The Effect of Interfacial Zone Due to Nanoparticle–Surfactant Interaction on Dielectric Properties of Vegetable Oil Based Nanofluids

Nanoparticles are generally anti-lipophilic and have a tendency to aggregate when they are embedded in nanofluids. Thus, surfactants have a major role in achieving long term dispersion stability of nanofluids through surface modification of nanoparticles. However, the surfactant changes the structur...

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Main Authors: Rizwan A. Farade, Noor Izzri Abdul Wahab, Diaa-Eldin A. Mansour, Norhafiz B. Azis, Jasronita Bt. Jasni, Veerapandiyan Veerasamy, Arangarajan Vinayagam, Bandanawaz M. Kotiyal, T. M. Yunus Khan
Format: Article
Language:English
Published: IEEE 2021-01-01
Series:IEEE Access
Subjects:
Online Access:https://ieeexplore.ieee.org/document/9491153/
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author Rizwan A. Farade
Noor Izzri Abdul Wahab
Diaa-Eldin A. Mansour
Norhafiz B. Azis
Jasronita Bt. Jasni
Veerapandiyan Veerasamy
Arangarajan Vinayagam
Bandanawaz M. Kotiyal
T. M. Yunus Khan
author_facet Rizwan A. Farade
Noor Izzri Abdul Wahab
Diaa-Eldin A. Mansour
Norhafiz B. Azis
Jasronita Bt. Jasni
Veerapandiyan Veerasamy
Arangarajan Vinayagam
Bandanawaz M. Kotiyal
T. M. Yunus Khan
author_sort Rizwan A. Farade
collection DOAJ
description Nanoparticles are generally anti-lipophilic and have a tendency to aggregate when they are embedded in nanofluids. Thus, surfactants have a major role in achieving long term dispersion stability of nanofluids through surface modification of nanoparticles. However, the surfactant changes the structure of the interfacial zone around nanoparticles and can have a crucial impact on the dielectric properties of dielectric nanofluids. Accordingly, this paper aims to clarify the role of interfacial zone on dielectric properties of vegetable oil based Al<sub>2</sub>O<sub>3</sub> nanofluids including relative permittivity, dissipation factor, and AC breakdown voltage. Moreover, a polarization model of nanofluids was proposed to calculate their relative permittivity considering surfactant effect. Different filler levels ranging from 0.01 wt&#x0025; to 0.05 wt&#x0025; were used and various temperature ranges were considered to validate the proposed model. Relative permittivity calculated from the proposed model was almost in line with experimental results. Proposed model depicted that surfactant contributes for orientational polarization of nanoparticles in the relative permittivity calculation. So, improvement in the relative permittivity of dielectric nanofluids has been attained from 0.01 wt&#x0025; to 0.05 wt&#x0025; of Al<sub>2</sub>O<sub>3</sub> nanoparticles due to both internal and orientational polarization of nanoparticles. Regarding dissipation factor of prepared nanofluids, it decreased against the weight percentage of nanoparticles, while the mean AC breakdown voltage increased against the weight percentage. All these effects were discussed considering the structure of interfacial zone and its impact on the alignment of oil chains and the energy loss of electrons.
