Thiosemicarbazone Complexes of Transition Metals as Catalysts for Cross-Coupling Reactions
Catalysis of cross-coupling reactions under phosphane-free conditions represents an important ongoing challenge. Although transition metal complexes based on the thiosemicarbazone unit have been known for a very long time, their use in homogeneous catalysis has been studied only relatively recently....
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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MDPI AG
2020-09-01
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| Series: | Catalysts |
| Subjects: | |
| Online Access: | https://www.mdpi.com/2073-4344/10/10/1107 |
| _version_ | 1797552767136432128 |
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| author | Ioannis D. Kostas Barry R. Steele |
| author_facet | Ioannis D. Kostas Barry R. Steele |
| author_sort | Ioannis D. Kostas |
| collection | DOAJ |
| description | Catalysis of cross-coupling reactions under phosphane-free conditions represents an important ongoing challenge. Although transition metal complexes based on the thiosemicarbazone unit have been known for a very long time, their use in homogeneous catalysis has been studied only relatively recently. In particular, reports of cross-coupling catalytic reactions with such complexes have appeared only in the last 15 years. This review provides a survey of the research in this area and a discussion of the prospects for future developments. |
| first_indexed | 2024-03-10T16:04:50Z |
| format | Article |
| id | doaj.art-92588fa78ed545d195d98007f4014b07 |
| institution | Directory Open Access Journal |
| issn | 2073-4344 |
| language | English |
| last_indexed | 2024-03-10T16:04:50Z |
| publishDate | 2020-09-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Catalysts |
| spelling | doaj.art-92588fa78ed545d195d98007f4014b072023-11-20T14:56:53ZengMDPI AGCatalysts2073-43442020-09-011010110710.3390/catal10101107Thiosemicarbazone Complexes of Transition Metals as Catalysts for Cross-Coupling ReactionsIoannis D. Kostas0Barry R. Steele1Laboratory of Organic/Organometallic Chemistry & Catalysis, Institute of Chemical Biology, National Hellenic Research Foundation, Vas. Constantinou 48, 11635 Athens, GreeceLaboratory of Organic/Organometallic Chemistry & Catalysis, Institute of Chemical Biology, National Hellenic Research Foundation, Vas. Constantinou 48, 11635 Athens, GreeceCatalysis of cross-coupling reactions under phosphane-free conditions represents an important ongoing challenge. Although transition metal complexes based on the thiosemicarbazone unit have been known for a very long time, their use in homogeneous catalysis has been studied only relatively recently. In particular, reports of cross-coupling catalytic reactions with such complexes have appeared only in the last 15 years. This review provides a survey of the research in this area and a discussion of the prospects for future developments.https://www.mdpi.com/2073-4344/10/10/1107thiosemicarbazonemetal complextransition metal catalysiscross-coupling reactionHeck reactionSuzuki reaction |
| spellingShingle | Ioannis D. Kostas Barry R. Steele Thiosemicarbazone Complexes of Transition Metals as Catalysts for Cross-Coupling Reactions Catalysts thiosemicarbazone metal complex transition metal catalysis cross-coupling reaction Heck reaction Suzuki reaction |
| title | Thiosemicarbazone Complexes of Transition Metals as Catalysts for Cross-Coupling Reactions |
| title_full | Thiosemicarbazone Complexes of Transition Metals as Catalysts for Cross-Coupling Reactions |
| title_fullStr | Thiosemicarbazone Complexes of Transition Metals as Catalysts for Cross-Coupling Reactions |
| title_full_unstemmed | Thiosemicarbazone Complexes of Transition Metals as Catalysts for Cross-Coupling Reactions |
| title_short | Thiosemicarbazone Complexes of Transition Metals as Catalysts for Cross-Coupling Reactions |
| title_sort | thiosemicarbazone complexes of transition metals as catalysts for cross coupling reactions |
| topic | thiosemicarbazone metal complex transition metal catalysis cross-coupling reaction Heck reaction Suzuki reaction |
| url | https://www.mdpi.com/2073-4344/10/10/1107 |
| work_keys_str_mv | AT ioannisdkostas thiosemicarbazonecomplexesoftransitionmetalsascatalystsforcrosscouplingreactions AT barryrsteele thiosemicarbazonecomplexesoftransitionmetalsascatalystsforcrosscouplingreactions |