Bis[2-(1H-imidazol-2-yl-κN3)-1H-imidazol-3-ium]silver(I) trinitrate

The synthesis of the title salt, [Ag(C6H7N4)2](NO3)3, was carried out employing a 1:2 molar ratio of 2,2′-biimidazole and silver nitrate respectively. The cation has crystallographically-imposed C2 symmetry with the metal atom in an almost linear coordination environment [N&#82...

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Main Authors: Shelonda R. Finch, Johnathan P. Harper, Amitava Choudhury, Ekkehard Sinn, Harvest L. Collier
Format: Article
Language:English
Published: International Union of Crystallography 2011-07-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811021799
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author Shelonda R. Finch
Johnathan P. Harper
Amitava Choudhury
Ekkehard Sinn
Harvest L. Collier
author_facet Shelonda R. Finch
Johnathan P. Harper
Amitava Choudhury
Ekkehard Sinn
Harvest L. Collier
author_sort Shelonda R. Finch
collection DOAJ
description The synthesis of the title salt, [Ag(C6H7N4)2](NO3)3, was carried out employing a 1:2 molar ratio of 2,2′-biimidazole and silver nitrate respectively. The cation has crystallographically-imposed C2 symmetry with the metal atom in an almost linear coordination environment [N—Ag—N = 177.01 (17)°]. The crystal structure displays N—H...O and C—H...O hydrogen-bonding interactions.
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spelling doaj.art-91c4c4119b174c4ab74bc7353d14be822022-12-21T20:01:07ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-07-01677m909m90910.1107/S1600536811021799Bis[2-(1H-imidazol-2-yl-κN3)-1H-imidazol-3-ium]silver(I) trinitrateShelonda R. FinchJohnathan P. HarperAmitava ChoudhuryEkkehard SinnHarvest L. CollierThe synthesis of the title salt, [Ag(C6H7N4)2](NO3)3, was carried out employing a 1:2 molar ratio of 2,2′-biimidazole and silver nitrate respectively. The cation has crystallographically-imposed C2 symmetry with the metal atom in an almost linear coordination environment [N—Ag—N = 177.01 (17)°]. The crystal structure displays N—H...O and C—H...O hydrogen-bonding interactions.http://scripts.iucr.org/cgi-bin/paper?S1600536811021799
spellingShingle Shelonda R. Finch
Johnathan P. Harper
Amitava Choudhury
Ekkehard Sinn
Harvest L. Collier
Bis[2-(1H-imidazol-2-yl-κN3)-1H-imidazol-3-ium]silver(I) trinitrate
Acta Crystallographica Section E
title Bis[2-(1H-imidazol-2-yl-κN3)-1H-imidazol-3-ium]silver(I) trinitrate
title_full Bis[2-(1H-imidazol-2-yl-κN3)-1H-imidazol-3-ium]silver(I) trinitrate
title_fullStr Bis[2-(1H-imidazol-2-yl-κN3)-1H-imidazol-3-ium]silver(I) trinitrate
title_full_unstemmed Bis[2-(1H-imidazol-2-yl-κN3)-1H-imidazol-3-ium]silver(I) trinitrate
title_short Bis[2-(1H-imidazol-2-yl-κN3)-1H-imidazol-3-ium]silver(I) trinitrate
title_sort bis 2 1h imidazol 2 yl amp 954 n3 1h imidazol 3 ium silver i trinitrate
url http://scripts.iucr.org/cgi-bin/paper?S1600536811021799
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