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spelling doaj.art-92600f725638446aadb64d041b9e65362022-12-21T19:11:57ZengIEEEIEEE Access2169-35362021-01-01910703310704510.1109/ACCESS.2021.30987589491153The Effect of Interfacial Zone Due to Nanoparticle&#x2013;Surfactant Interaction on Dielectric Properties of Vegetable Oil Based NanofluidsRizwan A. Farade0https://orcid.org/0000-0002-8037-2538Noor Izzri Abdul Wahab1https://orcid.org/0000-0002-9042-9796Diaa-Eldin A. Mansour2https://orcid.org/0000-0002-3894-4299Norhafiz B. Azis3https://orcid.org/0000-0002-9669-569XJasronita Bt. Jasni4https://orcid.org/0000-0002-9617-8609Veerapandiyan Veerasamy5https://orcid.org/0000-0002-7887-2613Arangarajan Vinayagam6https://orcid.org/0000-0003-2247-1893Bandanawaz M. Kotiyal7T. M. Yunus Khan8Department of Electrical and Electronics Engineering, Faculty of Engineering, University Putra Malaysia, Serdang, MalaysiaDepartment of Electrical and Electronics Engineering, Faculty of Engineering, University Putra Malaysia, Serdang, MalaysiaDepartment of Electrical Power and Machines Engineering, Faculty of Engineering, Tanta University, Tanta, EgyptDepartment of Electrical and Electronics Engineering, Faculty of Engineering, University Putra Malaysia, Serdang, MalaysiaDepartment of Electrical and Electronics Engineering, Faculty of Engineering, University Putra Malaysia, Serdang, MalaysiaDepartment of Electrical and Electronics Engineering, Faculty of Engineering, University Putra Malaysia, Serdang, MalaysiaDepartment of Electrical and Electronics Engineering, New Horizon College of Engineering, Bengaluru, IndiaDepartment of Electrical Engineering, School of Engineering and Technology, Anjuman-I-Islam&#x2019;s Kalsekar Technical Campus, Mumbai, IndiaDepartment of Mechanical Engineering, College of Engineering, King Khalid University, Abha, Saudi ArabiaNanoparticles are generally anti-lipophilic and have a tendency to aggregate when they are embedded in nanofluids. Thus, surfactants have a major role in achieving long term dispersion stability of nanofluids through surface modification of nanoparticles. However, the surfactant changes the structure of the interfacial zone around nanoparticles and can have a crucial impact on the dielectric properties of dielectric nanofluids. Accordingly, this paper aims to clarify the role of interfacial zone on dielectric properties of vegetable oil based Al<sub>2</sub>O<sub>3</sub> nanofluids including relative permittivity, dissipation factor, and AC breakdown voltage. Moreover, a polarization model of nanofluids was proposed to calculate their relative permittivity considering surfactant effect. Different filler levels ranging from 0.01 wt&#x0025; to 0.05 wt&#x0025; were used and various temperature ranges were considered to validate the proposed model. Relative permittivity calculated from the proposed model was almost in line with experimental results. Proposed model depicted that surfactant contributes for orientational polarization of nanoparticles in the relative permittivity calculation. So, improvement in the relative permittivity of dielectric nanofluids has been attained from 0.01 wt&#x0025; to 0.05 wt&#x0025; of Al<sub>2</sub>O<sub>3</sub> nanoparticles due to both internal and orientational polarization of nanoparticles. Regarding dissipation factor of prepared nanofluids, it decreased against the weight percentage of nanoparticles, while the mean AC breakdown voltage increased against the weight percentage. All these effects were discussed considering the structure of interfacial zone and its impact on the alignment of oil chains and the energy loss of electrons.https://ieeexplore.ieee.org/document/9491153/Al₂O₃ nanoparticlessurfactantrelative permittivity modelnanofluidsdielectric properties
spellingShingle Rizwan A. Farade
Noor Izzri Abdul Wahab
Diaa-Eldin A. Mansour
Norhafiz B. Azis
Jasronita Bt. Jasni
Veerapandiyan Veerasamy
Arangarajan Vinayagam
Bandanawaz M. Kotiyal
T. M. Yunus Khan
The Effect of Interfacial Zone Due to Nanoparticle&#x2013;Surfactant Interaction on Dielectric Properties of Vegetable Oil Based Nanofluids
IEEE Access
Al₂O₃ nanoparticles
surfactant
relative permittivity model
nanofluids
dielectric properties
title The Effect of Interfacial Zone Due to Nanoparticle&#x2013;Surfactant Interaction on Dielectric Properties of Vegetable Oil Based Nanofluids
title_full The Effect of Interfacial Zone Due to Nanoparticle&#x2013;Surfactant Interaction on Dielectric Properties of Vegetable Oil Based Nanofluids
title_fullStr The Effect of Interfacial Zone Due to Nanoparticle&#x2013;Surfactant Interaction on Dielectric Properties of Vegetable Oil Based Nanofluids
title_full_unstemmed The Effect of Interfacial Zone Due to Nanoparticle&#x2013;Surfactant Interaction on Dielectric Properties of Vegetable Oil Based Nanofluids
title_short The Effect of Interfacial Zone Due to Nanoparticle&#x2013;Surfactant Interaction on Dielectric Properties of Vegetable Oil Based Nanofluids
title_sort effect of interfacial zone due to nanoparticle x2013 surfactant interaction on dielectric properties of vegetable oil based nanofluids
topic Al₂O₃ nanoparticles
surfactant
relative permittivity model
nanofluids
dielectric properties
url https://ieeexplore.ieee.org/document/9491153/
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