A Probabilistic Method for Estimating the Influence of Corrosion on the CuAlNi Shape Memory Alloy in Different Marine Environments

This paper gives an approach to the probabilistic percent corrosion depth estimation model for the CuAlNi Shape Memory Alloy (SMA) in different marine environments. Real testing was performed for validation of the theoretical model, where CuAlNi SMAs were exposed to 6 and 12 months in different seaw...

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Main Authors: Špiro Ivošević, Nataša Kovač, Gyöngyi Vastag, Peter Majerič, Rebeka Rudolf
Format: Article
Language:English
Published: MDPI AG 2021-03-01
Series:Crystals
Subjects:
Online Access:https://www.mdpi.com/2073-4352/11/3/274
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author Špiro Ivošević
Nataša Kovač
Gyöngyi Vastag
Peter Majerič
Rebeka Rudolf
author_facet Špiro Ivošević
Nataša Kovač
Gyöngyi Vastag
Peter Majerič
Rebeka Rudolf
author_sort Špiro Ivošević
collection DOAJ
description This paper gives an approach to the probabilistic percent corrosion depth estimation model for the CuAlNi Shape Memory Alloy (SMA) in different marine environments. Real testing was performed for validation of the theoretical model, where CuAlNi SMAs were exposed to 6 and 12 months in different seawater environments. Focus Ion Beam (FIB) analysis was used to measure the real corrosion depth on the surfaces of tested samples. A statistical approach to the investigation of the corrosion rate of CuAlNi SMA is given, where the corrosion rate is observed as a continuous random variable described by a linear corrosion model, with the assumption that corrosion starts immediately upon alloy surfaces being exposed to the influences of the marine environment. The three best-fitted two-parameter distributions for estimating the cumulative density function and the probability density function of the random variable were obtained by applying adequate statistical tests. Furthermore, using EDX analyses, we identified the chemical composition of the corroded materials, and with the help of Principal Component Analyses, we determined which corrosion environment had the most dominant influence on the corrosion process. The research results indicated that the changeable environment in the tides had a more heterogenic chemical content, which accelerated the corrosion rate.
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spelling doaj.art-9218da726f3e43f0b741de7e6a4bb2462023-11-21T09:57:42ZengMDPI AGCrystals2073-43522021-03-0111327410.3390/cryst11030274A Probabilistic Method for Estimating the Influence of Corrosion on the CuAlNi Shape Memory Alloy in Different Marine EnvironmentsŠpiro Ivošević0Nataša Kovač1Gyöngyi Vastag2Peter Majerič3Rebeka Rudolf4Faculty of Maritime Studies Kotor, University of Montenegro, I Bokeljske Brigade 44, 85330 Kotor, MontenegroFaculty of Applied Sciences, University of Donja Gorica, Oktoih 1, Donja Gorica, 81000 Podgorica, MontenegroFaculty of Sciences, University Novi Sad, Trg Dositeja Obradovića 3, 21000 Novi Sad, SerbiaFaculty of Mechanical Engineering, University of Maribor, Smetanova ul.17, 2000 Maribor, SloveniaFaculty of Mechanical Engineering, University of Maribor, Smetanova ul.17, 2000 Maribor, SloveniaThis paper gives an approach to the probabilistic percent corrosion depth estimation model for the CuAlNi Shape Memory Alloy (SMA) in different marine environments. Real testing was performed for validation of the theoretical model, where CuAlNi SMAs were exposed to 6 and 12 months in different seawater environments. Focus Ion Beam (FIB) analysis was used to measure the real corrosion depth on the surfaces of tested samples. A statistical approach to the investigation of the corrosion rate of CuAlNi SMA is given, where the corrosion rate is observed as a continuous random variable described by a linear corrosion model, with the assumption that corrosion starts immediately upon alloy surfaces being exposed to the influences of the marine environment. The three best-fitted two-parameter distributions for estimating the cumulative density function and the probability density function of the random variable were obtained by applying adequate statistical tests. Furthermore, using EDX analyses, we identified the chemical composition of the corroded materials, and with the help of Principal Component Analyses, we determined which corrosion environment had the most dominant influence on the corrosion process. The research results indicated that the changeable environment in the tides had a more heterogenic chemical content, which accelerated the corrosion rate.https://www.mdpi.com/2073-4352/11/3/274CuAlNi Shape Memory Alloycorrosion rateprobabilistic methodFocus Ion Beam analysistwo-parameter distributions
spellingShingle Špiro Ivošević
Nataša Kovač
Gyöngyi Vastag
Peter Majerič
Rebeka Rudolf
A Probabilistic Method for Estimating the Influence of Corrosion on the CuAlNi Shape Memory Alloy in Different Marine Environments
Crystals
CuAlNi Shape Memory Alloy
corrosion rate
probabilistic method
Focus Ion Beam analysis
two-parameter distributions
title A Probabilistic Method for Estimating the Influence of Corrosion on the CuAlNi Shape Memory Alloy in Different Marine Environments
title_full A Probabilistic Method for Estimating the Influence of Corrosion on the CuAlNi Shape Memory Alloy in Different Marine Environments
title_fullStr A Probabilistic Method for Estimating the Influence of Corrosion on the CuAlNi Shape Memory Alloy in Different Marine Environments
title_full_unstemmed A Probabilistic Method for Estimating the Influence of Corrosion on the CuAlNi Shape Memory Alloy in Different Marine Environments
title_short A Probabilistic Method for Estimating the Influence of Corrosion on the CuAlNi Shape Memory Alloy in Different Marine Environments
title_sort probabilistic method for estimating the influence of corrosion on the cualni shape memory alloy in different marine environments
topic CuAlNi Shape Memory Alloy
corrosion rate
probabilistic method
Focus Ion Beam analysis
two-parameter distributions
url https://www.mdpi.com/2073-4352/11/3/274
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