Microwave-Assisted Synthesis of Zeolite A from Metakaolinite for CO<sub>2</sub> Adsorption

The global demand for energy and industrial growth has generated an exponential use of fossil fuels in recent years. It is well known that carbon dioxide (CO<sub>2</sub>) is mainly produced, but not only from fuels, which has a negative impact on the environment, such as the increasing e...

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Bibliographic Details
Main Authors: Marilia R. Oliveira, Juan A. Cecilia, Daniel Ballesteros-Plata, Isabel Barroso-Martín, Pedro Núñez, Antonia Infantes-Molina, Enrique Rodríguez-Castellón
Format: Article
Language:English
Published: MDPI AG 2023-09-01
Series:International Journal of Molecular Sciences
Subjects:
Online Access:https://www.mdpi.com/1422-0067/24/18/14040
Description
Summary:The global demand for energy and industrial growth has generated an exponential use of fossil fuels in recent years. It is well known that carbon dioxide (CO<sub>2</sub>) is mainly produced, but not only from fuels, which has a negative impact on the environment, such as the increasing emission of greenhouse gases. Thus, thinking about reducing this problem, this study analyzes microwave irradiation as an alternative to conventional heating to optimize zeolite A synthesis conditions for CO<sub>2</sub> capture. Synthesis reaction parameters such as different temperatures (60–150 °C) and different time durations (1–6 h) were evaluated. The CO<sub>2</sub> adsorption capacity was evaluated by CO<sub>2</sub> adsorption–desorption isotherms at 25 °C and atmospheric pressure. The results showed that the synthesis of zeolite A by microwave irradiation was successfully obtained from natural kaolinite (via metakaolinization), reducing both temperature and time. Adsorption isotherms show that the most promising adsorbent for CO<sub>2</sub> capture is a zeolite synthesized at 100 °C for 4 h, which reached an adsorption capacity of 2.2 mmol/g.
ISSN:1661-6596
1422-0067