Dielectric property of NiTiO3 doped substituted ortho-chloropolyaniline composites
Ortho-chloropolyaniline (OCP)-NiTiO3 composites have been synthesized via in-situ polymerization of ortho-chloroaniline with various weight percentages of NiTiO3. Fourier Transform Infrared spectroscopic studies of Ortho-chloropolyaniline and its composites indicated the formation of composites as a...
| Main Authors: | , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
AIP Publishing LLC
2013-11-01
|
| Series: | AIP Advances |
| Online Access: | http://dx.doi.org/10.1063/1.4832223 |
| _version_ | 1818020787756466176 |
|---|---|
| author | Mohana Lakshmi Aashish S. Roy Syed Khasim Muhammad Faisal K. C. Sajjan M. Revanasiddappa |
| author_facet | Mohana Lakshmi Aashish S. Roy Syed Khasim Muhammad Faisal K. C. Sajjan M. Revanasiddappa |
| author_sort | Mohana Lakshmi |
| collection | DOAJ |
| description | Ortho-chloropolyaniline (OCP)-NiTiO3 composites have been synthesized via in-situ polymerization of ortho-chloroaniline with various weight percentages of NiTiO3. Fourier Transform Infrared spectroscopic studies of Ortho-chloropolyaniline and its composites indicated the formation of composites as a result of Vander Waal's interaction between OCP and NiTiO3 particles. Surface morphology of OCP and OCP-NiTiO3 composites were studied using Scanning Electron Microscope (SEM). The SEM micrographs indicated a modified morphology after the composite formation. Dielectric properties and electric modulus of OCP and OCP-NiTiO3 composites have been investigated in the frequency range of 50 Hz – 5 MHz. It has been noticed that electrical resistance decreases with increase in weight percentage of NiTiO3 particles in polymer matrix as well as with applied frequency. The display of semicircular arcs in Cole-Cole plots indicates the formation of series resistor and capacitor in network causing a decrease in the relaxation time and as a result conductivity enhances in these composites. The facile and cost effective synthesis process and excellent dielectric and conductivity response of these materials makes them promising materials for practical applications. |
| first_indexed | 2024-04-14T08:10:02Z |
| format | Article |
| id | doaj.art-91e7f4326cd74325aa048986c55d2feb |
| institution | Directory Open Access Journal |
| issn | 2158-3226 |
| language | English |
| last_indexed | 2024-04-14T08:10:02Z |
| publishDate | 2013-11-01 |
| publisher | AIP Publishing LLC |
| record_format | Article |
| series | AIP Advances |
| spelling | doaj.art-91e7f4326cd74325aa048986c55d2feb2022-12-22T02:04:34ZengAIP Publishing LLCAIP Advances2158-32262013-11-01311112113112113-1410.1063/1.4832223013311ADVDielectric property of NiTiO3 doped substituted ortho-chloropolyaniline compositesMohana Lakshmi0Aashish S. Roy1Syed Khasim2Muhammad Faisal3K. C. Sajjan4M. Revanasiddappa5Department of Physics, PES Institute of Technology, BSC, Bangalore- 560100, IndiaDepartment of Materials Science, Gulbarga University, Gulbarga-585106, Karnataka, IndiaDepartment of Physics, PES Institute of Technology, BSC, Bangalore- 560100, IndiaDepartment of Physics, PES Institute of Technology, BSC, Bangalore- 560100, IndiaDepartment of Physics, Veerashaiva College, Bellary - 583 104, Karnataka, IndiaDepartment of Chemistry, PES Institute of Technology, BSC, Bangalore - 560100, IndiaOrtho-chloropolyaniline (OCP)-NiTiO3 composites have been synthesized via in-situ polymerization of ortho-chloroaniline with various weight percentages of NiTiO3. Fourier Transform Infrared spectroscopic studies of Ortho-chloropolyaniline and its composites indicated the formation of composites as a result of Vander Waal's interaction between OCP and NiTiO3 particles. Surface morphology of OCP and OCP-NiTiO3 composites were studied using Scanning Electron Microscope (SEM). The SEM micrographs indicated a modified morphology after the composite formation. Dielectric properties and electric modulus of OCP and OCP-NiTiO3 composites have been investigated in the frequency range of 50 Hz – 5 MHz. It has been noticed that electrical resistance decreases with increase in weight percentage of NiTiO3 particles in polymer matrix as well as with applied frequency. The display of semicircular arcs in Cole-Cole plots indicates the formation of series resistor and capacitor in network causing a decrease in the relaxation time and as a result conductivity enhances in these composites. The facile and cost effective synthesis process and excellent dielectric and conductivity response of these materials makes them promising materials for practical applications.http://dx.doi.org/10.1063/1.4832223 |
| spellingShingle | Mohana Lakshmi Aashish S. Roy Syed Khasim Muhammad Faisal K. C. Sajjan M. Revanasiddappa Dielectric property of NiTiO3 doped substituted ortho-chloropolyaniline composites AIP Advances |
| title | Dielectric property of NiTiO3 doped substituted ortho-chloropolyaniline composites |
| title_full | Dielectric property of NiTiO3 doped substituted ortho-chloropolyaniline composites |
| title_fullStr | Dielectric property of NiTiO3 doped substituted ortho-chloropolyaniline composites |
| title_full_unstemmed | Dielectric property of NiTiO3 doped substituted ortho-chloropolyaniline composites |
| title_short | Dielectric property of NiTiO3 doped substituted ortho-chloropolyaniline composites |
| title_sort | dielectric property of nitio3 doped substituted ortho chloropolyaniline composites |
| url | http://dx.doi.org/10.1063/1.4832223 |
| work_keys_str_mv | AT mohanalakshmi dielectricpropertyofnitio3dopedsubstitutedorthochloropolyanilinecomposites AT aashishsroy dielectricpropertyofnitio3dopedsubstitutedorthochloropolyanilinecomposites AT syedkhasim dielectricpropertyofnitio3dopedsubstitutedorthochloropolyanilinecomposites AT muhammadfaisal dielectricpropertyofnitio3dopedsubstitutedorthochloropolyanilinecomposites AT kcsajjan dielectricpropertyofnitio3dopedsubstitutedorthochloropolyanilinecomposites AT mrevanasiddappa dielectricpropertyofnitio3dopedsubstitutedorthochloropolyanilinecomposites |