Five Bonds to Carbon through Tri-Coordination in
<inline-formula><math display="inline"><semantics><mrow><msub><mrow><mi>Al</mi></mrow><mn>3</mn></msub><msubsup><mi mathvariant="normal">C</mi><mn>3</mn><mrow><mo>−</mo><mo>/</mo><mn>0</mn></mrow></msubsup></mrow></semantics></math></inline-formula>

Five Bonds to Carbon through Tri-Coordination in <inline-formula><math display="inline"><semantics><mrow><msub><mrow><mi>Al</mi></mrow><mn>3</mn></msub><msubsup><mi mathvariant="normal">C</mi><mn>3</mn><mrow><mo>−</mo><mo>/</mo><mn>0</mn></mrow></msubsup></mrow></semantics></math></inline-formula>

Here, five bonds to carbon through tri-coordination are theoretically established in the global minimum energy isomers of <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><msub><mrow><mi>A...

Full description

Bibliographic Details
Main Authors:	Abdul Hamid Malhan, Venkatesan S. Thimmakondu, Krishnan Thirumoorthy
Format:	Article
Language:	English
Published:	MDPI AG 2023-05-01
Series:	Chemistry
Subjects:	<named-content content-type="inline-formula"><inline-formula><mml:math id="mm5"><mml:semantics><mml:mrow><mml:msub><mml:mrow><mml:mi>Al</mml:mi></mml:mrow><mml:mn>3</mml:mn></mml:msub><mml:msubsup><mml:mi mathvariant="normal">C</mml:mi><mml:mn>3</mml:mn><mml:mrow><mml:mo>−</mml:mo><mml:mo>/</mml:mo><mml:mn>0</mml:mn></mml:mrow></mml:msubsup></mml:mrow></mml:semantics></mml:math></inline-formula></named-content> five bonds to carbon anti-van’t Hoff-Le Bel σ-aromaticity π-aromaticity bonding
Online Access:	https://www.mdpi.com/2624-8549/5/2/76

Similar Items

Response of Soil Respiration to Simulated Acid Rain with Different Ratios of <inline-formula><math display="inline"><semantics><mrow><msubsup><mrow><mi mathvariant="bold">SO</mi></mrow><mn mathvariant="bold">4</mn><mrow><mn mathvariant="bold">2</mn><mo mathvariant="bold">−</mo></mrow></msubsup></mrow></semantics></math></inline-formula> to <inline-formula><math display="inline"><semantics><mrow><msubsup><mrow><mi mathvariant="bold">NO</mi></mrow><mn mathvariant="bold">3</mn><mo mathvariant="bold">−</mo></msubsup></mrow></semantics></math></inline-formula> in <i>Cunninghamia lanceolata</i> (Lamb.) Hook. and <i>Michelia macclurei</i> Dandy Plantations
by: Jiao Wang, et al.
Published: (2022-11-01)

<inline-formula><math display="inline"><semantics><mrow><msub><mrow><mi mathvariant="normal">S</mi></mrow><mrow><mn>2</mn></mrow></msub><msubsup><mrow><mi mathvariant="normal">O</mi></mrow><mrow><mn>8</mn></mrow><mrow><mn>2</mn><mo>−</mo></mrow></msubsup></mrow></semantics></math></inline-formula>/CeO<sub>2</sub> Solid Superacid Catalyst Prepared by Radio-Frequency Plasma-Assisted Hydrothermal Method
by: Kaiqiang Wang, et al.
Published: (2023-10-01)

Fe<inline-formula><math display="inline"><semantics><mrow><msub><mi mathvariant="bold">C</mi><mn mathvariant="bold">4</mn></msub><msubsup><mi mathvariant="bold">H</mi><mn mathvariant="bold">2</mn><mrow><mrow><mn mathvariant="bold">2</mn><mo mathvariant="bold">+</mo></mrow></mrow></msubsup></mrow></semantics></math></inline-formula> Encompassing Planar Tetracoordinate Iron: Structure and Bonding Patterns
by: Shilpa Shajan, et al.
Published: (2024-02-01)

