Synthesis, characterization and spectroscopic studies of the dihydrobis(1,2,3-benzotriazolyl)borate anion and its complexes with MCl2·py2
The preparation of sodium dihydrobis(1,2,3-benzotriazolyl)borate was realised by refluxing one mole of sodium borohydride with two moles of 1,2,3-benzotriazole in toluene over a period of 12 h. Its complexes with MCl2·py2 [where M= Mn(II), Fe(II), Co(II), Ni(II), Cu(II) and py = Pyridine] were chara...
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| Format: | Article |
| Language: | English |
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Serbian Chemical Society
2006-01-01
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| Series: | Journal of the Serbian Chemical Society |
| Subjects: | |
| Online Access: | http://www.doiserbia.nb.rs/img/doi/0352-5139/2006/0352-51390611137S.pdf |
| _version_ | 1831707054524334080 |
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| author | Siddiqi Khwaja S. Umar Ahmad Nami Shahab A. A. Khan Sadaf |
| author_facet | Siddiqi Khwaja S. Umar Ahmad Nami Shahab A. A. Khan Sadaf |
| author_sort | Siddiqi Khwaja S. |
| collection | DOAJ |
| description | The preparation of sodium dihydrobis(1,2,3-benzotriazolyl)borate was realised by refluxing one mole of sodium borohydride with two moles of 1,2,3-benzotriazole in toluene over a period of 12 h. Its complexes with MCl2·py2 [where M= Mn(II), Fe(II), Co(II), Ni(II), Cu(II) and py = Pyridine] were characterized by elemental analysis as well as magnetic, spectroscopic and conductivity measurements. On the basis of these studies, it is proposed that the geometry of all the complexes is octahedral. The ligand field parameters 10 Dq, B and β show extensive overlap between the M-L orbital. The molar conductance of 10-3Msolutions of the complexes in DMSO suggest them to be non-ionic in nature. |
| first_indexed | 2024-12-20T18:11:06Z |
| format | Article |
| id | doaj.art-920d7c65546946d8a3380c96bccd5ba2 |
| institution | Directory Open Access Journal |
| issn | 0352-5139 1820-7421 |
| language | English |
| last_indexed | 2024-12-20T18:11:06Z |
| publishDate | 2006-01-01 |
| publisher | Serbian Chemical Society |
| record_format | Article |
| series | Journal of the Serbian Chemical Society |
| spelling | doaj.art-920d7c65546946d8a3380c96bccd5ba22022-12-21T19:30:28ZengSerbian Chemical SocietyJournal of the Serbian Chemical Society0352-51391820-74212006-01-0171111137114510.2298/JSC0611137S0352-51390611137SSynthesis, characterization and spectroscopic studies of the dihydrobis(1,2,3-benzotriazolyl)borate anion and its complexes with MCl2·py2Siddiqi Khwaja S.0Umar Ahmad1Nami Shahab A. A.2Khan Sadaf3Department of chemistry, Aligarh Muslim University, AligarhDepartment of chemistry, Aligarh Muslim University, AligarhDepartment of chemistry, Aligarh Muslim University, AligarhDepartment of chemistry, Aligarh Muslim University, AligarhThe preparation of sodium dihydrobis(1,2,3-benzotriazolyl)borate was realised by refluxing one mole of sodium borohydride with two moles of 1,2,3-benzotriazole in toluene over a period of 12 h. Its complexes with MCl2·py2 [where M= Mn(II), Fe(II), Co(II), Ni(II), Cu(II) and py = Pyridine] were characterized by elemental analysis as well as magnetic, spectroscopic and conductivity measurements. On the basis of these studies, it is proposed that the geometry of all the complexes is octahedral. The ligand field parameters 10 Dq, B and β show extensive overlap between the M-L orbital. The molar conductance of 10-3Msolutions of the complexes in DMSO suggest them to be non-ionic in nature.http://www.doiserbia.nb.rs/img/doi/0352-5139/2006/0352-51390611137S.pdfboratetransition metal complexesspectroscopy |
| spellingShingle | Siddiqi Khwaja S. Umar Ahmad Nami Shahab A. A. Khan Sadaf Synthesis, characterization and spectroscopic studies of the dihydrobis(1,2,3-benzotriazolyl)borate anion and its complexes with MCl2·py2 Journal of the Serbian Chemical Society borate transition metal complexes spectroscopy |
| title | Synthesis, characterization and spectroscopic studies of the dihydrobis(1,2,3-benzotriazolyl)borate anion and its complexes with MCl2·py2 |
| title_full | Synthesis, characterization and spectroscopic studies of the dihydrobis(1,2,3-benzotriazolyl)borate anion and its complexes with MCl2·py2 |
| title_fullStr | Synthesis, characterization and spectroscopic studies of the dihydrobis(1,2,3-benzotriazolyl)borate anion and its complexes with MCl2·py2 |
| title_full_unstemmed | Synthesis, characterization and spectroscopic studies of the dihydrobis(1,2,3-benzotriazolyl)borate anion and its complexes with MCl2·py2 |
| title_short | Synthesis, characterization and spectroscopic studies of the dihydrobis(1,2,3-benzotriazolyl)borate anion and its complexes with MCl2·py2 |
| title_sort | synthesis characterization and spectroscopic studies of the dihydrobis 1 2 3 benzotriazolyl borate anion and its complexes with mcl2·py2 |
| topic | borate transition metal complexes spectroscopy |
| url | http://www.doiserbia.nb.rs/img/doi/0352-5139/2006/0352-51390611137S.pdf |
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