(5-Aminoisophthalato-κN)triaqua(1,10-phenanthroline-κ2N,N′)cobalt(II) trihydrate
The CoII atom in the title compound, [Co(C8H5NO4)(C12H8N2)(H2O)3]·3H2O, is six-coordinated in a CoN3O3 octahedral geometry; the water-coordinated CoII atom is chelated by the N-heterocycle. An intermolecular N—H...O hydrogen bond occurs. The carboxylate entity coordinates...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010-11-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810040560 |
| Summary: | The CoII atom in the title compound, [Co(C8H5NO4)(C12H8N2)(H2O)3]·3H2O, is six-coordinated in a CoN3O3 octahedral geometry; the water-coordinated CoII atom is chelated by the N-heterocycle. An intermolecular N—H...O hydrogen bond occurs. The carboxylate entity coordinates through the amino group. The carboxylate donor unit, coordinated and uncoordinated water molecules interact through O—H...O and N—H...O hydrogen bonds, generating a tightly-held three-dimensional cage-like network. |
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| ISSN: | 1600-5368 |