Adaptive Neuro-Fuzzy Control of Active Vehicle Suspension Based on <inline-formula><math display="inline"><semantics><mrow><msub><mrow><mi mathvariant="bold-italic">H</mi></mrow><mrow><mn mathvariant="bold">2</mn></mrow></msub></mrow></semantics></math></inline-formula> and <inline-formula><math display="inline"><semantics><mrow><msub><mrow><mi mathvariant="bold-italic">H</mi></mrow><mrow><mstyle mathvariant="bold"><mo>∞</mo></mstyle></mrow></msub></mrow></semantics></math></inline-formula> Synthesis
by: Jaffar Seyyed Esmaeili, et al.
Published: (2023-11-01)

Analysis of <inline-formula><math display="inline"><semantics><mrow><msubsup><mi mathvariant="bold-italic">B</mi><mrow><mo mathvariant="bold">(</mo><mi mathvariant="bold-italic">s</mi><mo mathvariant="bold">)</mo></mrow><mn mathvariant="bold">0</mn></msubsup></mrow></semantics></math></inline-formula> → <i>μ</i><sup>+</sup><i>μ</i><sup>−</sup> Decays at the Large Hadron Collider
by: Kai-Feng Chen, et al.
Published: (2024-02-01)

The <inline-formula><math display="inline"><semantics><mrow><msub><mrow><mi mathvariant="bold-script">T</mi></mrow><mrow><mi mathvariant="bold">e</mi></mrow></msub></mrow></semantics></math></inline-formula> Transform: A High-Resolution Integral Transform and Its Key Properties
by: Eduardo Trutié-Carrero, et al.
Published: (2023-10-01)

The Degradation of Aqueous Oxytetracycline by an O<sub>3</sub>/CaO<sub>2</sub> System in the Presence of <inline-formula><math display="inline"><semantics><mrow><msubsup><mrow><mi mathvariant="bold">HCO</mi></mrow><mn mathvariant="bold">3</mn><mo mathvariant="bold">−</mo></msubsup></mrow></semantics></math></inline-formula>: Performance, Mechanism, Degradation Pathways, and Toxicity Evaluation
by: Zedian Li, et al.
Published: (2024-01-01)

<inline-formula><math display="inline"><semantics><mrow><msub><mrow><mi mathvariant="normal">C</mi></mrow><mrow><mn>2</mn></mrow></msub><mi mathvariant="normal">O</mi></mrow></semantics></math></inline-formula> Nanotubes with Negative Strain Energies and Improvements of Thermoelectric Properties via N-Doping Predicted from First-Principle Calculations
by: Jianbao Wu, et al.
Published: (2023-07-01)

(<inline-formula><math display="inline"><semantics><mrow><mover accent="true"><mo mathvariant="bold">∈</mo><mo mathvariant="bold">´</mo></mover><mo mathvariant="bold">,</mo><mover accent="true"><mo mathvariant="bold">∈</mo><mo mathvariant="bold">´</mo></mover><mo mathvariant="bold">∨</mo><msub><mover accent="true"><mi mathvariant="bold-italic">q</mi><mo mathvariant="bold">´</mo></mover><mover accent="true"><mi mathvariant="bold-italic">k</mi><mo mathvariant="bold">ˇ</mo></mover></msub></mrow></semantics></math></inline-formula>)-Uni-Intuitionistic Fuzzy Soft h-Ideals in Subtraction BG-Algebras
by: Manivannan Balamurugan, et al.
Published: (2023-05-01)

Multipurpose Quantum Simulator Based on a Hybrid Solid-State Quantum Device
by: Tingting Yuan, et al.
Published: (2019-04-01)

Accumulation and Distribution of Fertilizer Nitrogen and Nodule-Fixed Nitrogen in Soybeans with Dual Root Systems
by: Rui Zhang, et al.
Published: (2020-03-01)

<inline-formula><math display="inline"><semantics><mrow><mi>S</mi><mi>L</mi><mo>(</mo><mn>2</mn><mo>,</mo><mi mathvariant="double-struck">C</mi><mo>)</mo></mrow></semantics></math></inline-formula> Scheme Processing of Singularities in Quantum Computing and Genetics
by: Michel Planat, et al.
Published: (2023-02-01)

