Electrocatalytic Performance of MnMoO<sub>4</sub>-rGO Nano-Electrocatalyst for Methanol and Ethanol Oxidation

Today, finding low-cost electro-catalysts for methanol and ethanol oxidation with high performance and stability is one of the new research topics. A nanocatalyst based on metal oxides in the form of MnMoO<sub>4</sub> was synthesized by a hydrothermal method for methanol (MOR) and ethano...

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Bibliographic Details
Main Authors: Parisa Salarizadeh, Sadegh Azizi, Hossein Beydaghi, Ahmad Bagheri, Mohammad Bagher Askari
Format: Article
Language:English
Published: MDPI AG 2023-06-01
Series:Molecules
Subjects:
Online Access:https://www.mdpi.com/1420-3049/28/12/4613
Description
Summary:Today, finding low-cost electro-catalysts for methanol and ethanol oxidation with high performance and stability is one of the new research topics. A nanocatalyst based on metal oxides in the form of MnMoO<sub>4</sub> was synthesized by a hydrothermal method for methanol (MOR) and ethanol (EOR) oxidation reactions. Adding reduced graphene oxide (rGO) to the catalyst structure improved the electrocatalytic activity of MnMoO<sub>4</sub> for the oxidation processes. The crystal structure and morphology of the MnMoO<sub>4</sub> and MnMoO<sub>4</sub>-rGO nanocatalysts were investigated by physical analyses such as scanning electron microscopy and X-ray diffraction. Their abilities for MOR and EOR processes in an alkaline medium were evaluated by performing electrochemical tests such as cyclic voltammetry, chronoamperometry, and electrochemical impedance spectroscopy. MnMoO<sub>4</sub>-rGO showed oxidation current densities of 60.59 and 25.39 mA/cm<sup>2</sup> and peak potentials of 0.62 and 0.67 V in MOR and EOR processes (at a scan rate of 40 mV/s), respectively. Moreover, stabilities of 91.7% in MOR and 88.6% in EOR processes were obtained from the chronoamperometry analysis within 6 h. All these features make MnMoO<sub>4</sub>-rGO a promising electrochemical catalyst for the oxidation of alcohols.
ISSN:1420-3049