfriendlyinsulationmediumunderacvoltage AT jieliu studyonthedecompositionmechanismandinsulationstabilityofhfo1336mzzeairmixturesasanewenvironmentfriendlyinsulationmediumunderacvoltage AT dongweisun studyonthedecompositionmechanismandinsulationstabilityofhfo1336mzzeairmixturesasanewenvironmentfriendlyinsulationmediumunderacvoltage AT lili studyonthedecompositionmechanismandinsulationstabilityofhfo1336mzzeairmixturesasanewenvironmentfriendlyinsulationmediumunderacvoltage AT zhenguoliu studyonthedecompositionmechanismandinsulationstabilityofhfo1336mzzeairmixturesasanewenvironmentfriendlyinsulationmediumunderacvoltage AT manjunzhang studyonthedecompositionmechanismandinsulationstabilityofhfo1336mzzeairmixturesasanewenvironmentfriendlyinsulationmediumunderacvoltage AT fengwang studyonthedecompositionmechanismandinsulationstabilityofhfo1336mzzeairmixturesasanewenvironmentfriendlyinsulationmediumunderacvoltage AT zhequ studyonthedecompositionmechanismandinsulationstabilityofhfo1336mzzeairmixturesasanewenvironmentfriendlyinsulationmediumunderacvoltage AT yuzhuhu studyonthedecompositionmechanismandinsulationstabilityofhfo1336mzzeairmixturesasanewenvironmentfriendlyinsulationmediumunderacvoltage |