Enhanced Degradation of Deltamethrin in Water through Ferrous Ion Activated Sulfite: Efficiency and Mechanistic Insights
by: Ying Wan, et al.
Published: (2023-12-01)

Classification of Irreducible <inline-formula><math display="inline"><semantics><mrow><msub><mi mathvariant="double-struck">Z</mi><mo>+</mo></msub></mrow></semantics></math></inline-formula>-Modules of a <inline-formula><math display="inline"><semantics><mrow><msub><mi mathvariant="double-struck">Z</mi><mo>+</mo></msub></mrow></semantics></math></inline-formula>-Ring Using Matrix Equations
by: Zhichao Chen, et al.
Published: (2022-12-01)

Effect of Strain Rate on Nano-Scale Mechanical Behavior of A-Plane (<inline-formula><math display="inline"><semantics><mrow><mn>11</mn><mover accent="true"><mn>2</mn><mo>¯</mo></mover><mn>0</mn></mrow></semantics></math></inline-formula>) ZnO Single Crystal by Nanoindentation
by: Xiaolin Zhu, et al.
Published: (2023-02-01)

<inline-formula><math display="inline"><semantics><mrow><mi>f</mi><mo>(</mo><mi mathvariant="script">R</mi><mo>,</mo><mi mathvariant="script">T</mi><mo>)</mo></mrow></semantics></math></inline-formula>-Gravity Model with Perfect Fluid Admitting Einstein Solitons
by: Mohd Danish Siddiqi, et al.
Published: (2021-12-01)

On Translation Curves and Geodesics in <inline-formula><math display="inline"><semantics><msubsup><mrow><mi>Sol</mi></mrow><mn>1</mn><mn>4</mn></msubsup></semantics></math></inline-formula>
by: Zlatko Erjavec, et al.
Published: (2023-04-01)

<i>n</i><sub>0</sub>-Order Weighted Pseudo Δ-Almost Automorphic Functions and Abstract Dynamic Equations
by: Chao Wang, et al.
Published: (2019-08-01)

Dynamic Changes in Reactive Oxygen Species in the Shoot Apex Contribute to Stem Cell Death in <i>Arabidopsis thaliana</i>
by: Yukun Wang, et al.
Published: (2022-03-01)

Feature Extraction of a Non-Stationary Seismic–Acoustic Signal Using a High-Resolution Dyadic Spectrogram
by: Diego Seuret-Jiménez, et al.
Published: (2023-06-01)

Riemannian Structures on <inline-formula> <mml:math id="mm1" display="block"> <mml:semantics> <mml:msubsup> <mml:mi mathvariant="double-struck">Z</mml:mi> <mml:mn>2</mml:mn> <mml:mi>n</mml:mi> </mml:msubsup> </mml:semantics> </mml:math> </inline-formula>-Manifolds
by: Andrew James Bruce, et al.
Published: (2020-09-01)

On Relational Weak <inline-formula><math display="inline"><semantics><mfenced separators="" open="(" close=")"><msubsup><mi mathvariant="bold-italic">F</mi><mrow><mstyle mathvariant="bold"><mo>ℜ</mo></mstyle></mrow><mi mathvariant="bold-italic">m</mi></msubsup><mo>,</mo><mi mathvariant="sans-serif-bold-italic">η</mi></mfenced></semantics></math></inline-formula>-Contractive Mappings and Their Applications
by: Muhammad Tariq, et al.
Published: (2023-04-01)

On Modified Interpolative Almost <inline-formula><math display="inline"><semantics><mrow><mi mathvariant="script">E</mi><mo>−</mo></mrow></semantics></math></inline-formula>Type Contraction in Partial Modular <inline-formula><math display="inline"><semantics><mrow><mi>b</mi><mo>−</mo></mrow></semantics></math></inline-formula>Metric Spaces
by: Dilek Kesik, et al.
Published: (2023-07-01)

Amateur Female Athletes Perform the Running Split of a Triathlon Race at Higher Relative Intensity than the Male Athletes: A Cross-Sectional Study
by: Guilherme Corrêa De Araújo Moury Fernandes, et al.
Published: (2023-02-01)

On Generalized Closed Sets and Generalized Pre-Closed Sets in Neutrosophic Topological Spaces
by: Wadei Al-Omeri, et al.
Published: (2018-12-01)

<math id="mm2777"><semantics><mrow><mi>T</mi><mover accent="true"><mi>T</mi><mo stretchy="false">¯</mo></mover></mrow></semantics></math> Deformation: A Lattice Approach
by: Yunfeng Jiang
Published: (2023-12-01)

On Some Expansion Formulas for Products of Jacobi’s Theta Functions
by: Hong-Cun Zhai, et al.
Published: (2023-01-01)

Geodesics and Translation Curves in <inline-formula><math display="inline"><semantics><msubsup><mi>Sol</mi><mn>0</mn><mn>4</mn></msubsup></semantics></math></inline-formula>
by: Zlatko Erjavec
Published: (2023-03-01)

Hydrogen’s Effect on the Shape Memory Effect of TiNi Alloy Single Crystals
by: Irina V. Kireeva, et al.
Published: (2023-07-01)

Categories of Open Sets in Generalized Primal Topological Spaces
by: Hanan Al-Saadi, et al.
Published: (2024-01-01)

Sex Differences in Maximal Oxygen Uptake Adjusted for Skeletal Muscle Mass in Amateur Endurance Athletes: A Cross Sectional Study
by: Higgor Amadeus Martins, et al.
Published: (2023-05-01)

Sobolev Estimates for the <inline-formula><math display="inline"><semantics><mover accent="true"><mo>∂</mo><mo>¯</mo></mover></semantics></math></inline-formula> and the <inline-formula><math display="inline"><semantics><mover accent="true"><mo>∂</mo><mo>¯</mo></mover></semantics></math></inline-formula>-Neumann Operator on Pseudoconvex Manifolds
by: Haroun Doud Soliman Adam, et al.
Published: (2023-09-01)

The Convergence and Boundedness of Solutions to SFDEs with the G-Framework
by: Rahman Ullah, et al.
Published: (2024-01-01)

On Discrete Weighted Lorentz Spaces and Equivalent Relations between Discrete <i>ℓ<sub>p</sub></i>-Classes
by: Ravi P. Agarwal, et al.
Published: (2023-03-01)

Training-Induced Increase in <inline-formula><math display="inline"><semantics><mrow><mover><mi mathvariant="normal">V</mi><mo stretchy="false">·</mo></mover></mrow></semantics></math></inline-formula>O<sub>2max</sub> and Critical Power, and Acceleration of <inline-formula><math display="inline"><semantics><mrow><mover><mi mathvariant="normal">V</mi><mo stretchy="false">·</mo></mover></mrow></semantics></math></inline-formula>O<sub>2</sub> on-Kinetics Result from Attenuated P<sub>i</sub> Increase Caused by Elevated OXPHOS Activity
by: Bernard Korzeniewski
Published: (2023-10-01)

Detection of Background Water Leaks Using a High-Resolution Dyadic Transform
by: Eduardo Trutié-Carrero, et al.
Published: (2023-02-01)

The Relationship between the IC<sub>50</sub> Values and the Apparent Inhibition Constant in the Study of Inhibitors of Tyrosinase Diphenolase Activity Helps Confirm the Mechanism of Inhibition
by: Pablo Garcia-Molina, et al.
Published: (2022-05-01)

An Analysis of the Convergence Problem of a Function in Functional Norms by Applying the Generalized Nörlund-Matrix Product Operator
by: Hari M. Srivastava, et al.
Published: (2023-08-01)

Uncovering Hidden Insights with Long-Memory Process Detection: An In-Depth Overview
by: Hossein Hassani, et al.
Published: (2023-06-01)

A Method for Performing the Symmetric Anti-Difference Equations in Quantum Fractional Calculus
by: V. Rexma Sherine, et al.
Published: (2022-12-01)